SCI和EI收录∣中国化工学会会刊

›› 2017, Vol. 25 ›› Issue (2): 143-148.DOI: 10.1016/j.cjche.2016.10.001

• Selected Papers from the International Chemical Separation Technology Conference (ICSTC) • 上一篇    下一篇

H2 solubility and mass transfer in anthraquinone working solution: Experimental and modeling study

Zhigang Lei, Yaru Guo, Yanyan Guo, Xinxin Li, Chengna Dai   

  1. State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China
  • 收稿日期:2016-08-15 修回日期:2016-10-05 出版日期:2017-02-28 发布日期:2017-03-14
  • 通讯作者: Chengna Dai
  • 基金资助:
    Supported by the National Natural Science Foundation of China (Nos. 21476009, 21406007, and U1462104).

H2 solubility and mass transfer in anthraquinone working solution: Experimental and modeling study

Zhigang Lei, Yaru Guo, Yanyan Guo, Xinxin Li, Chengna Dai   

  1. State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China
  • Received:2016-08-15 Revised:2016-10-05 Online:2017-02-28 Published:2017-03-14
  • Supported by:
    Supported by the National Natural Science Foundation of China (Nos. 21476009, 21406007, and U1462104).

摘要: Thisworkwas focused on the measurement of the solubility of hydrogen (H2) in anthraquinoneworking solution at temperatures of 30.0-80.0℃ and pressures of 0.2-3.0 MPa by the method of experimental and COSMO-RS model study. The influence of various factors, i.e., including pressure, temperature and solvent volume ratio, on H2 solubility was investigated. According to the experimental results, H2 solubility in anthraquinone working solution increases with the increase of pressure. At low pressures, the temperature had little effect on H2 solubility while under high pressures H2 solubility increases with increasing temperature. Henry's constant lnH has a good linear relationship with 1/T (lnH=-1319.1/T+9.91). The effect of volume ratio of trioctyl phosphate to trimethylbenzene on the solubility of hydrogen was studied and the results showed that increasing the amount of trimethylbenzene was conducive to the dissolution of hydrogen. In addition, there is a linear relationship between ln((P0-Pe)/(Pt-Pe)) and the time t. Gas-liquid mass transfer coefficient was obtained by calculating the slope of the line.

关键词: Hydrogen, Solubility, Anthraquinone working solution, Trimethylbenzene, COSMO-RS model, Mass transfer

Abstract: Thisworkwas focused on the measurement of the solubility of hydrogen (H2) in anthraquinoneworking solution at temperatures of 30.0-80.0℃ and pressures of 0.2-3.0 MPa by the method of experimental and COSMO-RS model study. The influence of various factors, i.e., including pressure, temperature and solvent volume ratio, on H2 solubility was investigated. According to the experimental results, H2 solubility in anthraquinone working solution increases with the increase of pressure. At low pressures, the temperature had little effect on H2 solubility while under high pressures H2 solubility increases with increasing temperature. Henry's constant lnH has a good linear relationship with 1/T (lnH=-1319.1/T+9.91). The effect of volume ratio of trioctyl phosphate to trimethylbenzene on the solubility of hydrogen was studied and the results showed that increasing the amount of trimethylbenzene was conducive to the dissolution of hydrogen. In addition, there is a linear relationship between ln((P0-Pe)/(Pt-Pe)) and the time t. Gas-liquid mass transfer coefficient was obtained by calculating the slope of the line.

Key words: Hydrogen, Solubility, Anthraquinone working solution, Trimethylbenzene, COSMO-RS model, Mass transfer