Amine-immobilized HY zeolite for CO2 capture from hot flue gas

doi:10.1016/j.cjche.2022.02.004

摘要/Abstract

摘要： Solid amine-based adsorbents were widely studied as an alternative to liquid amine for post-combustion CO₂ capture (PCC). However, most of the amine adsorbents suffer from low thermal stability and poor cyclic regenerability at the temperature of hot flue gases. Here we present an amine loaded proton type Y zeolite (HY) where the amines namely monoethanolamine (MEA) and ethylenediamine (ED) are chemical immobilized via ionic bond to the zeolite framework to overcome the amine degradation problem. The MEA and ED of 5%, 10% and 20% (mass) concentration – immobilized zeolites were characterized by X-ray diffraction, Fourier-transform infrared spectroscopy, and N₂ -196 ℃ adsorption to confirm the structure integrity, amine functionalization, and surface area, respectively. The determination of the amine loading was given by C, H, N elemental analysis showing that ED has successfully grafted almost twice as many amino groups as MEA within the same solvent concentration. CO₂ adsorption capacity and thermal stability of these samples were measured using thermogravimetric analyser. The adsorption performance was tested at the adsorption temperature of 30, 60 and 90 ℃, respectively using pure CO₂ while the desorption was carried out with pure N₂ purge at the same temperature and then followed by elevated temperature at 150 ℃. It was found that all the amine@HY have a substantial high selectivity of CO₂ over N₂. The sample 20% ED@HY has the highest CO₂ adsorption capacity of 1.76 mmol·g^-1 at 90 ℃ higher than the capacity on parent NaY zeolite (1.45 mmol·g^-1 only). The amine@HY samples presented superior performance in cyclic thermal stability in the condition of the adsorption temperature of 90 ℃ and the desorption temperature of 150 ℃. These findings will foster the design of better adsorbents for CO₂ capture from flue gas in post-combustion power plants.

关键词: Zeolite HY, Amine-immobilization, CO₂ capture, Monoethanolamine (MEA), Ethylenediamine (ED), Adsorption

Abstract: Solid amine-based adsorbents were widely studied as an alternative to liquid amine for post-combustion CO₂ capture (PCC). However, most of the amine adsorbents suffer from low thermal stability and poor cyclic regenerability at the temperature of hot flue gases. Here we present an amine loaded proton type Y zeolite (HY) where the amines namely monoethanolamine (MEA) and ethylenediamine (ED) are chemical immobilized via ionic bond to the zeolite framework to overcome the amine degradation problem. The MEA and ED of 5%, 10% and 20% (mass) concentration – immobilized zeolites were characterized by X-ray diffraction, Fourier-transform infrared spectroscopy, and N₂ -196 ℃ adsorption to confirm the structure integrity, amine functionalization, and surface area, respectively. The determination of the amine loading was given by C, H, N elemental analysis showing that ED has successfully grafted almost twice as many amino groups as MEA within the same solvent concentration. CO₂ adsorption capacity and thermal stability of these samples were measured using thermogravimetric analyser. The adsorption performance was tested at the adsorption temperature of 30, 60 and 90 ℃, respectively using pure CO₂ while the desorption was carried out with pure N₂ purge at the same temperature and then followed by elevated temperature at 150 ℃. It was found that all the amine@HY have a substantial high selectivity of CO₂ over N₂. The sample 20% ED@HY has the highest CO₂ adsorption capacity of 1.76 mmol·g^-1 at 90 ℃ higher than the capacity on parent NaY zeolite (1.45 mmol·g^-1 only). The amine@HY samples presented superior performance in cyclic thermal stability in the condition of the adsorption temperature of 90 ℃ and the desorption temperature of 150 ℃. These findings will foster the design of better adsorbents for CO₂ capture from flue gas in post-combustion power plants.

Key words: Zeolite HY, Amine-immobilization, CO₂ capture, Monoethanolamine (MEA), Ethylenediamine (ED), Adsorption

Wanqiao Liang, Jihuan Huang, Penny Xiao, Ranjeet Singh, Jining Guo, Leila Dehdari, Gang Kevin Li. Amine-immobilized HY zeolite for CO₂ capture from hot flue gas[J]. 中国化学工程学报, 2022, 43(3): 335-342.

Wanqiao Liang, Jihuan Huang, Penny Xiao, Ranjeet Singh, Jining Guo, Leila Dehdari, Gang Kevin Li. Amine-immobilized HY zeolite for CO₂ capture from hot flue gas[J]. Chinese Journal of Chemical Engineering, 2022, 43(3): 335-342.

