Improvement of synergistic effect photocatalytic/peroxymonosulfate activation for degradation of amoxicillin using carbon dots anchored on rod-like CoFe2O4

doi:10.1016/j.cjche.2021.10.030

中国化学工程学报 ›› 2022, Vol. 52 ›› Issue (12): 136-145.DOI: 10.1016/j.cjche.2021.10.030

• Full Length Article • 上一篇下一篇

Improvement of synergistic effect photocatalytic/peroxymonosulfate activation for degradation of amoxicillin using carbon dots anchored on rod-like CoFe₂O₄

Weilong Shi^2,4, Yanan Liu¹, Wei Sun¹, Yuanzhi Hong¹, Xiangyu Li¹, Xue Lin¹, Feng Guo³, Junyou Shi¹

1. School of Material Science and Engineering, Beihua University, Jilin 132013, China;
2. School of Material Science and Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, China;
3. School of Energy and Power, Jiangsu University of Science and Technology, Zhenjiang 212003, China;
4. College of Chemistry, Zhengzhou University, Zhengzhou 450001, China

收稿日期:2021-08-28 修回日期:2021-10-19 出版日期:2022-12-28 发布日期:2023-01-31
通讯作者: Xue Lin,E-mail:jlsdlinxue@126.com;Feng Guo,E-mail:gfeng0105@126.com;Junyou Shi,E-mail:bhsjy64@163.com
基金资助:
The authors would like to acknowledge the founding support from the National Natural Science Foundation of China (Nos. 21906072, 22006057 and 31971616), the Natural Science Foundation of Jiangsu Province (BK20190982), “Doctor of Mass Entrepreneurship and Innovation” Project in Jiangsu Province, Henan Postdoctoral Foundation (202003013), Doctoral Scientific Research Foundation of Jiangsu University of Science and Technology (China) (1062931806 and 1142931803), the Science and Technology Research Project of the Department of Education of Jilin Province (JJKH20200039KJ), the Science and Technology Research Project of Jilin City (20190104120, 201830811) and the Project of Jilin Provincial Science and Technology Development Plan (20190201277JC, 20200301046RQ, YDZJ202101ZYTS070).

Improvement of synergistic effect photocatalytic/peroxymonosulfate activation for degradation of amoxicillin using carbon dots anchored on rod-like CoFe₂O₄

Weilong Shi^2,4, Yanan Liu¹, Wei Sun¹, Yuanzhi Hong¹, Xiangyu Li¹, Xue Lin¹, Feng Guo³, Junyou Shi¹

1. School of Material Science and Engineering, Beihua University, Jilin 132013, China;
2. School of Material Science and Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, China;
3. School of Energy and Power, Jiangsu University of Science and Technology, Zhenjiang 212003, China;
4. College of Chemistry, Zhengzhou University, Zhengzhou 450001, China

Received:2021-08-28 Revised:2021-10-19 Online:2022-12-28 Published:2023-01-31
Contact: Xue Lin,E-mail:jlsdlinxue@126.com;Feng Guo,E-mail:gfeng0105@126.com;Junyou Shi,E-mail:bhsjy64@163.com
Supported by:
The authors would like to acknowledge the founding support from the National Natural Science Foundation of China (Nos. 21906072, 22006057 and 31971616), the Natural Science Foundation of Jiangsu Province (BK20190982), “Doctor of Mass Entrepreneurship and Innovation” Project in Jiangsu Province, Henan Postdoctoral Foundation (202003013), Doctoral Scientific Research Foundation of Jiangsu University of Science and Technology (China) (1062931806 and 1142931803), the Science and Technology Research Project of the Department of Education of Jilin Province (JJKH20200039KJ), the Science and Technology Research Project of Jilin City (20190104120, 201830811) and the Project of Jilin Provincial Science and Technology Development Plan (20190201277JC, 20200301046RQ, YDZJ202101ZYTS070).

摘要/Abstract

摘要： β-lactam antibiotics in aquatic environment have severely damaged ecological stability and caused a series of environmental pollution problems to be solved urgently. Herein, a novel composite photocatalyst prepared by loading carbon dots (CDs) onto rod-like CoFe₂O₄ (CFO), which can effectively degrade amoxicillin (AMX) by photocatalytic/peroxymonosulfate (PMS) activation under visible light irradiation. The degradation results exhibits that the optimal degradation efficiency with 97.5% within 80 min is achievd by the CDs-CFO-5 composite. Such enhanced activity is ascribed to the introduction of CDs that effectively improves the separation efficiency of photogenerated electron pairs and creates new active sites as electron bridges that improve the photocatalytic performance. More importantly, a strong synergistic between CDs and photo-induced electrons generated from CFO can further activiate PMS to provide more SO₄^-· and ·OH radicals for boosting the degradation ability towards AMX. The present study aims to elucidate positive role of CDs in photocatalytic/peroxymonosulfate activation during the degradation reaction.

