The effect of protic ionic liquids incorporation on CO2 separation performance of Pebax-based membranes

doi:10.1016/j.cjche.2022.02.006

中国化学工程学报 ›› 2022, Vol. 43 ›› Issue (3): 169-176.DOI: 10.1016/j.cjche.2022.02.006

The effect of protic ionic liquids incorporation on CO₂ separation performance of Pebax-based membranes

Haiyan Jiang^1,2, Lu Bai¹, Bingbing Yang¹, Shaojuan Zeng¹, Haifeng Dong^1,3, Xiangping Zhang^1,3

1. CAS Key Laboratory of Green Process and Engineering, State Key Laboratory of Multiphase Complex Systems, Beijing Key Laboratory of Ionic Liquids Clean Process, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China;
2. School of Future Technology, University of Chinese Academy of Sciences, Beijing 100049, China;
3. Advanced Energy Science and Technology Guangdong Laboratory, Huizhou 516003, China

收稿日期:2021-08-25 修回日期:2022-02-11 出版日期:2022-03-28 发布日期:2022-04-28
通讯作者: Lu Bai,E-mail:lbai1207@ipe.ac.cn;Xiangping Zhang,E-mail:xpzhang@ipe.ac.cn
基金资助:
This work was supported by the National Key R&D Program of China (2020YFA0710200), the Science Fund for Creative Research Groups of the National Natural Science Foundation of China (21921005), the Major Scientific and Technological Project of Shanxi Province of China (20201102005), the Youth Innovation Promotion Association of the Chinese Academy of Sciences (2020047) and the Innovation Academy for Green Manufacture, Chinese Academy of Sciences (IAGM2020C15).

The effect of protic ionic liquids incorporation on CO₂ separation performance of Pebax-based membranes

Haiyan Jiang^1,2, Lu Bai¹, Bingbing Yang¹, Shaojuan Zeng¹, Haifeng Dong^1,3, Xiangping Zhang^1,3

1. CAS Key Laboratory of Green Process and Engineering, State Key Laboratory of Multiphase Complex Systems, Beijing Key Laboratory of Ionic Liquids Clean Process, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China;
2. School of Future Technology, University of Chinese Academy of Sciences, Beijing 100049, China;
3. Advanced Energy Science and Technology Guangdong Laboratory, Huizhou 516003, China

Received:2021-08-25 Revised:2022-02-11 Online:2022-03-28 Published:2022-04-28
Contact: Lu Bai,E-mail:lbai1207@ipe.ac.cn;Xiangping Zhang,E-mail:xpzhang@ipe.ac.cn
Supported by:
This work was supported by the National Key R&D Program of China (2020YFA0710200), the Science Fund for Creative Research Groups of the National Natural Science Foundation of China (21921005), the Major Scientific and Technological Project of Shanxi Province of China (20201102005), the Youth Innovation Promotion Association of the Chinese Academy of Sciences (2020047) and the Innovation Academy for Green Manufacture, Chinese Academy of Sciences (IAGM2020C15).

摘要/Abstract

摘要： The separation of carbon dioxide (CO₂) is of great importance for environment protection and gas resource purification. The ionic liquids (ILs)-based gas separation membrane provides a new chance for efficient CO₂ separation, while high permeability and selectivity of membranes is a great challenge. In this study, the influence of two protic ILs with different anion ([TMGH][Im] and [TMGH][PhO]) on the CO₂ separation performance of the prepared ILs/Pebax blended membranes were systematically investigated at different temperature. The results showed the CO₂ permeability exhibits the rising trend for ILs/Pebax blended membranes with the increment of IL content. Especially, the [TMGH][Im] with low viscosity and high CO₂ absorption capacity leads to the blended membranes showing better CO₂ permeability and ideal CO₂ selectivity than that of membranes with [TMGH][PhO] at high IL content. Besides, with operating temperature increasing, the gas permeability of 20% (mass) [TMGH][Im]/Pebax blended membrane increases due to the decreasing viscosity of IL and the rising chain mobility of polymer. Inversely, the gas selectivity shows decreasing trend because CO₂ absorption capacity obviously decreased at higher temperature.

