Preparation of Pd/γ-Al2O3/nickel foam monolithic catalyst and its performance for selective hydrogenation in a rotating packed bed reactor

doi:10.1016/j.cjche.2021.08.026

中国化学工程学报 ›› 2022, Vol. 41 ›› Issue (1): 311-319.DOI: 10.1016/j.cjche.2021.08.026

• Catalysis, Kinetics and Reaction Engineering • 上一篇下一篇

Preparation of Pd/γ-Al₂O₃/nickel foam monolithic catalyst and its performance for selective hydrogenation in a rotating packed bed reactor

Hai-Long Liao, Bao-Ju Wang, Ya-Zhao Liu, Yong Luo, Jie-Xin Wang, Guang-Wen Chu, Jian-Feng Chen

State Key Laboratory of Organic-Inorganic Composites, Beijing University of Chemical Technology, Beijing 100029, China;Research Center of the Ministry of Education for High Gravity Engineering and Technology, Beijing University of Chemical Technology, Beijing 100029, China

收稿日期:2021-05-17 修回日期:2021-08-25 出版日期:2022-01-28 发布日期:2022-02-25
通讯作者: Yong Luo,E-mail address:luoyong@mail.buct.edu.cn;Jian-Feng Chen,E-mail address:chenjf@mail.buct.edu.cn
基金资助:
This work was supported by the National Natural Science Foundation of China (22022802 and 91934303).

Preparation of Pd/γ-Al₂O₃/nickel foam monolithic catalyst and its performance for selective hydrogenation in a rotating packed bed reactor

Hai-Long Liao, Bao-Ju Wang, Ya-Zhao Liu, Yong Luo, Jie-Xin Wang, Guang-Wen Chu, Jian-Feng Chen

State Key Laboratory of Organic-Inorganic Composites, Beijing University of Chemical Technology, Beijing 100029, China;Research Center of the Ministry of Education for High Gravity Engineering and Technology, Beijing University of Chemical Technology, Beijing 100029, China

Received:2021-05-17 Revised:2021-08-25 Online:2022-01-28 Published:2022-02-25
Contact: Yong Luo,E-mail address:luoyong@mail.buct.edu.cn;Jian-Feng Chen,E-mail address:chenjf@mail.buct.edu.cn
Supported by:
This work was supported by the National Natural Science Foundation of China (22022802 and 91934303).

摘要/Abstract

摘要： Selective hydrogenation plays an important role in chemical industries, yet its selectivity is usually limited by the mass transfer. In this work, the enhanced hydrogenation selectivity was achieved in a rotating packed bed (RPB) reactor with excellent mass transfer efficiency. Aiming to be used under the centrifugal filed, a monolithic catalyst Pd/γ-Al₂O₃/nickel foam suiting for the shape and size of the rotor of RPB reactor was prepared by the electrophoretic deposition method. The mechanical strength of the catalyst can meet the requirement of high centrifugal force in the RPB. The hydrogenation selectivity in the RPB reactor using the 3-methyl-1-pentyn-3-ol hydrogenation system was 3–8 times higher than that in a stirred tank reactor under similar conditions. This work proves the feasibility of intensifying the selectivity of hydrogenation process in the RPB reactor.

关键词: Monolithic catalyst, Rotating packed bed reactor, Hydrogenation, Selectivity

Abstract: Selective hydrogenation plays an important role in chemical industries, yet its selectivity is usually limited by the mass transfer. In this work, the enhanced hydrogenation selectivity was achieved in a rotating packed bed (RPB) reactor with excellent mass transfer efficiency. Aiming to be used under the centrifugal filed, a monolithic catalyst Pd/γ-Al₂O₃/nickel foam suiting for the shape and size of the rotor of RPB reactor was prepared by the electrophoretic deposition method. The mechanical strength of the catalyst can meet the requirement of high centrifugal force in the RPB. The hydrogenation selectivity in the RPB reactor using the 3-methyl-1-pentyn-3-ol hydrogenation system was 3–8 times higher than that in a stirred tank reactor under similar conditions. This work proves the feasibility of intensifying the selectivity of hydrogenation process in the RPB reactor.

Key words: Monolithic catalyst, Rotating packed bed reactor, Hydrogenation, Selectivity

Hai-Long Liao, Bao-Ju Wang, Ya-Zhao Liu, Yong Luo, Jie-Xin Wang, Guang-Wen Chu, Jian-Feng Chen. Preparation of Pd/γ-Al₂O₃/nickel foam monolithic catalyst and its performance for selective hydrogenation in a rotating packed bed reactor[J]. 中国化学工程学报, 2022, 41(1): 311-319.

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Preparation of Pd/γ-Al₂O₃/nickel foam monolithic catalyst and its performance for selective hydrogenation in a rotating packed bed reactor

Preparation of Pd/γ-Al₂O₃/nickel foam monolithic catalyst and its performance for selective hydrogenation in a rotating packed bed reactor

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