关键词: Carbon dots (CDs), CoFe₂O₄(CFO), Peroxymonosulfate (PMS), Photocatalytic, Amoxicillin (AMX)

Abstract: β-lactam antibiotics in aquatic environment have severely damaged ecological stability and caused a series of environmental pollution problems to be solved urgently. Herein, a novel composite photocatalyst prepared by loading carbon dots (CDs) onto rod-like CoFe₂O₄ (CFO), which can effectively degrade amoxicillin (AMX) by photocatalytic/peroxymonosulfate (PMS) activation under visible light irradiation. The degradation results exhibits that the optimal degradation efficiency with 97.5% within 80 min is achievd by the CDs-CFO-5 composite. Such enhanced activity is ascribed to the introduction of CDs that effectively improves the separation efficiency of photogenerated electron pairs and creates new active sites as electron bridges that improve the photocatalytic performance. More importantly, a strong synergistic between CDs and photo-induced electrons generated from CFO can further activiate PMS to provide more SO₄^-· and ·OH radicals for boosting the degradation ability towards AMX. The present study aims to elucidate positive role of CDs in photocatalytic/peroxymonosulfate activation during the degradation reaction.

Key words: Carbon dots (CDs), CoFe₂O₄(CFO), Peroxymonosulfate (PMS), Photocatalytic, Amoxicillin (AMX)

Weilong Shi, Yanan Liu, Wei Sun, Yuanzhi Hong, Xiangyu Li, Xue Lin, Feng Guo, Junyou Shi. Improvement of synergistic effect photocatalytic/peroxymonosulfate activation for degradation of amoxicillin using carbon dots anchored on rod-like CoFe₂O₄[J]. 中国化学工程学报, 2022, 52(12): 136-145.

