Synthesis, characterization and application of PVA/ionic liquid mixed matrix membranes for pervaporation dehydration of isopropanol

doi:10.1016/j.cjche.2017.02.011

摘要/Abstract

摘要： In this study, polyvinyl alcohol (PVA)-ionic liquid (IL) membranes were prepared for the separation of isopropyl alcohol (IPA)-water azeotropic mixtures by pervaporation. PVA-IL composite membranes were prepared by simple solvent evaporation method using four ILs, viz., 1-n-butyl-3-methylimidazolium chloride (BMIMCl), 1-hexyl-3-methylimidazolium chloride (HMIMCl), 1-hexyl-3-methylimidazolium tetrafluoroborate (HMIMBF4) and 1-octyl-3-methylimidazolium chloride (OMIMCl). Three ILs were used to study the effect of alkyl chain on the pervaporation performance. The study had focused on the effect feed water concentration from 10%-40% and effect of feed temperature from 50-80℃. Physiochemical properties of all the membranes were studied using Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM) and contact angle measurement. The Arrhenius activation energies for permeation were estimated to be in the range 4-12 kJ·mol^-1 from the temperature dependent permeation values.

关键词: Composite membranes, Ionic liquids, Dehydration, Isopropanol, Pervaporation

Abstract: In this study, polyvinyl alcohol (PVA)-ionic liquid (IL) membranes were prepared for the separation of isopropyl alcohol (IPA)-water azeotropic mixtures by pervaporation. PVA-IL composite membranes were prepared by simple solvent evaporation method using four ILs, viz., 1-n-butyl-3-methylimidazolium chloride (BMIMCl), 1-hexyl-3-methylimidazolium chloride (HMIMCl), 1-hexyl-3-methylimidazolium tetrafluoroborate (HMIMBF4) and 1-octyl-3-methylimidazolium chloride (OMIMCl). Three ILs were used to study the effect of alkyl chain on the pervaporation performance. The study had focused on the effect feed water concentration from 10%-40% and effect of feed temperature from 50-80℃. Physiochemical properties of all the membranes were studied using Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM) and contact angle measurement. The Arrhenius activation energies for permeation were estimated to be in the range 4-12 kJ·mol^-1 from the temperature dependent permeation values.

Key words: Composite membranes, Ionic liquids, Dehydration, Isopropanol, Pervaporation

Ganesh B. Thorat, Smita Gupta, Z. V. P. Murthy. Synthesis, characterization and application of PVA/ionic liquid mixed matrix membranes for pervaporation dehydration of isopropanol[J]. , 2017, 25(10): 1402-1411.

