Process operation performance of PDMS membrane pervaporation coupled with fermentation for efficient bioethanol production

doi:10.1016/j.cjche.2018.12.005

中国化学工程学报 ›› 2019, Vol. 27 ›› Issue (6): 1339-1347.DOI: 10.1016/j.cjche.2018.12.005

• Special Issue: Separation Process Intensification of Chemical Engineering • 上一篇下一篇

Process operation performance of PDMS membrane pervaporation coupled with fermentation for efficient bioethanol production

Senqing Fan¹, Jingyun Liu¹, Xiaoyu Tang², Wenguo Wang², Zeyi Xiao¹, Boya Qiu¹, Yuyang Wang¹, Shizhao Jian¹, Yangmei Qin¹, Yinan Wang¹

1 School of Chemical Engineering, Sichuan University, Chengdu 610065, China;
2 Biogas Institute of Ministry of Agriculture, Chengdu 610041, China

收稿日期:2018-07-09 修回日期:2018-12-07 出版日期:2019-06-28 发布日期:2019-08-19
通讯作者: Zeyi Xiao
基金资助:
Supported by the National Natural Science Foundation of China (Nos. 20176030, 20276041, 20776088, 21808144), China Postdoctoral Science Foundation (No. 2016M592710), Fundamental Research Funds for the Central Universities (No. 20822041B4013) and Key Laboratory of Development and Application of Rural Renewable Energy, MOA, China (No. 18H0491).

Process operation performance of PDMS membrane pervaporation coupled with fermentation for efficient bioethanol production

Senqing Fan¹, Jingyun Liu¹, Xiaoyu Tang², Wenguo Wang², Zeyi Xiao¹, Boya Qiu¹, Yuyang Wang¹, Shizhao Jian¹, Yangmei Qin¹, Yinan Wang¹

1 School of Chemical Engineering, Sichuan University, Chengdu 610065, China;
2 Biogas Institute of Ministry of Agriculture, Chengdu 610041, China

Received:2018-07-09 Revised:2018-12-07 Online:2019-06-28 Published:2019-08-19
Contact: Zeyi Xiao
Supported by:
Supported by the National Natural Science Foundation of China (Nos. 20176030, 20276041, 20776088, 21808144), China Postdoctoral Science Foundation (No. 2016M592710), Fundamental Research Funds for the Central Universities (No. 20822041B4013) and Key Laboratory of Development and Application of Rural Renewable Energy, MOA, China (No. 18H0491).

摘要/Abstract

摘要： There would be strong product inhibition on ethanol fermentation process if ethanol is not removed in situ from broth. PDMS membrane pervaporation coupled with fermentation is a promising process for efficient bioethanol production since ethanol inhibition is relieved or eliminated. From the perspective of process operation, membrane separation performance, ethanol fermentation performance and the subsequent processing on membrane downstream are the three key issues. This review aims at contributing a comprehensive overview on the operation performance of the integrated process. The state-of-the-art of the three key issues related to the operation performance is focused. Finally, the tentative perspective on the possible future prospects of the integrated process is briefly presented.

关键词: Pervaporation, Membranes, Biofuel, Ethanol recovery, Fermentation broth

Abstract: There would be strong product inhibition on ethanol fermentation process if ethanol is not removed in situ from broth. PDMS membrane pervaporation coupled with fermentation is a promising process for efficient bioethanol production since ethanol inhibition is relieved or eliminated. From the perspective of process operation, membrane separation performance, ethanol fermentation performance and the subsequent processing on membrane downstream are the three key issues. This review aims at contributing a comprehensive overview on the operation performance of the integrated process. The state-of-the-art of the three key issues related to the operation performance is focused. Finally, the tentative perspective on the possible future prospects of the integrated process is briefly presented.

Key words: Pervaporation, Membranes, Biofuel, Ethanol recovery, Fermentation broth

Senqing Fan, Jingyun Liu, Xiaoyu Tang, Wenguo Wang, Zeyi Xiao, Boya Qiu, Yuyang Wang, Shizhao Jian, Yangmei Qin, Yinan Wang. Process operation performance of PDMS membrane pervaporation coupled with fermentation for efficient bioethanol production[J]. 中国化学工程学报, 2019, 27(6): 1339-1347.