参考文献

[1] X.L. Weng, W.L. Cai, S. Lin, Z.L. Chen, Degradation mechanism of amoxicillin using clay supported nanoscale zero-valent iron, Appl. Clay Sci. 147 (2017) 137–142
[2] D. Aksu Demirezen, Y.Ş. Yıldız, D. Demirezen Yılmaz, Amoxicillin degradation using green synthesized iron oxide nanoparticles: Kinetics and mechanism analysis, Environ. Nanotechnol. Monit. Manag. 11 (2019) 100219
[3] X.Z. Bian, Y. Xia, T.T. Zhan, L. Wang, W. Zhou, Q.Z. Dai, J.M. Chen, Electrochemical removal of amoxicillin using a Cu doped PbO₂ electrode: Electrode characterization, operational parameters optimization and degradation mechanism, Chemosphere 233 (2019) 762–770
[4] M. Verma, A.K. Haritash, Photocatalytic degradation of Amoxicillin in pharmaceutical wastewater: A potential tool to manage residual antibiotics, Environ. Technol. Innov. 20 (2020) 101072
[5] Y.Q. Zhang, Y.J. Xiao, Y. Zhong, T.T. Lim, Comparison of amoxicillin photodegradation in the UV/H₂O₂ and UV/persulfate systems: Reaction kinetics, degradation pathways, and antibacterial activity, Chem. Eng. J. 372 (2019) 420–428
[6] F.J. Ren, W.W. Zhu, J.Y. Zhao, H.T. Liu, X.A. Zhang, H. Zhang, H. Zhu, Y. Peng, B. Wang, Nitrogen-doped graphene oxide aerogel anchored with spinel CoFe₂O₄ nanoparticles for rapid degradation of tetracycline, Sep. Purif. Technol. 241 (2020) 116690
[7] W.L. Shi, F. Guo, M.Y. Li, Y. Shi, Y.B. Tang, N-doped carbon dots/CdS hybrid photocatalyst that responds to visible/near-infrared light irradiation for enhanced photocatalytic hydrogen production, Sep. Purif. Technol. 212 (2019) 142–149
[8] W.Y. Han, D.G. Li, M.Q. Zhang, X.M. Hu, X.G. Duan, S.M. Liu, S.B. Wang, Photocatalytic activation of peroxymonosulfate by surface-tailored carbon quantum dots, J. Hazard. Mater. 395 (2020) 122695
[9] I.A. Ike, K.G. Linden, J.D. Orbell, M. Duke, Critical review of the science and sustainability of persulphate advanced oxidation processes, Chem. Eng. J. 338 (2018) 651–669
[10] W.L. Shi, Y.N. Liu, W. Sun, Y.Z. Hong, X.Y. Li, X. Lin, F. Guo, J.Y. Shi, Assembling g-C₃N₄ nanosheets on rod-like CoFe₂O₄ nanocrystals to boost photocatalytic degradation of ciprofloxacin with peroxymonosulfate activation, Mater. Today Commun. 29 (2021) 102871
[11] H.R. Sun, F. Guo, J.J. Pan, W. Huang, K. Wang, W.L. Shi, One-pot thermal polymerization route to prepare N-deficient modified g-C₃N₄ for the degradation of tetracycline by the synergistic effect of photocatalysis and persulfate-based advanced oxidation process, Chem. Eng. J. 406 (2021) 126844
[12] F. Chen, G.X. Huang, F.B. Yao, Q. Yang, Y.M. Zheng, Q.B. Zhao, H.Q. Yu, Catalytic degradation of ciprofloxacin by a visible-light-assisted peroxymonosulfate activation system: Performance and mechanism, Water Res. 173 (2020) 115559
[13] X.B. Dong, B.X. Ren, Z.M. Sun, C.Q. Li, X.W. Zhang, M.H. Kong, S.L. Zheng, D.D. Dionysiou, Monodispersed CuFe₂O₄ nanoparticles anchored on natural kaolinite as highly efficient peroxymonosulfate catalyst for bisphenol A degradation, Appl. Catal. B Environ. 253 (2019) 206–217
[14] A. Durairaj, T. Sakthivel, A. Obadiah, S. Vasanthkumar, Enhanced photocatalytic activity of transition metal ions doped g–C₃N₄ nanosheet activated by PMS for organic pollutant degradation, J. Mater. Sci. Mater. Electron. 29 (10) (2018) 8201–8209
[15] L. Yang, Y.Z. Hong, E.L. Liu, X. Zhang, L.Y. Wang, X. Lin, J.Y. Shi, Significant enhancement of photocatalytic H₂ production simultaneous with dye degradation over Ni₂P modified In₂O₃ nanocomposites, Sep. Purif. Technol. 263 (2021) 118366
[16] M.F. Liang, T. Borjigin, Y.H. Zhang, B.H. Liu, H. Liu, H. Guo, Controlled assemble of hollow heterostructured g-C₃N₄@CeO₂ with rich oxygen vacancies for enhanced photocatalytic CO₂ reduction, Appl. Catal. B Environ. 243 (2019) 566–575
[17] Y.N. Liu, C. Liu, C.L. Shi, W. Sun, X. Lin, W.L. Shi, Y.Z. Hong, Carbon-based quantum dots (QDs) modified ms/tz-BiVO₄ heterojunction with enhanced photocatalytic performance for water purification, J. Alloys Compd. 881 (2021) 160437