参考文献

[1] D.Y.C. Leung, G. Caramanna, M.M. Maroto-Valer, An overview of current status of carbon dioxide capture and storage technologies, Renew. Sustain. Energy Rev. 39 (2014) 426-443.10.1016/j.rser.2014.07.093
[2] R.L. Siegelman, P.J. Milner, E.J. Kim, S.C. Weston, J.R. Long, Challenges and opportunities for adsorption-based CO₂ capture from natural gas combined cycle emissions, Energy Environ. Sci. 12 (7) (2019) 2161-2173.10.1039/c9ee00505f
[3] P. Tontiwachwuthikul, R. Idem, Recent Progress and New Developments in Post-Combustion Carbon-Capture Technology with Reactive Solvents, Future Science Ltd., London, 2013, pp. 2-8.https://www.researchgate.net/publication/309502469_Recent_progress_and_new_developments_in_post-combustion_carbon-capture_technology_with_reactive_solvents
[4] E.E. Ünveren, B.Ö. Monkul, Ş. Sarıoğlan, N. Karademir, E. Alper, Solid amine sorbents for CO₂ capture by chemical adsorption:A review, Petroleum 3 (1) (2017) 37-50.10.1016/j.petlm.2016.11.001
[5] T.L.P. Dantas, F.M.T. Luna, I.J. Silva Jr, D.C.S. de Azevedo, C.A. Grande, A.E. Rodrigues, R.F.P.M. Moreira, Carbon dioxide-nitrogen separation through adsorption on activated carbon in a fixed bed, Chem. Eng. J. 169 (1-3) (2011) 11-19.10.1016/j.cej.2010.08.026
[6] M.G. Plaza, A.S. González, C. Pevida, J.J. Pis, F. Rubiera, Valorisation of spent coffee grounds as CO₂ adsorbents for postcombustion capture applications, Appl. Energy 99 (2012) 272-279.10.1016/j.apenergy.2012.05.028
[7] M.G. Plaza, A.S. González, J.J. Pis, F. Rubiera, C. Pevida, Production of microporous biochars by single-step oxidation:Effect of activation conditions on CO₂ capture, Appl. Energy 114 (2014) 551-562.10.1016/j.apenergy.2013.09.058
[8] F. Akhtar, L. Andersson, N. Keshavarzi, L. Bergström, Colloidal processing and CO₂ capture performance of sacrificially templated zeolite monoliths, Appl. Energy 97 (2012) 289-296.10.1016/j.apenergy.2011.12.064
[9] S.J. Datta, C. Khumnoon, Z.H. Lee, W.K. Moon, S. Docao, T.H. Nguyen, I.C. Hwang, D. Moon, P. Oleynikov, O. Terasaki, K.B. Yoon, CO₂ capture from humid flue gases and humid atmosphere using a microporous coppersilicate, Science 350 (6258) (2015) 302-306.https://pubmed.ncbi.nlm.nih.gov/26472904/
[10] D.P. Bezerra, F.W.M. da Silva, P.A.S. de Moura, A.G.S. Sousa, R.S. Vieira, E. Rodriguez-Castellon, D.C.S. Azevedo, CO₂ adsorption in amine-grafted zeolite 13X, Appl. Surf. Sci. 314 (2014) 314-321.10.1016/j.apsusc.2014.06.164
[11] R. Chatti, A.K. Bansiwal, J.A. Thote, V. Kumar, P. Jadhav, S.K. Lokhande, R.B. Biniwale, N.K. Labhsetwar, S.S. Rayalu, Amine loaded zeolites for carbon dioxide capture:Amine loading and adsorption studies, Microporous Mesoporous Mater. 121 (1-3) (2009) 84-89.10.1016/j.micromeso.2009.01.007
[12] M. Broda, C.R. Müller, Sol-gel-derived, CaO-based, ZrO₂-stabilized CO₂ sorbents, Fuel 127 (2014) 94-100.10.1016/j.fuel.2013.08.004
[13] K. Sumida, D.L. Rogow, J.A. Mason, T.M. McDonald, E.D. Bloch, Z.R. Herm, T.H. Bae, J.R. Long, Carbon dioxide capture in metal-organic frameworks, Chem. Rev. 112 (2) (2012) 724-781.https://pubmed.ncbi.nlm.nih.gov/22204561/
[14] R. Dawson, A.I. Cooper, D.J. Adams, Chemical functionalization strategies for carbon dioxide capture in microporous organic polymers, Polym. Int. 62 (3) (2013) 345-352.10.1002/pi.4407
[15] T.C. Drage, C.E. Snape, L.A. Stevens, J. Wood, J.W. Wang, A.I. Cooper, R. Dawson, X. Guo, C. Satterley, R. Irons, Materials challenges for the development of solid sorbents for post-combustion carbon capture, J. Mater. Chem. 22 (7) (2012) 2815-2823.10.1039/c2jm12592g
[16] H.A. Patel, J. Byun, C.T. Yavuz, Carbon dioxide capture adsorbents:Chemistry and methods, ChemSusChem 10 (7) (2017) 1303-1317.https://pubmed.ncbi.nlm.nih.gov/28001318/