参考文献

[1] M. Balat, H. Balat, Recent trends in global production and utilization of bio-ethanol fuel, Appl. Energy 86(2009) 2273-2282.
[2] P.S. Nigam, A. Singh, Production of liquid biofuels from renewable resources, Prog. Energy Combust. 37(2011) 52-68.
[3] J. Baeyens, Q. Kang, L. Appels, R. Dewil, Y. Lv, T. Tan, Challenges and opportunities in improving the production of bio-ethanol, Prog. Energy Combust. 47(2015) 60-88.
[4] C.A. Cardona, O.J. Sanchez, Fuel ethanol production:Process design trends and integration opportunities, Bioresour. Technol. 98(2007) 2415-2457.
[5] Z.-P. Zhao, X.-L. Wang, G.-Y. Zhou, Y. Cao, P. Lu, W.-F. Liu, Hydrolysis kinetics of inulin by imidazole-based acidic ionic liquid in aqueous media and bioethanol fermentation, Chem. Eng. Sci. 151(2016) 16-24.
[6] L.M. Vane, A review of pervaporation for product recovery from biomass fermentation processes, J. Chem. Technol. Biotechnol. 80(2005) 603-629.
[7] L.M. Vane, Separation technologies for the recovery and dehydration of alcohols from fermentation broths, Biofuels Bioprod. Biorefin. 2(2008) 553-588.
[8] X. Cheng, F. Pan, M. Wang, W. Li, Y. Song, G. Liu, H. Yang, B. Gao, H. Wu, Z. Jiang, Hybrid membranes for pervaporation separations, J. Membr. Sci. 541(2017) 329-346.
[9] H.J. Lee, E.J. Cho, Y.G. Kim, I.S. Choi, H.J. Bae, Pervaporative separation of bioethanol using a polydimethylsiloxane/polyetherimide composite hollow-fiber membrane, Bioresour. Technol. 109(2012) 110-115.
[10] W. Wei, S. Xia, G. Liu, X. Dong, W. Jin, N. Xu, Effects of polydimethylsiloxane (PDMS) molecular weight on performance of PDMS/ceramic composite membranes, J. Membr. Sci. 375(2011) 334-344.
[11] F. Xiangli, Y. Chen, W. Jin, N. Xu, Polydimethylsiloxane (PDMS)/ceramic composite membrane with high flux for pervaporation of ethanol-water mixtures, Ind. Eng. Chem. Res. 46(2007) 2224-2230.
[12] J. Zhao, W. Jin, Manipulation of confined structure in alcohol-permselective pervaporation membranes, Chin. J. Chem. Eng. 25(2017) 1616-1626.
[13] L. Li, Z. Xiao, Z. Zhang, S. Tan, Mass transfer kinetics of pervaporation by using composite silicone rubber membrane-convective transportation on membrane surface, J. Chem. Ind. Eng. 53(2002) 1169-1174.
[14] A. Raisi, A. Aroujalian, T. Kaghazchi, A predictive mass transfer model for aroma compounds recovery by pervaporation, J. Food Eng. 95(2009) 305-312.
[15] A. Mafi, A. Raisi, A. Aroujalian, Computational fluid dynamics modeling of mass transfer for aroma compounds recovery from aqueous solutions by hydrophobic pervaporation, J. Food Eng. 119(2013) 46-55.
[16] A. Mafia, A. Raisi, M. Hatam, A. Aroujalian, A mathematical model for mass transfer in hydrophobic pervaporation for organic compounds separation from aqueous solutions, J. Membr. Sci. 423(2012) 175-188.
[17] T. Okada, T. Matsuura, A new transport model for pervaporation, J. Membr. Sci. 59(1991) 133-150.
[18] J.J. Shieh, R.Y.M. Huang, A pseudophase-change solution-diffusion model for pervaporation. I. Single component permeation, Sep. Sci. Technol. 33(1998) 767-785.
[19] P. Peng, B.L. Shi, Y.Q. Lan, A review of membrane materials for ethanol recovery by pervaporation, Sep. Sci. Technol. 46(2011) 234-246.