[18] W.L. Shi, F. Guo, H.B. Wang, S.J. Guo, H. Li, Y.J. Zhou, C. Zhu, Y.H. Liu, H. Huang, B.D. Mao, Y. Liu, Z.H. Kang, New insight of water-splitting photocatalyst: H₂O ₂-resistance poisoning and photothermal deactivation in sub-micrometer CoO octahedrons, ACS Appl. Mater. Interfaces 9 (24) (2017) 20585–20593
[19] W. Sun, S. Yang, Y.N. Liu, C.L. Shi, W.L. Shi, X. Lin, F. Guo, Y.Z. Hong, Fabricating nitrogen-doped carbon dots (NCDs) on Bi_3.64Mo_0.36O_6.55 nanospheres: A nanoheterostructure for enhanced photocatalytic performance for water purification, J. Phys. Chem. Solids 159 (2021) 110283
[20] W.L. Shi, F. Guo, S.L. Yuan, In situ synthesis of Z-scheme Ag₃PO₄/CuBi₂O₄ photocatalysts and enhanced photocatalytic performance for the degradation of tetracycline under visible light irradiation, Appl. Catal. B Environ. 209 (2017) 720–728
[21] F. Guo, W.L. Shi, M.Y. Li, Y. Shi, H.B. Wen, 2D/2D Z-scheme heterojunction of CuInS₂/g-C₃N₄ for enhanced visible-light-driven photocatalytic activity towards the degradation of tetracycline, Sep. Purif. Technol. 210 (2019) 608–615
[22] F. Guo, M.Y. Li, H.J. Ren, X.L. Huang, W.X. Hou, C. Wang, W.L. Shi, C.Y. Lu, Fabrication of p-n CuBi₂O₄/MoS₂ heterojunction with nanosheets-on-microrods structure for enhanced photocatalytic activity towards tetracycline degradation, Appl. Surf. Sci. 491 (2019) 88–94
[23] F. Guo, M.Y. Li, H.J. Ren, X.L. Huang, K.K. Shu, W.L. Shi, C.Y. Lu, Facile bottom-up preparation of Cl-doped porous g-C₃N₄ nanosheets for enhanced photocatalytic degradation of tetracycline under visible light, Sep. Purif. Technol. 228 (2019) 115770
[24] M. Golshan, B. Kakavandi, M. Ahmadi, M. Azizi, Photocatalytic activation of peroxymonosulfate by TiO₂ anchored on cupper ferrite (TiO₂@CuFe₂O₄) into 2,4-D degradation: Process feasibility, mechanism and pathway, J. Hazard. Mater. 359 (2018) 325–337
[25] W.L. Shi, J.B. Wang, S. Yang, X. Lin, F. Guo, J.Y. Shi, Fabrication of a ternary carbon dots/CoO/g-C₃N₄ nanocomposite photocatalyst with enhanced visible-light-driven photocatalytic hydrogen production, J. Chem. Technol. Biotechnol. 95 (8) (2020) 2129–2138
[26] K.L. Yan, X. Shang, Z.Z. Liu, B. Dong, S.S. Lu, J.Q. Chi, W.K. Gao, Y.M. Chai, C.G. Liu, A facile method for reduced CoFe₂O₄ nanosheets with rich oxygen vacancies for efficient oxygen evolution reaction, Int. J. Hydrog. Energy 42 (38) (2017) 24150–24158
[27] M.M. Gao, J. Feng, F. He, W.J. Zeng, X. Wang, Y.M. Ren, T. Wei, Carbon microspheres work as an electron bridge for degrading high concentration MB in CoFe₂O₄@carbon microsphere/g-C₃N₄ with a hierarchical sandwich-structure, Appl. Surf. Sci. 507 (2020) 145167
[28] A.H. Mady, M.L. Baynosa, D. Tuma, J.J. Shim, Heterogeneous activation of peroxymonosulfate by a novel magnetic 3D γ-MnO₂@ZnFe₂O₄/rGO nanohybrid as a robust catalyst for phenol degradation, Appl. Catal. B Environ. 244 (2019) 946–956
[29] X.G. Duan, H.Q. Sun, S.B. Wang, Metal-free carbocatalysis in advanced oxidation reactions, Acc. Chem. Res. 51(3) (2018) 678–687
[30] L.H. Zhang, T. Wei, Z.M. Jiang, C.Q. Liu, H. Jiang, J. Chang, L.Z. Sheng, Q.H. Zhou, L.B. Yuan, Z.J. Fan, Electrostatic interaction in electrospun nanofibers: Double-layer carbon protection of CoFe₂O₄ nanosheets enabling ultralong-life and ultrahigh-rate lithium ion storage, Nano Energy 48 (2018) 238–247
[31] H.Y. Gao, J.J. Xiang, Y. Cao, Hierarchically porous CoFe₂O₄ nanosheets supported on Ni foam with excellent electrochemical properties for asymmetric supercapacitors, Appl. Surf. Sci. 413 (2017) 351–359
[32] X.Y. Yao, J.H. Kong, X.S. Tang, D. Zhou, C.Y. Zhao, R. Zhou, X.H. Lu, Facile synthesis of porous CoFe₂O₄ nanosheets for lithium-ion battery anodes with enhanced rate capability and cycling stability, RSC Adv. 4 (52) (2014) 27488–27492
[33] C.L. Xia, S.J. Zhu, T.L. Feng, M.X. Yang, B. Yang, Evolution and synthesis of carbon dots: From carbon dots to carbonized polymer dots, Adv. Sci. (Weinh) 6 (23) (2019) 1901316