[17] S. Karka, S. Kodukula, S.V. Nandury, U. Pal, Polyethylenimine-modified zeolite 13X for CO₂ capture:Adsorption and kinetic studies, ACS Omega 4 (15) (2019) 16441-16449.https://pubmed.ncbi.nlm.nih.gov/31616822/
[18] V. Tejavath, V. Kasarabada, S. Gonuguntla, V. Perupoga, S.V. Nandury, S. Bojja, U. Pal, Technoeconomic investigation of amine-grafted zeolites and their kinetics for CO₂ capture, ACS Omega 6 (9) (2021) 6153-6162.https://pubmed.ncbi.nlm.nih.gov/33718706/
[19] A. Sayari, Y. Belmabkhout, Stabilization of amine-containing CO₂ adsorbents:Dramatic effect of water vapor, J. Am. Chem. Soc. 132 (18) (2010) 6312-6314.https://pubmed.ncbi.nlm.nih.gov/20405941/
[20] C. Kim, H.S. Cho, S. Chang, S.J. Cho, M. Choi, An ethylenediamine-grafted Y zeolite:A highly regenerable carbon dioxide adsorbent via temperature swing adsorption without urea formation, Energy Environ. Sci. 9 (5) (2016) 1803-1811.10.1039/c6ee00601a
[21] A.D. Ebner, M.L. Gray, N.G. Chisholm, Q.T. Black, D.D. Mumford, M.A. Nicholson, J.A. Ritter, Suitability of a solid amine sorbent for CO₂ capture by pressure swing adsorption, Ind. Eng. Chem. Res. 50 (9) (2011) 5634-5641.10.1021/ie2000709
[22] A. Golmakani, S. Fatemi, J. Tamnanloo, Investigating PSA, VSA, and TSA methods in SMR unit of refineries for hydrogen production with fuel cell specification, Sep. Purif. Technol. 176 (2017) 73-91.10.1016/j.seppur.2016.11.030
[23] W. Lutz, R.A. Shutilov, V.Y. Gavrilov, Pore structure of USY zeolites in dependence on steaming condition, Zeitschrift Für Anorg. Und Allgemeine Chemie 640 (3-4) (2014) 577-581.10.1002/zaac.201300403
[24] D. Verboekend, N. Nuttens, R. Locus, J. van Aelst, P. Verolme, J.C. Groen, J. Pérez-Ramírez, B.F. Sels, Synthesis, characterisation, and catalytic evaluation of hierarchical faujasite zeolites:Milestones, challenges, and future directions, Chem. Soc. Rev. 45 (12) (2016) 3331-3352.10.1039/c5cs00520e
[25] F.S. Su, C. Lu, S.C. Kuo, W.T. Zeng, Adsorption of CO₂ on amine-functionalized Y-type zeolites, Energy Fuels 24 (2) (2010) 1441-1448.10.1021/ef901077k
[26] T.D. Pham, R.F. Lobo, Adsorption equilibria of CO₂ and small hydrocarbons in AEI-, CHA-, STT-, and RRO-type siliceous zeolites, Microporous Mesoporous Mater. 236 (2016) 100-108.10.1016/j.micromeso.2016.08.025
[27] R. Kusumastuti, Sriyono, M. Pancoko, S.L. Butarbutar, G.E. Putra, H. Tjahjono, Study on the mechanism of CO₂ adsorption process on zeolite 5A as a molecular sieve in RDE system:An infrared investigation, J. Phys. Conf. Ser.1198(3), (2019) 032009
[28] D. Bonenfant, M. Kharoune, P. Niquette, M. Mimeault, R. Hausler, Advances in principal factors influencing carbon dioxide adsorption on zeolites, Sci. Technol. Adv. Mater. 9 (1) (2008) 013007.https://pubmed.ncbi.nlm.nih.gov/27877925/
[29] W. Li, S. Choi, J.H. Drese, M. Hornbostel, G. Krishnan, P.M. Eisenberger, C.W. Jones, Steam-stripping for regeneration of supported amine-based CO₂ adsorbents, ChemSusChem 3 (8) (2010) 899-903.https://pubmed.ncbi.nlm.nih.gov/20575143/
[30] N. Otsuka, Fireside Corrosion, Shreir's Corrosion, 2010, pp. 457-481
[31] W. Shao, L.Z. Zhang, L.X. Li, R.L. Lee, Adsorption of CO₂ and N₂ on synthesized NaY zeolite at high temperatures, Adsorption 15 (5-6) (2009) 497-505.10.1007/s10450-009-9200-y
[32] W. Jia, S. Murad, Molecular dynamics simulations of gas separations using faujasite-type zeolite membranes, J. Chem. Phys. 120 (10) (2004) 4877-4885.https://pubmed.ncbi.nlm.nih.gov/15267348/
[33] A.E.O. Lima, V.A.M. Gomes, S.M.P. Lucena, Theoretical study of CO₂:N₂ adsorption in faujasite impregnated with monoethanolamine, Braz. J. Chem. Eng. 32 (3) (2015) 663-669.10.1590/0104-6632.20150323s00003450

Amine-immobilized HY zeolite for CO₂ capture from hot flue gas

Amine-immobilized HY zeolite for CO₂ capture from hot flue gas

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