[20] P. Schaetzel, C. Vauclair, Q.T. Nguyen, R. Bouzerar, A simplified solution-diffusion theory in pervaporation:the total solvent volume fraction model, J. Membr. Sci. 244(2004) 117-127.
[21] F. Qin, S. Li, P. Qin, M.N. Karim, T. Tan, A PDMS membrane with high pervaporation performance for the separation of furfural and its potential in industrial application, Green Chem. 16(2014) 1262-1273.
[22] P. Schaetzel, R. Bouallouche, H.A. Amar, Q.T. Nguyen, B. Riffault, S. Marais, Mass transfer in pervaporation:The key component approximation for the solutiondiffusion model, Desalination 251(2010) 161-166.
[23] Y.L. Zhang, N.E. Benes, R.G.H. Lammertink, Performance study of pervaporation in a microfluidic system for the removal of acetone from water, Chem. Eng. J. 284(2016) 1342-1347.
[24] R. Psaume, P. Aptel, Y. Aurelle, J.C. Mora, J.L. Bersillon, Pervaporation-Importance of concentration polarization in the extraction of trace organics from water, J. Membr. Sci. 36(1988) 373-384.
[25] B. Raghunath, S.T. Hwang, Effect of boundary-layer mass-transfer resistance in the pervaporation of dilute organics, J. Membr. Sci. 65(1992) 147-161.
[26] S. Tan, L. Li, Z. Zhang, Z. Wang, The influence of support layer structure on mass transfer in pervaporation of composite PDMS-PSF membranes, Chem. Eng. J. 157(2010) 304-310.
[27] L. Li, Z. Xiao, S. Tan, L. Pu, Z. Zhang, Composite PDMS membrane with high flux for the separation of organics from water by pervaporation, J. Membr. Sci. 243(2004) 177-187.
[28] H. Yan, J. Li, H.W. Fan, S.L. Ji, G.J. Zhang, Z.G. Zhang, Sonication-enhanced in situ assembly of organic/inorganic hybrid membranes:Evolution of nanoparticle distribution and pervaporation performance, J. Membr. Sci. 481(2015) 94-105.
[29] G.J. Zhang, J. Li, N.X. Wang, H.W. Fan, R. Zhang, G.J. Zhang, S.L. Ji, Enhanced flux of polydimethylsiloxane membrane for ethanol permselective pervaporation via incorporation of MIL-53 particles, J. Membr. Sci. 492(2015) 322-330.
[30] J. Guo, G. Zhang, W. Wu, S. Ji, Z. Qin, Z. Liu, Dynamically formed inner skin hollow fiber polydimethylsiloxane/polysulfone composite membrane for alcohol permselective pervaporation, Chem. Eng. J. 158(2010) 558-565.
[31] A. Yadav, M.L. Lind, X.L. Ma, Y.S. Lin, Nanocomposite silicalite-1/polydimethylsiloxane membranes for pervaporation of ethanol from dilute aqueous solutions, Ind. Eng. Chem. Res. 52(2013) 5207-5212.
[32] H.L. Zhou, J.Q. Zhang, Y.H. Wan, W.Q. Jin, Fabrication of high silicalite-1 content filled PDMS thin composite pervaporation membrane for the separation of ethanol from aqueous solutions, J. Membr. Sci. 524(2017) 1-11.
[33] R.H. Bello, P. Linzmeyer, C.M.B. Franco, O. Souza, N. Sellin, S.H.W. Medeiros, C. Marangoni, Pervaporation of ethanol produced from banana waste, Waste Manag. 34(2014) 1501-1509.
[34] C.Y. Chen, S.H. Long, A.R. Li, G.Q. Xiao, L.Y. Wang, Z.Y. Xiao, Performance comparison of ethanol and butanol production in a continuous and closed-circulating fermentation system with membrane bioreactor, Prep. Biochem. Biotechnol. 47(2017) 254-260.