[34] V. Strauss, A. Roth, M. Sekita, D.M. Guldi, Efficient energy-conversion materials for the future: Understanding and tailoring charge-transfer processes in carbon nanostructures, Chem 1 (4) (2016) 531–556
[35] T. Gatti, N. Vicentini, M. Mba, E. Menna, Organic functionalized carbon nanostructures for functional polymer-based nanocomposites, Eur. J. Org. Chem. 2016 (6) (2016) 1071–1090
[36] W.L. Shi, F. Guo, H.B. Wang, C.G. Liu, Y.J. Fu, S.L. Yuan, H. Huang, Y. Liu, Z.H. Kang, Carbon dots decorated magnetic ZnFe₂O₄ nanoparticles with enhanced adsorption capacity for the removal of dye from aqueous solution, Appl. Surf. Sci. 433 (2018) 790–797
[37] W.L. Shi, F. Guo, M.Y. Li, Y. Shi, M.F. Wu, Y.B. Tang, Enhanced visible-light-driven photocatalytic H₂ evolution on the novel nitrogen-doped carbon dots/CuBi₂O₄ microrods composite, J. Alloys Compd. 775 (2019) 511–517
[38] H. Li, H.B. Wang, J.Q. Guo, S. Ye, W.L. Shi, X. Peng, J. Song, J.L. Qu, Long-wavelength excitation of carbon dots as the probe for real-time imaging of the living-cell cycle process, Sens. Actuat. B Chem. 311 (2020) 127891
[39] F. Guo, H.R. Sun, L. Cheng, W.L. Shi, Oxygen-defective ZnO porous nanosheets modified by carbon dots to improve their visible-light photocatalytic activity and gain mechanistic insight, New J. Chem. 44 (26) (2020) 11215–11223
[40] W.L. Shi, S. Yang, H.R. Sun, J.B. Wang, X. Lin, F. Guo, J.Y. Shi, Carbon dots anchored high-crystalline g-C₃N₄ as a metal-free composite photocatalyst for boosted photocatalytic degradation of tetracycline under visible light, J. Mater. Sci. 56 (3) (2021) 2226–2240
[41] H.T. Li, Z.H. Kang, Y. Liu, S.T. Lee, Carbon nanodots: Synthesis, properties and applications, J. Mater. Chem. 22 (46) (2012) 24230
[42] S.J. Yang, X.J. Qiu, P.K. Jin, M. Dzakpasu, X.C. Wang, Q.H. Zhang, L. zhang, L. Yang, D.H. Ding, W.D. Wang, K. Wu, MOF-templated synthesis of CoFe₂O₄ nanocrystals and its coupling with peroxymonosulfate for degradation of bisphenol A, Chem. Eng. J. 353 (2018) 329–339
[43] S. Asadzadeh-Khaneghah, A. Habibi-Yangjeh, D. Seifzadeh, Graphitic carbon nitride nanosheets coupled with carbon dots and BiOI nanoparticles: Boosting visible-light-driven photocatalytic activity, J. Taiwan Inst. Chem. Eng. 87 (2018) 98–111
[44] X.Q. Wu, J. Zhao, L.P. Wang, M.M. Han, M.L. Zhang, H.B. Wang, H. Huang, Y. Liu, Z.H. Kang, Carbon dots as solid-state electron mediator for BiVO₄/CDs/CdS Z-scheme photocatalyst working under visible light, Appl. Catal. B Environ. 206 (2017) 501–509
[45] S.Q. Huang, Y.G. Xu, M. Xie, H. Xu, M.Q. He, J.X. Xia, L.Y. Huang, H.M. Li, Synthesis of magnetic CoFe₂O₄/g-C₃N₄ composite and its enhancement of photocatalytic ability under visible-light, Colloids Surf. A Physicochem. Eng. Aspects 478 (2015) 71–80
[46] A. Paul, S.S. Dhar, Designing Cu₂V₂O₇/CoFe₂O₄/g-C₃N₄ ternary nanocomposite: A high performance magnetically recyclable photocatalyst in the reduction of 4-nitrophenol to 4-aminophenol, J. Solid State Chem. 290 (2020) 121563
[47] M. Kamranifar, A. Allahresani, A. Naghizadeh, Synthesis and characterizations of a novel CoFe₂O₄@CuS magnetic nanocomposite and investigation of its efficiency for photocatalytic degradation of penicillin G antibiotic in simulated wastewater, J. Hazard. Mater. 366 (2019) 545–555
[48] J. Wang, G.H. Wang, B. Cheng, J.G. Yu, J.J. Fan, Sulfur-doped g-C₃N₄/TiO₂ S-scheme heterojunction photocatalyst for Congo red photodegradation, Chin. J. Catal. 42 (1) (2021) 56–68
[49] W.L. Shi, M.Y. Li, X.L. Huang, H.J. Ren, C. Yan, F. Guo, Facile synthesis of 2D/2D Co₃(PO₄)₂/g-C₃N₄ heterojunction for highly photocatalytic overall water splitting under visible light, Chem. Eng. J. 382 (2020) 122960
[50] C.X. Li, H.N. Che, P.W. Huo, Y.S. Yan, C.B. Liu, H.J. Dong, Confinement of ultrasmall CoFe₂O₄ nanoparticles in hierarchical ZnIn₂S₄ microspheres with enhanced interfacial charge separation for photocatalytic H₂ evolution, J. Colloid Interface Sci. 581 (2021) 764–773