参考文献

[1] D. Shah, D. Bhattacharyya, A.Ghorpade, W. Mangum, Pervaporation of pharmaceutical waste streams and synthetic mixtures using water selective membranes, Environ. Prog. 18(1999) 21-29.
[2] N. Wynn, Pervaporation comes of age, Chem. Eng. Prog. 97(2001) 66-72.
[3] Q. Wang, N. Li, B. Bolto, M. Hoang, Z. Xie, Desalination by pervaporation, Desalination 387(2016) 46-60.
[4] Y.K. Ong, G.M. Shi, N.L. Le, Y.P. Tang, J. Zuo, S.P. Nunes, T.S. Chung, Recent membrane development for pervaporation processes, Prog. Polym. Sci. 57(2016) 1-31.
[5] Z. Jia, G. Wu, Metal-organic frameworks based mixed matrix membranes for pervaporation, Microporous Mesoporous Mater. 235(2016) 151-159.
[6] M.J. Salar-García, V.M. Ortiz-Martínez, F.J. Hernández-Fernández, A.P. de los Ríos, J. Quesada-Medina, Ionic liquid technology to recover volatile organic compounds (VOCs), J. Hazard. Mater. 321(2017) 484-499.
[7] Z.L. Xiu, A.P. Zeng, Present state and perspective of downstream processing of biologically produced 1, 3-propanediol and 2,3-butanediol, Appl. Microbiol. Biotechnol. 78(2008) 917-926.
[8] T. Uragami, T. Saito, T. Miyata, Pervaporative dehydration characteristics of an ethanol/water azeotrope through various chitosan membranes, Carbohydr. Polym. 120(2015) 1-6.
[9] Y.T. Ong, S.H. Tan, Pervaporation separation of a ternary azeotrope containing ethyl acetate, ethanol and water using a buckypaper supported ionic liquid membrane, Chem. Eng. Res. Des. 109(2016) 116-126.
[10] H.S. Samanta, S.K. Ray, Separation of ethanol from water by pervaporation using mixed matrix copolymer membranes, Sep. Purif. Technol. 146(2015) 176-186.
[11] N. Jullok, R. Van Hooghten, P. Luis, A. Volodin, C. Van Haesendonck, J. Vermant, B. Van der Bruggen, Effect of silica nanoparticles in mixed matrix membranes for pervaporation dehydration of acetic acid aqueous solution:Plant-inspired dewatering systems, J. Clean. Prod. 112(2016) 4879-4889.
[12] H. Sardarabadi, S.M. Mousavi, E. Saljoughi, Removal of 2-propanol from water by pervaporation using poly(vinylidene fluoride) membrane filled with carbon black, Appl. Surf. Sci. 368(2016) 277-287.
[13] K.Y. Jee, N. Kim, Y.T. Lee, The effect of metal complex on pervaporation performance of composite membrane for separation of n-butanol/water mixture, J. Ind. Eng. Chem. 44(2016) 155-163.
[14] W. Zhang, Y. Ying, J. Ma, X. Guo, H. Huang, D. Liu, C. Zhong, Mixed matrix membranes incorporated with polydopamine-coated metal-organic framework for dehydration of ethylene glycol by pervaporation, J. Membr. Sci. 527(2017) 8-17.
[15] M. Chen, X. Wu, F. Soyekwo, Q. Zhang, R. Lv, A. Zhu, Q. Liu, Toward improved hydrophilicity of polymers of intrinsic microporosity for pervaporation dehydration of ethylene glycol, Sep. Purif. Technol. 174(2017) 166-173.
[16] H. Wu, T. Zhou, X. Li, C. Zhao, Z. Jiang, Enhancing the separation performance by introducing bioadhesive bonding layer in composite pervaporation membranes for ethanol dehydration, Chin. J. Chem. Eng. 23(2015) 372-378.
[17] H.R. Mehta, Z.V.P. Murthy, Preparation of sodium montmorillonite clay loaded poly(vinyl alcohol)-chitosan composite mixed matrix membranes and their application in pervaporation dehydration of isopropanol, J. Polym. Mater. 33(2016) 319-331.
[18] X. Chen, G. Liu, H. Zhang, Y. Fan, Fabrication of graphene oxide composite membranes and their application for pervaporation dehydration of butanol, Chin. J. Chem. Eng. 23(2015) 1102-1109.
[19] J.H. Jhaveri, Z.V.P. Murthy, A comprehensive review on anti-fouling nanocomposite membranes for pressure driven membrane separation processes, Desalination 379(2016) 137-154.
[20] J.H. Jhaveri, Z.V.P. Murthy, Nanocomposite membranes, Desalin. Water Treat. 57(2016) 26803-26819.
[21] V. Van Hoof, L. Van den Abeele, A. Buekenhoudt, C. Dotremont, R. Leysen, Economic comparison between azeotropic distillation and different hybrid systems combining distillation with pervaporation for the dehydration of isopropanol, Sep. Purif. Technol. 37(2004) 33-49.
[22] X. Feng, R.Y. Huang, Liquid separation by membrane pervaporation:A review, Ind. Eng. Chem. Res. 36(1997) 1048-1066.
[23] J.E. Logsdon, R.A. Loke, Isopropyl Alcohol, Kirk-Othmer Encyclopedia of Chemical Technology, 2000.
[24] J.G. Varghese, A.A. Kittur, P.S. Rachipudi, M.Y. Kariduraganavar, Synthesis, characterization and pervaporation performance of chitosan-g-polyaniline membranes for the dehydration of isopropanol, J. Membr. Sci. 364(2010) 111-121.
[25] S. Razavi, A. Sabetghadam, T. Mohammadi, Dehydration of isopropanol by PVA-APTEOS/TEOS nanocomposite membranes, Chem. Eng. Res. Des. 89(2011) 148-155.
[26] M. Sairam, M.B. Patil, R.S. Veerapur, S.A. Patil, T.M. Aminabhavi, Novel dense poly (vinyl alcohol)-TiO₂ mixed matrix membranes for pervaporation separation of water-isopropanol mixtures at 30℃, J. Membr. Sci. 281(2006) 95-102.
[27] Y. Qin, J. Sheth, K. Sirkar, Supported liquid membrane-based pervaporation for VOC removal from water, Ind. Eng. Chem. Res. 41(2002) 3413-3428.
