SCI和EI收录∣中国化工学会会刊

中国化学工程学报 ›› 2019, Vol. 27 ›› Issue (6): 1348-1360.DOI: 10.1016/j.cjche.2019.01.001

• Special Issue: Separation Process Intensification of Chemical Engineering • 上一篇    下一篇

Review on structural control and modification of graphene oxide-based membranes in water treatment: From separation performance to robust operation

Ning Zhang1, Wenxu Qi1, Lili Huang1,2, En Jiang1, Junjiang Bao1, Xiaopeng Zhang1, Baigang An2, Gaohong He1   

  1. 1 State Key Laboratory of Fine Chemicals, School of Petroleum and Chemical Engineering, Dalian University of Technology, Panjin 124221, China;
    2 School of Chemical Engineering, University of Science and Technology Liaoning, Anshan 114051, China
  • 收稿日期:2018-11-30 修回日期:2018-12-26 出版日期:2019-06-28 发布日期:2019-08-19
  • 通讯作者: Baigang An, Gaohong He
  • 基金资助:
    Supported by the National Natural Science Foundation of China (Grant Nos. 21506019, 51672118, 51672117), the Fundamental Research Funds for the Central Universities (Grant Nos. DUT16RC(4)80, DUT16QY43), the Program for Changjiang Scholars (T2012049).

Review on structural control and modification of graphene oxide-based membranes in water treatment: From separation performance to robust operation

Ning Zhang1, Wenxu Qi1, Lili Huang1,2, En Jiang1, Junjiang Bao1, Xiaopeng Zhang1, Baigang An2, Gaohong He1   

  1. 1 State Key Laboratory of Fine Chemicals, School of Petroleum and Chemical Engineering, Dalian University of Technology, Panjin 124221, China;
    2 School of Chemical Engineering, University of Science and Technology Liaoning, Anshan 114051, China
  • Received:2018-11-30 Revised:2018-12-26 Online:2019-06-28 Published:2019-08-19
  • Contact: Baigang An, Gaohong He
  • Supported by:
    Supported by the National Natural Science Foundation of China (Grant Nos. 21506019, 51672118, 51672117), the Fundamental Research Funds for the Central Universities (Grant Nos. DUT16RC(4)80, DUT16QY43), the Program for Changjiang Scholars (T2012049).

摘要: Membrane separation has become an important technology to deal with the global water crisis. The polymerbased membrane technology is currently in the forefront of water purification and desalination but is plagued with some bottlenecks. Laminated graphene oxide (GO) membranes exhibit excellent advantages in water purification and desalination due to the single atomic layer structure, hydrophilic property, rich oxygen-containing groups for modification, mechanical and chemical robust, anti-fouling properties, facile and large-scale production, etc. Thus the GO-based membrane technology is believed to offer huge opportunities for efficient and practical water treatment. This review systematically summarizes the current progress on the water flux and selectivity intensification, stability improvement, anti-fouling and anti-biofouling ability enhancement by structural control and modification. To improve the performance of the laminated GO membrane, interlayer spacing tunability and surface modification are mainly used to enhance its water flux and selectivity. It is found that the stability and biofouling also block the service life of the GO membrane. The crosslinking method is found to effectively solve the stability of GO membrane in aqueous environment. Introducing nanoparticles is a widely used method to improve the membrane biofouling ability. Overall, we believe that this review could provide benefit to researchers in the area of GO-based membrane technology for water treatment.

关键词: Membranes, Graphene oxide, Water flux, Selectivity, Stability, Fouling

Abstract: Membrane separation has become an important technology to deal with the global water crisis. The polymerbased membrane technology is currently in the forefront of water purification and desalination but is plagued with some bottlenecks. Laminated graphene oxide (GO) membranes exhibit excellent advantages in water purification and desalination due to the single atomic layer structure, hydrophilic property, rich oxygen-containing groups for modification, mechanical and chemical robust, anti-fouling properties, facile and large-scale production, etc. Thus the GO-based membrane technology is believed to offer huge opportunities for efficient and practical water treatment. This review systematically summarizes the current progress on the water flux and selectivity intensification, stability improvement, anti-fouling and anti-biofouling ability enhancement by structural control and modification. To improve the performance of the laminated GO membrane, interlayer spacing tunability and surface modification are mainly used to enhance its water flux and selectivity. It is found that the stability and biofouling also block the service life of the GO membrane. The crosslinking method is found to effectively solve the stability of GO membrane in aqueous environment. Introducing nanoparticles is a widely used method to improve the membrane biofouling ability. Overall, we believe that this review could provide benefit to researchers in the area of GO-based membrane technology for water treatment.

Key words: Membranes, Graphene oxide, Water flux, Selectivity, Stability, Fouling