[51] D.S. Lei, J.Q. Xue, X.Y. Peng, S.H. Li, Q. Bi, C.B. Tang, L. Zhang, Oxalate enhanced synergistic removal of chromium(VI) and arsenic(III) over ZnFe₂O₄/g-C₃N₄: Z-scheme charge transfer pathway and photo-Fenton like reaction, Appl. Catal. B Environ. 282 (2021) 119578
[52] H.J. Zhang, L.Z. Liu, X.R. Zhang, S. Zhang, F.N. Meng, Microwave-assisted solvothermal synthesis of shape-controlled CoFe₂O₄ nanoparticles for acetone sensor, J. Alloys Compd. 788 (2019) 1103–1112
[53] R.S. Sahu, Y.H. Shih, W.L. Chen, New insights of metal free 2D graphitic carbon nitride for photocatalytic degradation of bisphenol A, J. Hazard. Mater. 402 (2021) 123509
[54] S. Farhadi, F. Siadatnasab, A. Khataee, Ultrasound-assisted degradation of organic dyes over magnetic CoFe₂O₄@ZnS core-shell nanocomposite, Ultrason. Sonochem. 37 (2017) 298–309
[55] J.G. Zhang, H.P. Bi, G.Y. He, Y.W. Zhou, H.Q. Chen, Fabrication of Ag₃PO₄-PANI-GO composites with high visible light photocatalytic performance and stability, J. Environ. Chem. Eng. 2 (2) (2014) 952–957
[56] J.Q. Pan, Y.Z. Sheng, J.X. Zhang, J.M. Wei, P. Huang, X. Zhang, B.X. Feng, Preparation of carbon quantum dots/TiO₂ nanotubes composites and their visible light catalytic applications, J. Mater. Chem. A 2 (42) (2014) 18082–18086
[57] Z.J. Xie, Y.P. Feng, F.L. Wang, D.N. Chen, Q.X. Zhang, Y.Q. Zeng, W.Y. Lv, G.G. Liu, Construction of carbon dots modified MoO₃/g-C₃N₄ Z-scheme photocatalyst with enhanced visible-light photocatalytic activity for the degradation of tetracycline, Appl. Catal. B Environ. 229 (2018) 96–104
[58] S. Renukadevi, A.P. Jeyakumari, A one-pot microwave irradiation route to synthesis of CoFe₂O₄-g-C₃N₄ heterojunction catalysts for high visible light photocatalytic activity: Exploration of efficiency and stability, Diam. Relat. Mater. 109 (2020) 108012
[59] J.M. Dangwang Dikdim, Y. Gong, G.B. Noumi, J.M. Sieliechi, X. Zhao, N. Ma, M. Yang, J.B. Tchatchueng, Peroxymonosulfate improved photocatalytic degradation of atrazine by activated carbon/graphitic carbon nitride composite under visible light irradiation, Chemosphere 217 (2019) 833–842
[60] W.L. Shi, M.Y. Li, H.J. Ren, F. Guo, X.L. Huang, Y. Shi, Y.B. Tang, Construction of a 0D/1D composite based on Au nanoparticles/CuBi₂O₄ microrods for efficient visible-light-driven photocatalytic activity, Beilstein J. Nanotechnol. 10 (2019) 1360–1367
[61] Q. Zhu, Y.K. Sun, F.S. Na, J. Wei, S. Xu, Y.L. Li, F. Guo, Fabrication of CdS/titanium-oxo-cluster nanocomposites based on a Ti32 framework with enhanced photocatalytic activity for tetracycline hydrochloride degradation under visible light, Appl. Catal. B Environ. 254 (2019) 541–550
[62] C.Y. Lu, F. Guo, Q.Z. Yan, Z.J. Zhang, D. Li, L.P. Wang, Y.H. Zhou, Hydrothermal synthesis of type II ZnIn₂S₄/BiPO₄ heterojunction photocatalyst with dandelion-like microflower structure for enhanced photocatalytic degradation of tetracycline under simulated solar light, J. Alloys Compd. 811 (2019) 151976
[63] S.H. Wang, L. Zhao, W. Huang, H. Zhao, J.Y. Chen, Q. Cai, X. Jiang, C.Y. Lu, W.L. Shi, Solvothermal synthesis of CoO/BiVO₄ p-n heterojunction with micro-nano spherical structure for enhanced visible light photocatalytic activity towards degradation of tetracycline, Mater. Res. Bull. 135 (2021) 111161
[64] F. Guo, X.L. Huang, Z.H. Chen, Y.X. Shi, H.R. Sun, X.F. Cheng, W.L. Shi, L.Z. Chen, Formation of unique hollow ZnSnO₃@ZnIn₂S₄ core-shell heterojunction to boost visible-light-driven photocatalytic water splitting for hydrogen production, J. Colloid Interface Sci. 602 (2021) 889–897
[65] C. Zhao, Z.Z. Liao, W. Liu, F.Y. Liu, J.Y. Ye, J.L. Liang, Y.Y. Li, Carbon quantum dots modified tubular g-C₃N₄ with enhanced photocatalytic activity for carbamazepine elimination: Mechanisms, degradation pathway and DFT calculation, J. Hazard. Mater. 381 (2020) 120957
