Effect of monovalent anions on cationic Gemini micro-emulsion

doi:10.1016/j.cjche.2018.03.010

Chinese Journal of Chemical Engineering ›› 2018, Vol. 26 ›› Issue (12): 2636-2640.DOI: 10.1016/j.cjche.2018.03.010

• Energy, Resources and Environmental Technology • 上一篇下一篇

Effect of monovalent anions on cationic Gemini micro-emulsion

Yinglu Gu, Shuang Chen, Hui'e Liu, Yubin Wang, Pingping Zhou

State Key Laboratory of Heavy Oil Processing, China University of Petroleum(East China), Qingdao 266580, China

收稿日期:2017-12-27 修回日期:2018-03-07 出版日期:2018-12-28 发布日期:2019-01-09
通讯作者: Shuang Chen
基金资助:
Supported by China Petroleum Science and Technology Innovation Fund (2017D-5007-0601), State Key Laboratory of Heavy Oil Processing and China University of Petroleum (East China) 2018 Graduate Engineering Innovation Project Found (SLKZZ-2017002).

Effect of monovalent anions on cationic Gemini micro-emulsion

Yinglu Gu, Shuang Chen, Hui'e Liu, Yubin Wang, Pingping Zhou

State Key Laboratory of Heavy Oil Processing, China University of Petroleum(East China), Qingdao 266580, China

Received:2017-12-27 Revised:2018-03-07 Online:2018-12-28 Published:2019-01-09
Contact: Shuang Chen
Supported by:
Supported by China Petroleum Science and Technology Innovation Fund (2017D-5007-0601), State Key Laboratory of Heavy Oil Processing and China University of Petroleum (East China) 2018 Graduate Engineering Innovation Project Found (SLKZZ-2017002).

摘要/Abstract

摘要： Micro-emulsion usually consists of water, oil, surfactants and co-surfactants, and each component has an effect on the phase behavior and solubilization of the micro-emulsion. When the surfactant in the micro-emulsion system is quaternary ammonium cationic Gemini surfactant, the surfactant mainly combines with the anions in the salt. With the increase of salt concentration, the phase transformation of Winsor I → Winsor Ⅲ → Winsor Ⅱ occurred, but the optimum salinity and salt width are different because of the type of salt. The effects of 5 different kinds of monovalent anions, including C₆H₅SO₃^-, I^-, Br^-, NO₃^- and Cl^-, on the phase behavior and solubilization of quaternary ammonium cationic Gemini micro-emulsion are researched by Winsor phase diagram. It is found that the effects of organic anions C₆H₅SO₃^- and I^- on the phase behavior and solubilization of quaternary ammonium cationic Gemini micro-emulsion are most significant, and the effects of Br^-, NO₃^- and Cl^- are less significant. Meanwhile, when the optimum solubilization is achieved, the amount of sodium benzoate is the least, indicating that the organic anion has stronger self-organization behavior with quaternary ammonium cationic Gemini surfactants.

关键词: Gemini surfactant, Monovalent anions, Micro-emulsion, Phase behavior, Solubilization

Abstract: Micro-emulsion usually consists of water, oil, surfactants and co-surfactants, and each component has an effect on the phase behavior and solubilization of the micro-emulsion. When the surfactant in the micro-emulsion system is quaternary ammonium cationic Gemini surfactant, the surfactant mainly combines with the anions in the salt. With the increase of salt concentration, the phase transformation of Winsor I → Winsor Ⅲ → Winsor Ⅱ occurred, but the optimum salinity and salt width are different because of the type of salt. The effects of 5 different kinds of monovalent anions, including C₆H₅SO₃^-, I^-, Br^-, NO₃^- and Cl^-, on the phase behavior and solubilization of quaternary ammonium cationic Gemini micro-emulsion are researched by Winsor phase diagram. It is found that the effects of organic anions C₆H₅SO₃^- and I^- on the phase behavior and solubilization of quaternary ammonium cationic Gemini micro-emulsion are most significant, and the effects of Br^-, NO₃^- and Cl^- are less significant. Meanwhile, when the optimum solubilization is achieved, the amount of sodium benzoate is the least, indicating that the organic anion has stronger self-organization behavior with quaternary ammonium cationic Gemini surfactants.

Key words: Gemini surfactant, Monovalent anions, Micro-emulsion, Phase behavior, Solubilization

Yinglu Gu, Shuang Chen, Hui'e Liu, Yubin Wang, Pingping Zhou. Effect of monovalent anions on cationic Gemini micro-emulsion[J]. Chinese Journal of Chemical Engineering, 2018, 26(12): 2636-2640.

