Reactive extraction for synthesizing long chain ester butyl hexanoate intensified by deep eutectic solvent

doi:10.1016/j.cjche.2020.10.005

中国化学工程学报 ›› 2021, Vol. 36 ›› Issue (8): 120-127.DOI: 10.1016/j.cjche.2020.10.005

• Catalysis, Kinetics and Reaction Engineering • 上一篇下一篇

Reactive extraction for synthesizing long chain ester butyl hexanoate intensified by deep eutectic solvent

Yishan Zhou^1,2, Hao Qin¹, Hongye Cheng¹, Lifang Chen¹, Bingjian Zhang², Zhiwen Qi¹

1 State Key Laboratory of Chemical Engineering, School of Chemical Engineering, East China University of Science and Technology, Shanghai 200237, China;
2 Key Laboratory of Low-carbon Chemistry & Energy Conservation of Guangdong Province, Sun Yat-sen University, Guangzhou 510275, China

收稿日期:2020-07-16 修回日期:2020-09-11 出版日期:2021-08-28 发布日期:2021-09-30
通讯作者: Hao Qin, Zhiwen Qi
基金资助:
The financial support from National Natural Science Foundation of China (21776074 and 21576081) is greatly acknowledged.

Reactive extraction for synthesizing long chain ester butyl hexanoate intensified by deep eutectic solvent

Yishan Zhou^1,2, Hao Qin¹, Hongye Cheng¹, Lifang Chen¹, Bingjian Zhang², Zhiwen Qi¹

1 State Key Laboratory of Chemical Engineering, School of Chemical Engineering, East China University of Science and Technology, Shanghai 200237, China;
2 Key Laboratory of Low-carbon Chemistry & Energy Conservation of Guangdong Province, Sun Yat-sen University, Guangzhou 510275, China

Received:2020-07-16 Revised:2020-09-11 Online:2021-08-28 Published:2021-09-30
Contact: Hao Qin, Zhiwen Qi
Supported by:
The financial support from National Natural Science Foundation of China (21776074 and 21576081) is greatly acknowledged.

摘要/Abstract

摘要： Butyl hexanoate (BuHE) is an important long-chain ester that is widely used in the food, beverage and cosmetic industries. In this work, reactive extraction concept was proposed to intensify the BuHE formation in a biphasic system, in which deep eutectic solvent (DES) comprising 2-methylimidazole (2-MIm) and p-toluenesulfonic acid (PTSA) was used as dual solvent-catalyst. First, the effect of 2-MIm to PTSA molar ratio on esterification was investigated to determine the optimum DES of[2-MIm:2PTSA], which was characterized by FT-IR and TGA. Then, the liquid-liquid equilibrium (LLE) and esterification experiments were carried out to confirm the extraction and catalytic effect of[2-MIm:2PTSA], respectively. Afterwards, the pseudo-homogeneous kinetic model was employed to describe the esterification kinetics. Finally, the intensification mechanism of reactive extraction for BuHE formation was proposed according to the experiments and interaction effect analysis.

关键词: Esterification, Reactive extraction, Deep eutectic solvent, Catalysis effect, Solvent effect, Pseudo-homogeneous kinetic model

Abstract: Butyl hexanoate (BuHE) is an important long-chain ester that is widely used in the food, beverage and cosmetic industries. In this work, reactive extraction concept was proposed to intensify the BuHE formation in a biphasic system, in which deep eutectic solvent (DES) comprising 2-methylimidazole (2-MIm) and p-toluenesulfonic acid (PTSA) was used as dual solvent-catalyst. First, the effect of 2-MIm to PTSA molar ratio on esterification was investigated to determine the optimum DES of[2-MIm:2PTSA], which was characterized by FT-IR and TGA. Then, the liquid-liquid equilibrium (LLE) and esterification experiments were carried out to confirm the extraction and catalytic effect of[2-MIm:2PTSA], respectively. Afterwards, the pseudo-homogeneous kinetic model was employed to describe the esterification kinetics. Finally, the intensification mechanism of reactive extraction for BuHE formation was proposed according to the experiments and interaction effect analysis.

Key words: Esterification, Reactive extraction, Deep eutectic solvent, Catalysis effect, Solvent effect, Pseudo-homogeneous kinetic model

Yishan Zhou, Hao Qin, Hongye Cheng, Lifang Chen, Bingjian Zhang, Zhiwen Qi. Reactive extraction for synthesizing long chain ester butyl hexanoate intensified by deep eutectic solvent[J]. 中国化学工程学报, 2021, 36(8): 120-127.

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Reactive extraction for synthesizing long chain ester butyl hexanoate intensified by deep eutectic solvent

Reactive extraction for synthesizing long chain ester butyl hexanoate intensified by deep eutectic solvent

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