[28] M. Matsumura, H. Kataoka, Separation of dilute aqueous butanol and acetone solutions by pervaporation through liquid membranes, Biotechnol. Bioeng. 30(1987) 887-895.
[29] Y.T. Ong, K.F. Yee, Y.K. Cheng, S.H. Tan, A review on the use and stability of supported liquid membranes in the pervaporation process, Sep. Purif. Rev. 43(2014) 62-88.
[30] M. Amirilargani, B. Sadatnia, Poly (vinyl alcohol)/zeolitic imidazolate frameworks (ZIF-8) mixed matrix membranes for pervaporation dehydration of isopropanol, J. Membr. Sci. 469(2014) 1-10.
[31] D. Hua, Y.K. Ong, P. Wang, T.S. Chung, Thin-film composite tri-bore hollow fiber (TFC TbHF) membranes for isopropanol dehydration by pervaporation, J. Membr. Sci. 471(2014) 155-167.
[32] Z.V.P. Murthy, M.K. Shah, Separation of isopropyl alcohol-toluene mixtures by pervaporation using poly (vinyl alcohol) membrane, Arab. J. Chem. 10(Supplement 1) (2017) S56-S61.
[33] L.L. Xia, C.L. Li, Y. Wang, In-situ crosslinked PVA/organosilica hybrid membranes for pervaporation separations, J. Membr. Sci. 498(2016) 263-275.
[34] A.V. Penkova, S.F.A. Acquah, M.E. Dmitrenko, M.P. Sokolova, M.E. Mikhailova, E.S. Polyakov, S.S. Ermakov, D.A. Markelov, D. Roizard, Improvement of pervaporation PVA membranes by the controlled incorporation of fullerenol nanoparticles, Mater. Des. 96(2016) 416-423.
[35] P. Rachipudi, M. Kariduraganavar, A. Kittur, A. Sajjan, Synthesis and characterization of sulfonated-poly (vinyl alcohol) membranes for the pervaporation dehydration of isopropanol, J. Membr. Sci. 383(2011) 224-234.
[36] Q. Zhao, J. Qian, Q. An, M. Zhu, M. Yin, Z. Sun, Poly (vinyl alcohol)/polyelectrolyte complex blend membrane for pervaporation dehydration of isopropanol, J. Membr. Sci. 343(2009) 53-61.
[37] S.G. Adoor, M. Sairam, L.S. Manjeshwar, K. Raju, T.M. Aminabhavi, Sodium montmorillonite clay loaded novel mixed matrix membranes of poly (vinyl alcohol) for pervaporation dehydration of aqueous mixtures of isopropanol and 1,4-dioxane, J. Membr. Sci. 285(2006) 182-195.
[38] P. Rdzanek, S. Heitmann, A. Górak, W. Kamiński, Application of supported ionic liquid membranes (SILMs) for biobutanol pervaporation, Sep. Purif. Technol. 155(2015) 83-88.
[39] T. Uragami, Y. Matsuoka, T. Miyata, Permeation and separation characteristics in removal of dilute volatile organic compounds from aqueous solutions through copolymer membranes consisted of poly(styrene) and poly(dimethylsiloxane) containing a hydrophobic ionic liquid by pervaporation, J. Membr. Sci. 506(2016) 109-118.
[40] C.W. Liew, S. Ramesh, A.K. Arof, A novel approach on ionic liquid-based poly(vinyl alcohol) proton conductive polymer electrolytes for fuel cell applications, Int. J. Hydrog. Energy 39(2014) 2917-2928.
[41] P. Izák, W. Ruth, Z. Fei, P.J. Dyson, U. Kragl, Selective removal of acetone and butan-1-ol from water with supported ionic liquid-polydimethylsiloxane membrane by pervaporation, Chem. Eng. J. 139(2008) 318-321.
[42] Y. Wang, L. Jiang, T. Matsuura, T.S. Chung, S.H. Goh, Investigation of the fundamental differences between polyamide-imide (PAI) and polyetherimide (PEI) membranes for isopropanol dehydration via pervaporation, J. Membr. Sci. 318(2008) 217-226.
[43] P.J. Flory, J. Rehner Jr., Statistical mechanics of cross-linked polymer networks Ⅱ. Swelling, J. Chem. Phys. 11(1943) 521-526.
[44] R. Huang, R. Pal, G. Moon, Pervaporation dehydration of aqueous ethanol and isopropanol mixtures through alginate/chitosan two ply composite membranes supported by poly (vinylidene fluoride) porous membrane, J. Membr. Sci. 167(2000) 275-289.
[45] R.W. Baker, Membrane Technology and Applications, second ed., 2004(Chapter 9), John Wiley & Sons Chichester, England.
[46] P. Rachipudi, A. Kittur, A. Sajjan, M. Kariduraganavar, Synthesis and characterization of hybrid membranesusingchitosan and 2-(3,4-epoxycyclohexyl)ethyltrimethoxysilane for pervaporation dehydration of isopropanol, J. Membr. Sci. 441(2013) 83-92.
[47] X. Qiao, T.S. Chung, K. Pramoda, Fabrication and characterization of BTDA-TDI/MDI (P84) co-polyimide membranes for the pervaporation dehydration of isopropanol, J. Membr. Sci. 264(2005) 176-189.
[48] D.H. Zaitsau, K. Fumino, V.N. Emel'yanenko, A.V. Yermalayeu, R. Ludwig, S.P. Verevkin, Structure-property relationships in ionic liquids:A study of the anion dependence in vaporization enthalpies of imidazolium-based ionic liquids, ChemPhysChem 13(2012) 1868-1876.
[49] J.G. Huddleston, A.E. Visser, W.M. Reichert, H.D. Willauer, G.A. Broker, R.D. Rogers, Characterization and comparison of hydrophilic and hydrophobic room temperature ionic liquids incorporating the imidazolium cation, Green Chem. 3(2001) 156-164.
[50] S.P. Verevkin, D.H. Zaitsau, V.N. Emelyanenko, R.V. Ralys, A.V. Yermalayeu, C. Schick, Does alkyl chain length really matter? Structure-property relationships in thermochemistry of ionic liquids, Thermochim. Acta 562(2013) 84-95.