[35] W.-W. Ding, Y.-T. Wu, X.-Y. Tang, L. Yuan, Z.-Y. Xiao, Continuous ethanol fermentation in a closed-circulating system using an immobilized cell coupled with PDMS membrane pervaporation, J. Chem. Technol. Biotechnol. 86(2011) 82-87.
[36] S. Fan, Z. Xiao, M. Li, Energy efficient of ethanol recovery in pervaporation membrane bioreactor with mechanical vapor compression eliminating the cold traps, Bioresour. Technol. 211(2016) 24-30.
[37] P.V. Naik, S. Kerkhofs, J.A. Martens, I.F.J. Vankelecom, PDMS mixed matrix membranes containing hollow silicalite sphere for ethanol/water separation by pervaporation, J. Membr. Sci. 502(2016) 48-56.
[38] J. Liu, J. Chen, X. Zhan, M. Fang, T. Wang, J. Li, Preparation and characterization of ZSM-5/PDMS hybrid pervaporation membranes:Laboratory results and pilot-scale performance, Sep. Purif. Technol. 150(2015) 257-267.
[39] A. Khan, M. Ali, A. Ilyas, P. Naik, I.F.J. Vankelecom, M.A. Gilani, M.R. Bilad, Z. Sajjad, A.L. Khan, ZIF-67 filled PDMS mixed matrix membranes for recovery of ethanol via pervaporation, Sep. Purif. Technol. 206(2018) 50-58.
[40] Y. Li, L.H. Wee, J.A. Martens, I.F.J. Vankelecom, ZIF-71 as a potential filler to prepare pervaporation membranes for bio-alcohol recovery, J. Mater. Chem. A 2(2014) 10034-10040.
[41] C. Fu, D. Cai, S. Hu, Q. Miao, Y. Wang, P. Qin, Z. Wang, T. Tan, Ethanol fermentation integrated with PDMS composite membrane:An effective process, Bioresour. Technol. 200(2016) 648-657.
[42] S. Xu, H. Zhang, F. Yu, X. Zhao, Y. Wang, Enhanced ethanol recovery of PDMS mixed matrix membranes with hydrophobically modified ZIF-90, Sep. Purif. Technol. 206(2018) 80-89.
[43] E. Shi, W. Huang, Z. Xiao, D. Li, M. Tang, Influence of binding interface between active and support layers in composite PDMS membranes on permeation performance, J. Appl. Polym. Sci. 104(2007) 2468-2477.
[44] X. Tang, R. Wang, Z. Xiao, E. Shi, J. Yang, Preparation and pervaporation performances of fumed-silica-filled polydimethylsiloxane-polyamide (PA) composite membranes, J. Appl. Polym. Sci. 105(2007) 3132-3137.
[45] J.J. Richardson, M. Bjornmalm, F. Caruso, Multilayer assembly. Technology-driven layer-by-layer assembly of nanofilms, Science 348(2015) 411-421.
[46] M.R. Chowdhury, J. Steffes, B.D. Huey, J.R. McCutcheon, 3D printed polyamide membranes for desalination, Science 361(2018) 682-686.
[47] D. Sun, B.-B. Li, Z.-L. Xu, Pervaporation of ethanol/water mixture by organophilic nano-silica filled PDMS composite membranes, Desalination 322(2013) 159-166.
[48] G. Liu, F. Xiangli, W. Wei, S. Liu, W. Jin, Improved performance of PDMS/ceramic composite pervaporation membranes by ZSM-5 homogeneously dispersed in PDMS via a surface graft/coating approach, Chem. Eng. J. 174(2011) 495-503.
[49] C. Xue, Z.-X. Wang, G.-Q. Du, L.-H. Fan, Y. Mu, J.-G. Ren, F.-W. Bai, Integration of ethanol removal using carbon nanotube (CNT)-mixed membrane and ethanol fermentation by self-flocculating yeast for antifouling ethanol recovery, Process Biochem. 51(2016) 1140-1146.