[66] F. Guo, X.L. Huang, Z.H. Chen, L.W. Cao, X.F. Cheng, L.Z. Chen, W.L. Shi, Construction of Cu₃P-ZnSnO₃-g-C₃N₄ p-n-n heterojunction with multiple built-in electric fields for effectively boosting visible-light photocatalytic degradation of broad-spectrum antibiotics, Sep. Purif. Technol. 265 (2021) 118477
[67] J.J. Pan, F. Guo, H.R. Sun, M.Y. Li, X.F. Zhu, L.L. Gao, W.L. Shi, Nanodiamond decorated 2D hexagonal Fe₂O₃ nanosheets with a Z-scheme photogenerated electron transfer path for enhanced photocatalytic activity, J. Mater. Sci. 56 (11) (2021) 6663–6675
[68] J.J. Pan, F. Guo, H.R. Sun, Y.X. Shi, W.L. Shi, Nanodiamonds anchored on porous ZnSnO₃ cubes as an efficient composite photocatalyst with improved visible-light photocatalytic degradation of tetracycline, Sep. Purif. Technol. 263 (2021) 118398
[69] F. Guo, L.J. Wang, H.R. Sun, M.Y. Li, W.L. Shi, X. Lin, A one-pot sealed ammonia self-etching strategy to synthesis of N-defective g-C₃N₄ for enhanced visible-light photocatalytic hydrogen, Int. J. Hydrog. Energy 45 (55) (2020) 30521–30532
[70] H.T. Xu, R. Xiao, J.R. Huang, Y. Jiang, C.X. Zhao, X.F. Yang, In situ construction of protonated g-C₃N₄/Ti₃C₂ MXene Schottky heterojunctions for efficient photocatalytic hydrogen production, Chin. J. Catal. 42 (1) (2021) 107–114
[71] Z.H. Chen, F. Guo, H.R. Sun, Y.X. Shi, W.L. Shi, Well-designed three-dimensional hierarchical hollow tubular g-C₃N₄/ZnIn₂S₄ nanosheets heterostructure for achieving efficient visible-light photocatalytic hydrogen evolution, J. Colloid Interface Sci. 607 (2022) 1391–1401
[72] F. Guo, Z.H. Chen, X.L. Huang, L.W. Cao, X.F. Cheng, W.L. Shi, L.Z. Chen, Cu₃P nanoparticles decorated hollow tubular carbon nitride as a superior photocatalyst for photodegradation of tetracycline under visible light, Sep. Purif. Technol. 275 (2021) 119223
[73] E.L. Liu, X. Lin, Y.Z. Hong, L. Yang, B.F. Luo, W.L. Shi, J.Y. Shi, Rational copolymerization strategy engineered C self-doped g-C₃N₄ for efficient and robust solar photocatalytic H₂ evolution, Renew. Energy 178 (2021) 757–765
[74] X.F. Zhu, F. Guo, J.J. Pan, H.R. Sun, L.L. Gao, J.X. Deng, X.Y. Zhu, W.L. Shi, Fabrication of visible-light-response face-contact ZnSnO₃@g-C₃N₄ core–shell heterojunction for highly efficient photocatalytic degradation of tetracycline contaminant and mechanism insight, J. Mater. Sci. 56 (6) (2021) 4366–4379
[75] B.Y. Ren, W. Shen, L. Li, S.Z. Wu, W. Wang, 3D CoFe₂O₄ nanorod/flower-like MoS₂ nanosheet heterojunctions as recyclable visible light-driven photocatalysts for the degradation of organic dyes, Appl. Surf. Sci. 447 (2018) 711–723
[76] F. Guo, X.L. Huang, Z.H. Chen, H.R. Sun, W.L. Shi, Investigation of visible-light-driven photocatalytic tetracycline degradation via carbon dots modified porous ZnSnO₃ cubes: Mechanism and degradation pathway, Sep. Purif. Technol. 253 (2020) 117518
[77] J.J. Dang, J.R. Guo, L.P. Wang, F. Guo, W.L. Shi, Y.L. Li, W.S. Guan, Construction of Z-scheme Fe₃O₄/BiOCl/BiOI heterojunction with superior recyclability for improved photocatalytic activity towards tetracycline degradation, J. Alloys Compd. 893 (2022) 162251
[78] S. Asadzadeh-Khaneghah, A. Habibi-Yangjeh, S. Vadivel, Fabrication of novel g-C₃N₄ nanosheet/carbon dots/Ag₆Si₂O₇ nanocomposites with high stability and enhanced visible-light photocatalytic activity, J. Taiwan Inst. Chem. Eng. 103 (2019) 94–109
[79] F. Guo, X.L. Huang, Z.H. Chen, H.R. Sun, L.Z. Chen, Prominent co-catalytic effect of CoP nanoparticles anchored on high-crystalline g-C₃N₄ nanosheets for enhanced visible-light photocatalytic degradation of tetracycline in wastewater, Chem. Eng. J. 395 (2020) 125118
[80] P. Chen, Y.J. Gou, J.M. Ni, Y.M. Liang, B.Q. Yang, F.F. Jia, S.X. Song, Efficient Ofloxacin degradation with Co(II)-doped MoS₂ nano-flowers as PMS activator under visible-light irradiation, Chem. Eng. J. 401 (2020) 125978
[81] S.F. Tang, Enhanced photocatalytic performance of BiVO₄ for degradation of methylene blue under LED visible light irradiation assisted by peroxymonosulfate, Int. J. Electrochem. Sci. (2020) 2470–2480