关键词: CO₂, Protic ionic liquids, Membranes, Pebax

Abstract: The separation of carbon dioxide (CO₂) is of great importance for environment protection and gas resource purification. The ionic liquids (ILs)-based gas separation membrane provides a new chance for efficient CO₂ separation, while high permeability and selectivity of membranes is a great challenge. In this study, the influence of two protic ILs with different anion ([TMGH][Im] and [TMGH][PhO]) on the CO₂ separation performance of the prepared ILs/Pebax blended membranes were systematically investigated at different temperature. The results showed the CO₂ permeability exhibits the rising trend for ILs/Pebax blended membranes with the increment of IL content. Especially, the [TMGH][Im] with low viscosity and high CO₂ absorption capacity leads to the blended membranes showing better CO₂ permeability and ideal CO₂ selectivity than that of membranes with [TMGH][PhO] at high IL content. Besides, with operating temperature increasing, the gas permeability of 20% (mass) [TMGH][Im]/Pebax blended membrane increases due to the decreasing viscosity of IL and the rising chain mobility of polymer. Inversely, the gas selectivity shows decreasing trend because CO₂ absorption capacity obviously decreased at higher temperature.

Key words: CO₂, Protic ionic liquids, Membranes, Pebax

Haiyan Jiang, Lu Bai, Bingbing Yang, Shaojuan Zeng, Haifeng Dong, Xiangping Zhang. The effect of protic ionic liquids incorporation on CO₂ separation performance of Pebax-based membranes[J]. 中国化学工程学报, 2022, 43(3): 169-176.