Yinglu Gu, Shuang Chen, Hui'e Liu, Yubin Wang, Pingping Zhou. Effect of monovalent anions on cationic Gemini micro-emulsion[J]. Chin.J.Chem.Eng., 2018, 26(12): 2636-2640.

参考文献

[1] S. Tenjarla, Micro-emulsions:An overview and pharmaceutical applications, Crit. Rev. Ther. Drug Carrier Syst. 16(5) (1999) 461-521.

[2] M.J. Lawrence, G.D. Rees, Micro-emulsion-based media as novel drug delivery systems, Adv. Drug Deliv. Rev. 45(2000) 89-121.

[3] S.P. Moulik, B.K. Paul, Structure, dynamics and transport properties of microemulsions, Adv. Colloid Interf. Sci. 78(1998) 99-195.

[4] Principles of surfactant action. China Reading Weekly, 2004-02-11(in Chinese).

[5] Y. Yuan, H.E. Liu, M.M. Xu, et al., Effect of inorganic salts on the phase behavior of sodium dodecyl benzene sulfonate micro-emulsion system, Pet. Eng. 11(2014) 1277-1283.

[6] K. Bijma, E. Rank, J.B.F.N. Engberts, Effect of counter-ion structure on micellar growth of alkylpyridinium surfactants in aqueous solution, J. Colloid Interface Sci. 205(2) (1998) 245-256.

[7] M.B. And, V.G. Gaikar, Characterization of interaction between butyl benzene sulfonates and cetyl trimethylammonium bromide in mixed aggregate systems, Langmuir 15(14) (1999) 4740-4751.

[8] H. Kawasaki, I.A. Ryota, H. Maeda, Effects of hydrophobic counter-ions on the phase behavior of tetradecyldimethylhydroxylammonium chloride in aqueous solutions, Langmuir 18(22) (2002) 8358-8363.

[9] M. Mao, J.B. Huang, J.X. Xiao, et al., The interaction between the aromatic organic counter-ion and ionic surfactant micelle, Acta Chim. Sin. 11(2000) 1358-1364.

[10] A.A. Ait, R. Makhloufi, Linear and nonlinear rheology of an aqueous concentrated system of cethyltrimethylammonium chloride and sodium salicylate, Phys. Rev. E Stat. Phys. Plasmas Fluids Relat. Interdiscip. Top. 56(4) (1997) 4474-4478.

[11] R. Jiang, J.X. Zhao, X.M. Hu, et al., Effect of organic counter-ions on the surface activity of C₁₂-s-C₁₂·2Br in aqueous solution, Acta Phys. Chim. Sin. 8(2007) 1260-1264.

[12] M.Q. Ao, P.P. Huang, G.Y. Xu, et al., Aggregation and thermodynamic properties of ionic liquid-type Gemini imidazolium surfactants with different spacer length, Colloid Polym. Sci. 287(2009) 395-402.

[13] L. Cash, J.L. Cayias, G. Fournier, et al., The application of low interfacial tension scaling rules to binary hydrocarbon mixtures, J. Colloid Interface Sci. 59(1977) 39-44.

[14] J.L. Cayias, R.S. Schechter, W.H. Wade, Modeling crude oils for low interfacial tension, Soc. Pet. Eng. J. 16(6) (1976) 351-357.

[15] P. Tanthakit, S. Chavadej, J.F. Scamehorn, et al., Micro-emulsion formation and detergency with oily soil:IV. Effect of rinse cycle design, J. Surf. Deter. 11(2) (2008) 117-128.

[16] C. Tongcumpou, E.J. Acosts, L.B. Quencer, et al., Micro-emulsion formation and detergency with oily soils:I. Phase behavior and interfacial tension, J. Surf. Deter. 6(3) (2003) 191-203.

[17] J. Biais, M. Barthe, B. Clin, et al., The pseudophase model for micro-emulsions:Phase diagrams in pseudo-phase space, J. Colloid Interface Sci. 102(2) (1984) 361-369.

[18] J.L. Chai, H. Sun, X.Q. Li, et al., Effect of inorganic salts on the phase behavior of microemulsion systems containing sodium dodecyl sulfate, J. Dispers. Sci. Technol. 33(10) (2012) 1470-1474.

[19] Z.H. Wu, Y.B. Ma, H.E. Liu, et al., Effect of organic counter-ions on the surface activity of C₁₂-s-C₁₂·2Br in aqueous solution, CIESC J. 4(2016) 1399-1404(in Chinese).

[20] Z.G. Cui, F.S. Yin, Micro-emulsion Technology and Application, China Light Ind. Pre., Beijing, 199919-28(in Chinese).