[50] Q. Li, L. Cheng, J. Shen, J. Shi, G. Chen, J. Zhao, J. Duan, G. Liu, W. Jin, Improved ethanol recovery through mixed-matrix membrane with hydrophobic MAF-6 as filler, Sep. Purif. Technol. 178(2017) 105-112.
[51] X. He, T. Wang, Y. Li, J. Chen, J. Li, Fabrication and characterization of micropatterned PDMS composite membranes for enhanced ethanol recovery, J. Membr. Sci. 563(2018) 447-459.
[52] S. Tan, L. Li, Z. Xiao, Y. Wu, Z. Zhang, Pervaporation of alcoholic beverages-The coupling effects between ethanol and aroma compounds, J. Membr. Sci. 264(2005) 129-136.
[53] M. García, M.T. Sanz, S. Beltrán, Separation by pervaporation of ethanol from aqueous solutions and effect of other components present in fermentation broths, J. Chem. Technol. Biotechnol. 84(2009) 1873-1882.
[54] S. Fan, S. Chen, X. Tang, Z. Xiao, Q. Deng, P. Yao, Z. Sun, Y. Zhang, C. Chen, Kinetic model of continuous ethanol fermentation in closed-circulating process with pervaporation membrane bioreactor by Saccharomyces cerevisiae, Bioresour. Technol. 177(2015) 169-175.
[55] S. Chovau, S. Gaykawad, A.J. Straathof, B. Van der Bruggen, Influence of fermentation by-products on the purification of ethanol from water using pervaporation, Bioresour. Technol. 102(2011) 1669-1674.
[56] R.H. Bello, O. Souza, N. Sellin, S.H.W. Medeiros, C. Marangoni, Effect of the microfiltration phase on pervaporation of ethanol produced from banana residues, Proceedings of the 11th International Symposium on Process Systems Engineering, Singapore 2012, pp. 820-824.
[57] S.S. Gaykawad, Y. Zha, P.J. Punt, J.W. van Groenestijn, L.A. van der Wielen, A.J. Straathof, Pervaporation of ethanol from lignocellulosic fermentation broth, Bioresour. Technol. 129(2013) 469-476.
[58] E.A. Fouad, X. Feng, Use of pervaporation to separate butanol from dilute aqueous solutions:Effects of operating conditions and concentration polarization, J. Membr. Sci. 323(2008) 428-435.
[59] C. Chen, Z. Xiao, K. Deng, W. Li, H. Cui, J. Zhang, Pervaporation of high boiling point organic compounds with composite PDMS membrane, Sep. Sci. Technol. 48(2013) 1252-1260.
[60] F. Peng, C. Hu, Z. Jiang, Novel ploy(vinyl alcohol)/carbon nanotube hybrid membranes for pervaporation separation of benzene/cyclohexane mixtures, J. Membr. Sci. 297(2007) 236-242.
[61] L. Liang, J.M. Dickson, J. Jiang, M.A. Brook, Effect of low flow rate on pervaporation of 1,2-dichloroethane with novel polydimethylsiloxane composite membranes, J. Membr. Sci. 231(2004) 71-79.
[62] S. Fan, Z. Xiao, Y. Zhang, X. Tang, C. Chen, W. Li, Q. Deng, P. Yao, Enhanced ethanol fermentation in a pervaporation membrane bioreactor with the convenient permeate vapor recovery, Bioresour. Technol. 155(2014) 229-234.
[63] C. Chen, X. Tang, Z. Xiao, Y. Zhou, Y. Jiang, S. Fu, Ethanol fermentation kinetics in a continuous and closed-circulating fermentation system with a pervaporation membrane bioreactor, Bioresour. Technol. 114(2012) 707-710.
[64] C.H. Fu, D. Cai, S. Hu, Q. Miao, Y. Wang, P.Y. Qin, Z. Wang, T.W. Tan, Ethanol fermentation integrated with PDMS composite membrane:An effective process, Bioresour. Technol. 200(2016) 648-657.