参考文献

[1] L. Jeffry, M.Y. Ong, S. Nomanbhay, M. Mofijur, M. Mubashir, P.L. Show, Greenhouse gases utilization:A review, Fuel 301 (2021) 121017
[2] Z.D. Dai, L. Ansaloni, L.Y. Deng, Recent advances in multi-layer composite polymeric membranes for CO₂ separation:A review, Green Energy Environ. 1 (2) (2016) 102-128
[3] R.M. Lilleby Helberg, Z.D. Dai, L. Ansaloni, L.Y. Deng, PVA/PVP blend polymer matrix for hosting carriers in facilitated transport membranes:Synergistic enhancement of CO₂ separation performance, Green Energy Environ. 5 (1) (2020) 59-68
[4] L.H. Dai, K. Huang, Y.S. Xia, Z. Xu, Two-dimensional material separation membranes for renewable energy purification, storage, and conversion, Green Energy Environ. 6 (2) (2021) 193-211
[5] D.S. Sholl, R.P. Lively, Seven chemical separations to change the world, Nature 532 (7600) (2016) 435-437
[6] A. Brunetti, F. Scura, G. Barbieri, E. Drioli, Membrane technologies for CO₂ separation, J. Membr. Sci. 359 (1-2) (2010) 115-125
[7] O. Selyanchyn, R. Selyanchyn, S. Fujikawa, Critical role of the molecular interface in double-layered pebax-1657/PDMS nanomembranes for highly efficient CO₂/N₂ gas separation, ACS Appl. Mater. Interfaces 12 (29) (2020) 33196-33209
[8] T.Y. Zhu, X. Yang, Y.Y. Zheng, X.Q. He, F.F. Chen, J.J. Luo, Preparation of poly(ether-block-amide)/poly(amide-co-poly(propylene glycol)) random copolymer blend membranes for CO₂/N₂ separation, Polym. Eng. Sci. 59 (S1) (2019) E14-E23
[9] A. Atash Jameh, T. Mohammadi, O. Bakhtiari, Preparation of PEBAX-1074/modified ZIF-8 nanoparticles mixed matrix membranes for CO₂ removal from natural gas, Sep. Purif. Technol. 231 (2020) 115900
[10] R. Casadei, M. Giacinti Baschetti, M.J. Yoo, H.B. Park, L. Giorgini, Pebax^® 2533/graphene oxide nanocomposite membranes for carbon capture, Membranes 10 (8) (2020) 188
[11] S. Meshkat, S. Kaliaguine, D. Rodrigue, Mixed matrix membranes based on amine and non-amine MIL-53(Al) in Pebax^® MH-1657 for CO₂ separation, Sep. Purif. Technol. 200 (2018) 177-190
[12] D. Zhao, J.Z. Ren, Y. Wang, Y.T. Qiu, H. Li, K.S. Hua, X.X. Li, J.M. Ji, M.C. Deng, High CO₂ separation performance of Pebax^®/CNTs/GTA mixed matrix membranes, J. Membr. Sci. 521 (2017) 104-113
[13] L.M. Robeson, The upper bound revisited, J. Membr. Sci. 320 (1-2) (2008) 390-400
[14] K. Wang, H.J. Xu, C. Yang, T. Qiu, Machine learning-based ionic liquids design and process simulation for CO₂ separation from flue gas, Green Energy Environ. 6 (3) (2021) 432-443
[15] Y.X. Wu, J.H. Xu, K. Mumford, G.W. Stevens, W.Y. Fei, Y.D. Wang, Recent advances in carbon dioxide capture and utilization with amines and ionic liquids, Green Chem. Eng. 1 (1) (2020) 16-32
[16] X.M. Zhang, W.J. Xiong, L.L. Peng, Y.T. Wu, X.B. Hu, Highly selective absorption separation of H₂ S and CO₂ from CH₄ by novel azole-based protic ionic liquids, Aiche J. 66 (6) (2020):e16936
[17] D.M. Correia, L.C. Fernandes, P.M. Martins, C. García-Astrain, C.M. Costa, J. Reguera, S. Lanceros-Méndez, Ionic liquid-polymer composites:A new platform for multifunctional applications, Adv. Funct. Mater. 30 (24) (2020) 1909736
[18] M. Zia ul Mustafa, H. bin Mukhtar, N.A.H. Md Nordin, H.A. Mannan, R. Nasir, N. Fazil, Recent developments and applications of ionic liquids in gas separation membranes, Chem. Eng. Technol. 42 (12) (2019) 2580-2593
[19] J.F. Wang, J.Q. Luo, S.C. Feng, H.R. Li, Y.H. Wan, X.P. Zhang, Recent development of ionic liquid membranes, Green Energy Environ. 1 (1) (2016) 43-61
[20] I.K. Swati, Q. Sohaib, S.Y. Cao, M. Younas, D. Liu, J.Z. Gui, M. Rezakazemi, Protic/aprotic ionic liquids for effective CO₂ separation using supported ionic liquid membrane, Chemosphere 267 (2021) 128894
[21] A. Ito, T. Yasuda, T. Yoshioka, A. Yoshida, X. Li, K. Hashimoto, K. Nagai, M. Shibayama, M. Watanabe, Sulfonated polyimide/ionic liquid composite membranes for CO₂ separation:Transport properties in relation to their nanostructures, Macromolecules 51 (18) (2018) 7112-7120
[22] Z.X. Guo, W.J. Zheng, X.M. Yan, Y. Dai, X.H. Ruan, X.C. Yang, X.C. Li, N. Zhang, G.H. He, Ionic liquid tuning nanocage size of MOFs through a two-step adsorption/infiltration strategy for enhanced gas screening of mixed-matrix membranes, J. Membr. Sci. 605 (2020) 118101