[21] J.L. Chai, Y.T. Wu, X.Q. Li, et al., Phase behavior of the micro-emulsion systems containing alkyl polyglucoside and hexadecyl-trimethyl-ammonium bromide, J. Chem. Eng. Data 56(1) (2010) 48-52.

[22] T. Dona, E. Acosta, J.F. Scamehorn, et al., Formulating middle-phase micro-emulsions using mixed anionic and cationic surfactant systems, J. Surf. Deter. 6(3) (2003) 215-224.

[23] H.K. And, R. Aoki, Effect of added salt on the maximum solubilization in an ionicsurfactant micro-emulsion, Langmuir 12(24) (1996) 5796-5799.

Effect of monovalent anions on cationic Gemini micro-emulsion

Effect of monovalent anions on cationic Gemini micro-emulsion

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	Huie Liu, Hongjian Chen, Guanghui Huang, Yunfei Yu, Rujie Li, Shuang Chen. Remediation of oily soil using acidic sophorolipids micro-emulsion[J]. 中国化学工程学报, 2023, 59(7): 270-278.
[2]	Medhat Kamel, Mohamed Hegazy, Salah Rashwan, Mohamed El Kotb. Innovative surfactant of Gemini-type for dissolution mitigation of steel in pickling HCl medium[J]. 中国化学工程学报, 2021, 34(6): 125-133.
[3]	Zoya Zaheer, Ekram Yousif Danish, Samia A. Kosa. 2-Hydroxy-1, 4-napthoquinone solubilization, thermodynamics and adsorption kinetics with surfactant[J]. 中国化学工程学报, 2021, 32(4): 212-223.
[4]	Yinglu Gu, Shuang Chen, Hui'e Liu, Jun Li, Yutong Liu, Long Wang. Remediation of diesel oil contaminated sand by micro-emulsion[J]. 中国化学工程学报, 2020, 28(2): 526-531.
[5]	Hui Jia, Huixin Wang, Kang Ma, Mengxiao Yu, Zhaoyou Zhu, Yinglong Wang. Effect of thermodynamic parameters on prediction of phase behavior and process design of extractive distillation[J]. Chinese Journal of Chemical Engineering, 2018, 26(5): 993-1002.
[6]	Naved Azum, Malik Abdul Rub, Abdullah M. Asiri. Interaction of antipsychotic drug with novel surfactants: Micellization and binding studies[J]. Chinese Journal of Chemical Engineering, 2018, 26(3): 566-573.
[7]	Huma Siddiqui, Mohammad Kamil, Manorama Panda, Kabir-ud-Din. Solubilization of Phenanthrene and Fluorene in Equimolar Binary Mixtures of Gemini/Conventional Surfactants[J]. , 2014, 22(9): 1009-1015.
[8]	Mona Ebrahimi Fakhari, Mostafa Keshavarz Moraveji, Reza Davarnejad. Hydrodynamics and Mass Transfer of Oily Micro-emulsions in An External Loop Airlift Reactor[J]. Chinese Journal of Chemical Engineering, 2014, 22(3): 267-273.
[9]	焦真, 陈志明, 吴有庭, 马少玲. Determination of Paclitaxel Solubility in Carbon Dioxide Using Quartz Crystal Microbalance[J]. , 2011, 19(2): 227-231.
[10]	李进龙, 何清, 何昌春, 彭昌军, 刘洪来. Representation of Phase Behavior of Ionic Liquids Using the Equation of State for Square-well Chain Fluids with Variable Range[J]. , 2009, 17(6): 983-989.
[11]	游晓艳, 秦炜, 戴猷元. Phase Separation Behavior of Cocamidopropyl Betaine/Water/Polyethylene Glycol System[J]. , 2009, 17(5): 746-749.
[12]	赵小芳, 尚亚卓, 刘洪来, 胡英, 姜建文. Interaction of DNA with Cationic Gemini Surfactant Trimethylene-1, 3-bis(dodecyldimethyl-ammonium bromide) and Anionic Surfactant SDS Mixed System[J]. , 2008, 16(6): 923-928.
[13]	徐毅, 冯剑, 尚亚卓, 刘洪来. 连接基团与尾链长度对阳离子Gemini表面活性剂与阴离子聚电解质复合物影响的分子动力学模拟[J]. , 2007, 15(4): 560-565.
[14]	曹维良, 徐金龙, 张敬畅. 超(亚)临界CO₂中涂料基体的相行为研究[J]. , 2003, 11(2): 181-184.
[15]	杨根生, 施介华, 李景华, 王普, 姚善泾. 十二烷基磺酸钠/异辛烷/正构醇/水微乳状液的相行为及其结构转变的研究[J]. , 2002, 10(6): 670-672.