[65] D. Cai, S. Hu, C.J. Chen, Y. Wang, C.W. Zhang, Q. Miao, P.Y. Qin, T.W. Tan, Immobilized ethanol fermentation coupled to pervaporation with silicalite-1/polydimethylsiloxane/polyvinylidene fluoride composite membrane, Bioresour. Technol. 220(2016) 124-131.
[66] W. Sun, W. Jia, C.J. Xia, W.D. Zhang, Z.Q. Ren, Study of in situ ethanol recovery via vapor permeation from fermentation, J. Membr. Sci. 530(2017) 192-200.
[67] D. Cai, Q.Q. Zhu, C.J. Chen, S. Hu, P.Y. Qin, B. Wang, T.W. Tan, Fermentationpervaporation-catalysis integration process for bio-butadiene production using sweet sorghum juice as feedstock, J. Taiwan Inst. Chem. Eng. 82(2018) 137-143.
[68] D.J. O'Brien, G.E. Senske, M.J. Kurantz, J.C. Craig, Ethanol recovery from corn fiber hydrolysate fermentations by pervaporation, Bioresour. Technol. 92(2004) 15-19.
[69] C.Y. Chen, X.Y. Tang, Z.Y. Xiao, Y.H. Zhou, Y. Jiang, S.W. Fu, Adaptive evolution of Saccharomyces cerevisiae in a continuous and closed circulating fermentation (CCCF) system coupled with PDMS membrane pervaporation, Appl. Biochem. Biotechnol. 169(2013) 2362-2373.
[70] W. Ding, Z. Xiao, X. Tang, K. Deng, S. Fu, Y. Jiang, L. Yuan, Evolutionary engineering of yeast for closed-circulating ethanol fermentation in PDMS membrane bioreactor, Biochem. Eng. J. 60(2012) 56-61.
[71] S. Fan, Z. Xiao, X. Tang, C. Chen, Y. Zhang, Q. Deng, P. Yao, W. Li, Inhibition effect of secondary metabolites accumulated in a pervaporation membrane bioreactor on ethanol fermentation of Saccharomyces cerevisiae, Bioresour. Technol. 162(2014) 8-13.
[72] S. Xue, A.D. Jones, L. Sousa, J. Piotrowski, M. Jin, C. Sarks, B.E. Dale, V. Balan, Watersoluble phenolic compounds produced from extractive ammonia pretreatment exerted binary inhibitory effects on yeast fermentation using synthetic hydrolysate, PLoS One 13(3) (2018), e0194012.
[73] H.B. Klinke, A.B. Thomsen, B.K. Ahring, Inhibition of ethanol-producing yeast and bacteria by degradation products produced during pre-treatment of biomass, Appl. Microbiol. Biotechnol. 66(2004) 10-26.
[74] C. Bellido, S. Bolado, M. Coca, S. Lucas, G. González-Benito, M.T. García-Cubero, Effect of inhibitors formed during wheat straw pretreatment on ethanol fermentation by Pichia stipitis, Bioresour. Technol. 102(2011) 10868-10874.
[75] S. Fan, Z. Xiao, M. Li, S. Li, Pervaporation membrane bioreactor with permeate fractional condensation and mechanical vapor compression for energy efficient ethanol production, Appl. Energy 179(2016) 939-947.
[76] V. LM, A. FR, M. AP, B. RW, Separation of vapor-phase alcohol/water mixtures via fractional condensation using a pilot-scale dephlegmator:enhancement of the pervaporation process separation factor, Ind. Eng. Chem. Res. 43(2004) 173-183.
[77] S. Fan, Z. Xiao, M. Li, S. Li, T. Zhou, Y. Hu, S. Wu, Pervaporation performance in PDMS membrane bioreactor for ethanol recovery with running water and air as coolants at room temperature, J. Chem. Technol. Biotechnol. 92(2017) 292-297.
[78] W.-C. Chen, C.-T. Sheng, Y.-C. Liu, W.-J. Chen, W.-L. Huang, S.-H. Chang, W.-C. Chang, Optimizing the efficiency of anhydrous ethanol purification via regenerable molecular sieve, Appl. Energy 135(2014) 483-489.