[23] R. Zhao, H. Wu, L.X. Yang, Y.X. Ren, Y.T. Liu, Z.H. Qu, Y.Z. Wu, L. Cao, Z. Chen, Z.Y. Jiang, Modification of covalent organic frameworks with dual functions ionic liquids for membrane-based biogas upgrading, J. Membr. Sci. 600 (2020) 117841
[24] Z.H. Tu, P.P. Liu, X.M. Zhang, M.Z. Shi, Z. Zhang, S.L. Luo, L.P. Zhang, Y.T. Wu, X.B. Hu, Highly-selective separation of CO₂ from N₂ or CH₄ in task-specific ionic liquid membranes:Facilitated transport and salting-out effect, Sep. Purif. Technol. 254 (2021) 117621
[25] X. Zhang, W. Xiong, Z. Tu, L. Peng, Y. Wu, X. Hu, Supported Ionic Liquid Membranes with Dual-Site Interaction Mechanism for Efficient Separation of CO₂, ACS Sustain. Chem. Eng. 7 (2019) 10792-10799
[26] M. Li, X. Zhang, S. Zeng, L. bai, H. Gao, J. Deng, Q. Yang, S. Zhang, Pebax-based composite membranes with high gas transport properties enhanced by ionic liquids for CO₂ separation, RSC Adv. 7 (2017) 6422-6431
[27] H.R. Mahdavi, N. Azizi, M. Arzani, T. Mohammadi, Improved CO₂/CH₄ separation using a nanocomposite ionic liquid gel membrane, J. Nat. Gas. Sci. Eng. 46 (2017) 275-288
[28] W. Fam, J. Mansouri, H. Li, V. Chen, Improving CO₂ separation performance of thin film composite hollow fiber with Pebax^®1657/ionic liquid gel membranes, J. Memb. Sci. 537 (2017) 54-68
[29] Z. Dai, L. Bai, K.N. Hval, X. Zhang, S. Zhang, L. Deng, Pebax^®/TSIL blend thin film composite membranes for CO₂ separation, Sci. China Chem. 59 (2016) 538-546
[30] T.C. Merkel, R. Blanc, I. Ciobanu, B. Firat, A. Suwarlim, J. Zeid, Silver salt facilitated transport membranes for olefin/paraffin separations:Carrier instability and a novel regeneration method, J. Memb. Sci. 447 (2013) 177-189
[31] J. Deng, Z.D. Dai, L.Y. Deng, Effects of the morphology of the ZIF on the CO₂ separation performance of MMMs, Ind. Eng. Chem. Res. 59 (32) (2020) 14458-14466
[32] Z.Q. Ren, Z.Y. Zhou, M.X. Li, F. Zhang, L. Wei, W.D. Liu, Deep desulfurization of fuels using imidazole anion-based ionic liquids, ACS Sustainable Chem. Eng. 7 (2) (2019) 1890-1900
[33] K. Huang, X.M. Zhang, L.S. Zhou, D.J. Tao, J.P. Fan, Highly efficient and selective absorption of H₂S in phenolic ionic liquids:A cooperative result of anionic strong basicity and cationic hydrogen-bond donation, Chem. Eng. Sci. 173 (2017) 253-263
[34] H. Sanaeepur, S. Mashhadikhan, G. Mardassi, A. Ebadi Amooghin, B. van der Bruggen, A. Moghadassi, Aminosilane cross-linked poly ether-block-amide PEBAX 2533:Characterization and CO₂ separation properties, Korean J. Chem. Eng. 36 (8) (2019) 1339-1349
[35] X.C. Yang, W.J. Zheng, Y. Xi, W.X. Guan, X.M. Yan, X.H. Ruan, C.H. Ma, Y. Dai, G.H. He, Constructing low-resistance and high-selectivity transport multi-channels in mixed matrix membranes for efficient CO₂ separation, J. Membr. Sci. 624 (2021) 119046
[36] C.A. Scholes, J. Bacus, G.Q. Chen, W.X. Tao, G. Li, A. Qader, G.W. Stevens, S.E. Kentish, Pilot plant performance of rubbery polymeric membranes for carbon dioxide separation from syngas, J. Membr. Sci. 389 (2012) 470-477
[37] J. Gao, H.Z. Mao, H. Jin, C. Chen, A. Feldhoff, Y.S. Li, Functionalized ZIF-7/Pebax^® 2533 mixed matrix membranes for CO₂/N₂ separation, Microporous Mesoporous Mater. 297 (2020) 110030
[38] F.F. Li, Y.G. Bai, S.J. Zeng, X.D. Liang, H. Wang, F. Huo, X.P. Zhang, Protic ionic liquids with low viscosity for efficient and reversible capture of carbon dioxide, Int. J. Greenh. Gas Control 90 (2019) 102801
[39] Y.S. Zhao, X.P. Zhang, S.J. Zeng, Q. Zhou, H.F. Dong, X. Tian, S.J. Zhang, Density, viscosity, and performances of carbon dioxide capture in 16 absorbents of amine + ionic liquid + H₂O, ionic liquid + H₂O, and amine + H₂O systems, J. Chem. Eng. Data 55 (9) (2010) 3513-3519
[40] E. Ghasemi Estahbanati, M. Omidkhah, A. Ebadi Amooghin, Preparation and characterization of novel Ionic liquid/Pebax membranes for efficient CO₂/light gases separation, J. Ind. Eng. Chem. 51 (2017) 77-89
[41] P. Bernardo, J.C. Jansen, F. Bazzarelli, F. Tasselli, A. Fuoco, K. Friess, P. Izák, V. Jarmarová, M. Kačírková, G. Clarizia, Gas transport properties of Pebax^®/room temperature ionic liquid gel membranes, Sep. Purif. Technol. 97 (2012) 73-82

