Bio-synthesized palladium nanoparticles using alginate for catalytic degradation of azo-dyes

doi:10.1016/j.cjche.2020.02.014

中国化学工程学报 ›› 2020, Vol. 28 ›› Issue (5): 1334-1343.DOI: 10.1016/j.cjche.2020.02.014

• Catalysis, Kinetics and Reaction Engineering • 上一篇下一篇

Bio-synthesized palladium nanoparticles using alginate for catalytic degradation of azo-dyes

Yi Xiong¹, Liping Huang¹, Sakil Mahmud^1,2,3, Feng Yang¹, Huihong Liu¹

1 College of Chemistry and Chemical Engineering, Hubei Key Laboratory of Biomass Fibers and Eco-dyeing&Finishing, Wuhan Textile University, Wuhan 430200, China;
2 Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, China;
3 University of Chinese Academy of Sciences, Beijing 100049, China

收稿日期:2019-10-18 修回日期:2019-12-23 出版日期:2020-05-28 发布日期:2020-07-29
通讯作者: Sakil Mahmud, Huihong Liu
基金资助:
The authors thank the kind support of this work from Key Laboratory of Biomass Fibers & Eco-Dyeing & Finishing, Hubei Province (STRZ2019015) and the Innovation Platform Projects of Wuhan Textile University (183052).

Bio-synthesized palladium nanoparticles using alginate for catalytic degradation of azo-dyes

Yi Xiong¹, Liping Huang¹, Sakil Mahmud^1,2,3, Feng Yang¹, Huihong Liu¹

1 College of Chemistry and Chemical Engineering, Hubei Key Laboratory of Biomass Fibers and Eco-dyeing&Finishing, Wuhan Textile University, Wuhan 430200, China;
2 Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, China;
3 University of Chinese Academy of Sciences, Beijing 100049, China

Received:2019-10-18 Revised:2019-12-23 Online:2020-05-28 Published:2020-07-29
Contact: Sakil Mahmud, Huihong Liu
Supported by:
The authors thank the kind support of this work from Key Laboratory of Biomass Fibers & Eco-Dyeing & Finishing, Hubei Province (STRZ2019015) and the Innovation Platform Projects of Wuhan Textile University (183052).

摘要/Abstract

摘要： Palladium nanoparticles (PdNPs) were synthesized in a green way using sodium alginate functioning as both reductant and stabilizer. The formation of as-synthesized PdNPs was supervised by Ultraviolet-visible (UV-Vis) spectroscopy and confirmed by the surface plasmon resonance (SPR) band. The effect of several synthesis factors such as precursor ratio, solution pH, reaction time, and temperature were investigated by the factorial design of experiments in order to optimize the experimental conditions. The optimal synthesis parameters were achieved by heating 1.0 ml of 1.0% sodium alginate (SA), 3.0 ml of 10^-2 mol·L^-1 H₂PdCl₄ at 80℃ for a period of 30 min in a neutral reaction medium (pH=6). High-resolution transmission electron microscope (HRTEM), energy dispersive X-ray (EDX) spectroscopy, selected area electron diffraction (SAED) pattern, X-ray powder diffraction (XRD), and dynamic light scattering (DLS) were used to confirm the uniform spherical shapes and high crystallinity of PdNPs with average particle size of (2.12 ±1.42) nm. The SEM images show the distribution of PdNPs presented among the SA. FTIR spectra indicate that SA is a good capping agent to stabilize PdNPs for a long time. The catalytic degradation of model azo-dyes such as mono-azo (Cibacron Yellow FN-2R) and di-azo (Cibacron Deep Red S-B) were confirmed the catalytic activity of PdNPs. The PdNPs can accelerate the degradation rate by more than 80 and 10 times respectively as confirmed by kinetics constant (k) values.

关键词: Palladium nanoparticles, sodium alginate, Green synthesis, Azo dyes, Catalysis

Abstract: Palladium nanoparticles (PdNPs) were synthesized in a green way using sodium alginate functioning as both reductant and stabilizer. The formation of as-synthesized PdNPs was supervised by Ultraviolet-visible (UV-Vis) spectroscopy and confirmed by the surface plasmon resonance (SPR) band. The effect of several synthesis factors such as precursor ratio, solution pH, reaction time, and temperature were investigated by the factorial design of experiments in order to optimize the experimental conditions. The optimal synthesis parameters were achieved by heating 1.0 ml of 1.0% sodium alginate (SA), 3.0 ml of 10^-2 mol·L^-1 H₂PdCl₄ at 80℃ for a period of 30 min in a neutral reaction medium (pH=6). High-resolution transmission electron microscope (HRTEM), energy dispersive X-ray (EDX) spectroscopy, selected area electron diffraction (SAED) pattern, X-ray powder diffraction (XRD), and dynamic light scattering (DLS) were used to confirm the uniform spherical shapes and high crystallinity of PdNPs with average particle size of (2.12 ±1.42) nm. The SEM images show the distribution of PdNPs presented among the SA. FTIR spectra indicate that SA is a good capping agent to stabilize PdNPs for a long time. The catalytic degradation of model azo-dyes such as mono-azo (Cibacron Yellow FN-2R) and di-azo (Cibacron Deep Red S-B) were confirmed the catalytic activity of PdNPs. The PdNPs can accelerate the degradation rate by more than 80 and 10 times respectively as confirmed by kinetics constant (k) values.

Key words: Palladium nanoparticles, sodium alginate, Green synthesis, Azo dyes, Catalysis

Yi Xiong, Liping Huang, Sakil Mahmud, Feng Yang, Huihong Liu. Bio-synthesized palladium nanoparticles using alginate for catalytic degradation of azo-dyes[J]. 中国化学工程学报, 2020, 28(5): 1334-1343.

Yi Xiong, Liping Huang, Sakil Mahmud, Feng Yang, Huihong Liu. Bio-synthesized palladium nanoparticles using alginate for catalytic degradation of azo-dyes[J]. Chinese Journal of Chemical Engineering, 2020, 28(5): 1334-1343.

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Bio-synthesized palladium nanoparticles using alginate for catalytic degradation of azo-dyes

Bio-synthesized palladium nanoparticles using alginate for catalytic degradation of azo-dyes

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