Process operation performance of PDMS membrane pervaporation coupled with fermentation for efficient bioethanol production

Process operation performance of PDMS membrane pervaporation coupled with fermentation for efficient bioethanol production

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	Xinxin Li, Hongwei Shao, Shichao Zhang, Yong Li, Jingjing Gu, Qiang Huang, Jin Ran. Two dimensional MoS₂ finding its way towards constructing high-performance alkaline recovery membranes[J]. 中国化学工程学报, 2023, 60(8): 155-164.
[2]	Wenwen Zhang, Zhigang Xue, Liyun Cui, Haoliang Gao, Di Zhao, Rongfei Zhou, Weihong Xing. Synthesis of an IMF zeolite membrane for the separation of xylene isomer[J]. 中国化学工程学报, 2023, 60(8): 205-211.
[3]	Hammad Saulat, Jianhua Yang, Tao Yan, Waseem Raza, Wensen Song, Gaohong He. Tungsten incorporated mobil-type eleven zeolite membranes: Facile synthesis and tuneable wettability for highly efficient separation of oil/water mixtures[J]. 中国化学工程学报, 2023, 60(8): 242-252.
[4]	Meihua Zhu, Xingguo An, Tian Gui, Ting Wu, Yuqin Li, Xiangshu Chen. Effects of ion-exchange on the pervaporation performance and microstructure of NaY zeolite membrane[J]. 中国化学工程学报, 2023, 59(7): 176-181.
[5]	Jiajia Chen, Xinyu Lu, Dandan Wang, Pengcheng Xiu, Xiaoli Gu. Effective depolymerization of alkali lignin using an attapulgite-Ce_0.75Zr_0.25O₂(ATP-CZO)-supported cobalt catalyst in ethanol/isopropanol media[J]. 中国化学工程学报, 2023, 57(5): 50-62.
[6]	Xingzhong Li, Kunlin Yu, Zibo He, Bo Liu, Rongfei Zhou, Weihong Xing. Improved SSZ-13 thin membranes fabricated by seeded-gel approach for efficient CO₂ capture[J]. 中国化学工程学报, 2023, 56(4): 273-280.
[7]	Tutuk Djoko Kusworo, Monica Yulfarida, Andri Cahyo Kumoro, Dani Puji Utomo. Purification of bioethanol fermentation broth using hydrophilic PVA crosslinked PVDF-GO/TiO₂ membrane[J]. 中国化学工程学报, 2023, 55(3): 123-136.
[8]	Xi Zhang, Xiaodong Wang, Wei Huang. Separation of a C₃H₆/C₂H₄ mixture using Pebax^® 2533/PEG600 blend membranes[J]. 中国化学工程学报, 2023, 54(2): 192-198.
[9]	Qinggang Xu, Yasen Dai, Qing Zhao, Zhengrun Chen, Peizhe Cui, Zhaoyou Zhu, Yinglong Wang, Jun Gao, Yixin Ma. Economy, environmental assessment and energy conservation for separation of isopropanol/diisopropyl ether/water multi-azeotropes via extractive distillation coupled pervaporation process[J]. 中国化学工程学报, 2023, 54(2): 353-363.
[10]	Monique Juna L. Leite, Ingrid Ramalho Marques, Mariane Carolina Proner, Pedro H.H. Araújo, Alan Ambrosi, Marco Di Luccio. Catalytically active membranes for esterification: A review[J]. 中国化学工程学报, 2023, 53(1): 142-154.
[11]	Lin-Bing Zou, Jue-Ying Gong, Xiao-Jie Ju, Zhuang Liu, Wei Wang, Rui Xie, Liang-Yin Chu. Smart membranes for biomedical applications[J]. 中国化学工程学报, 2022, 49(9): 34-45.
[12]	Sihan Huang, Yaohan Chen, Xue Wang, Jing Guo, Yonggang Li, Lei Dai, Shenghai Li, Suobo Zhang. Preparation of antifouling ultrafiltration membranes from copolymers of polysulfone and zwitterionic poly(arylene ether sulfone)s[J]. 中国化学工程学报, 2022, 49(9): 100-110.
[13]	Ping Zhang, Chao Gong, Tao Zhou, Peng Du, Jieyu Song, Mengyang Shi, Xuerui Wang, Xuehong Gu. Helium extraction from natural gas using DD3R zeolite membranes[J]. 中国化学工程学报, 2022, 49(9): 122-129.
[14]	Juanjuan Liu, Xiaolong Lu, Guiming Shu, Ke Li, Shuyun Zheng, Xiao Kong, Tao Li, Jun Yang. The facile method developed for preparing polyvinylidene fluoride plasma separation membrane via macromolecular interaction[J]. 中国化学工程学报, 2022, 49(9): 140-149.
[15]	Xing Zhang, Jingfeng Wu, Junhao Chen, Liang Lu, Lingjun Zhu, Shurong Wang. Production of aromatic hydrocarbons by co-cracking of bio-oil and ethanol over Ga₂O₃/HZSM-5 catalysts[J]. 中国化学工程学报, 2022, 46(6): 126-133.