The effect of protic ionic liquids incorporation on CO₂ separation performance of Pebax-based membranes

The effect of protic ionic liquids incorporation on CO₂ separation performance of Pebax-based membranes

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	Xinxin Li, Hongwei Shao, Shichao Zhang, Yong Li, Jingjing Gu, Qiang Huang, Jin Ran. Two dimensional MoS₂ finding its way towards constructing high-performance alkaline recovery membranes[J]. 中国化学工程学报, 2023, 60(8): 155-164.
[2]	Wenwen Zhang, Zhigang Xue, Liyun Cui, Haoliang Gao, Di Zhao, Rongfei Zhou, Weihong Xing. Synthesis of an IMF zeolite membrane for the separation of xylene isomer[J]. 中国化学工程学报, 2023, 60(8): 205-211.
[3]	Hammad Saulat, Jianhua Yang, Tao Yan, Waseem Raza, Wensen Song, Gaohong He. Tungsten incorporated mobil-type eleven zeolite membranes: Facile synthesis and tuneable wettability for highly efficient separation of oil/water mixtures[J]. 中国化学工程学报, 2023, 60(8): 242-252.
[4]	Jian Wang, Yuanhui Shen, Donghui Zhang, Zhongli Tang, Wenbin Li. Integrated vacuum pressure swing adsorption and Rectisol process for CO₂ capture from underground coal gasification syngas[J]. 中国化学工程学报, 2023, 57(5): 265-279.
[5]	Shujun Peng, Song Lei, Sisi Wen, Jian Xue, Haihui Wang. A Ruddlesden–Popper oxide as a carbon dioxide tolerant cathode for solid oxide fuel cells that operate at intermediate temperatures[J]. 中国化学工程学报, 2023, 56(4): 25-32.
[6]	Xingzhong Li, Kunlin Yu, Zibo He, Bo Liu, Rongfei Zhou, Weihong Xing. Improved SSZ-13 thin membranes fabricated by seeded-gel approach for efficient CO₂ capture[J]. 中国化学工程学报, 2023, 56(4): 273-280.
[7]	Tutuk Djoko Kusworo, Monica Yulfarida, Andri Cahyo Kumoro, Dani Puji Utomo. Purification of bioethanol fermentation broth using hydrophilic PVA crosslinked PVDF-GO/TiO₂ membrane[J]. 中国化学工程学报, 2023, 55(3): 123-136.
[8]	Yuandong Cui, Bin He, Yu Lei, Yu Liang, Wanting Zhao, Jian Sun, Xiaomin Liu. Lignin derived absorbent for efficient and sustainable CO₂ capture[J]. 中国化学工程学报, 2023, 54(2): 89-97.
[9]	Xi Zhang, Xiaodong Wang, Wei Huang. Separation of a C₃H₆/C₂H₄ mixture using Pebax^® 2533/PEG600 blend membranes[J]. 中国化学工程学报, 2023, 54(2): 192-198.
[10]	Lin-Bing Zou, Jue-Ying Gong, Xiao-Jie Ju, Zhuang Liu, Wei Wang, Rui Xie, Liang-Yin Chu. Smart membranes for biomedical applications[J]. 中国化学工程学报, 2022, 49(9): 34-45.
[11]	Sihan Huang, Yaohan Chen, Xue Wang, Jing Guo, Yonggang Li, Lei Dai, Shenghai Li, Suobo Zhang. Preparation of antifouling ultrafiltration membranes from copolymers of polysulfone and zwitterionic poly(arylene ether sulfone)s[J]. 中国化学工程学报, 2022, 49(9): 100-110.
[12]	Ping Zhang, Chao Gong, Tao Zhou, Peng Du, Jieyu Song, Mengyang Shi, Xuerui Wang, Xuehong Gu. Helium extraction from natural gas using DD3R zeolite membranes[J]. 中国化学工程学报, 2022, 49(9): 122-129.
[13]	Juanjuan Liu, Xiaolong Lu, Guiming Shu, Ke Li, Shuyun Zheng, Xiao Kong, Tao Li, Jun Yang. The facile method developed for preparing polyvinylidene fluoride plasma separation membrane via macromolecular interaction[J]. 中国化学工程学报, 2022, 49(9): 140-149.
[14]	Yimin Zhang, Ruiming Zeng, Yun Zu, Linhua Zhu, Yi Mei, Yongming Luo, Dedong He. Low-temperature dry reforming of methane tuned by chemical speciations of active sites on the SiO₂ and γ-Al₂O₃ supported Ni and Ni-Ce catalysts[J]. 中国化学工程学报, 2022, 48(8): 76-90.
[15]	Tianping Wang, Xuxiang Jia, Yu Wang, Chunsong Ye. Influence of CO₂ inleakage on the slight-alkalization of generator internal cooling water[J]. 中国化学工程学报, 2022, 48(8): 91-97.