Improvement of synergistic effect photocatalytic/peroxymonosulfate activation for degradation of amoxicillin using carbon dots anchored on rod-like CoFe₂O₄

Improvement of synergistic effect photocatalytic/peroxymonosulfate activation for degradation of amoxicillin using carbon dots anchored on rod-like CoFe₂O₄

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	Jingjing Pan, Haoran Sun, Keyi Chen, Yuhao Zhang, Pengnian Shan, Weilong Shi, Feng Guo. Nanodiamonds decorated yolk-shell ZnFe₂O₄ sphere as magnetically separable and recyclable composite for boosting antibiotic degradation performance[J]. 中国化学工程学报, 2023, 54(2): 162-172.
[2]	Duanlian Tang, Xiaoyan Chen, Jiayan Yan, Zhuo Xiong, Xiaoyu Lou, Changshen Ye, Jie Chen, Ting Qiu. Facile one-pot synthesis of a BiOBr/Bi₂WO₆ heterojunction with enhanced visible-light photocatalytic activity for tetracycline degradation[J]. 中国化学工程学报, 2023, 53(1): 222-231.
[3]	Weilong Shi, Jie Gao, Haoran Sun, Zhongyi Liu, Feng Guo, Lijing Wang. Highly efficient visible/near-infrared light photocatalytic degradation of antibiotic wastewater over 3D yolk-shell ZnFe₂O₄ supported 0D carbon dots with up-conversion property[J]. 中国化学工程学报, 2022, 49(9): 213-223.
[4]	Feng Guo, Chunli Shi, Wei Sun, Yanan Liu, Xue Lin, Weilong Shi. Pomelo biochar as an electron acceptor to modify graphitic carbon nitride for boosting visible-light-driven photocatalytic degradation of tetracycline[J]. 中国化学工程学报, 2022, 48(8): 1-11.
[5]	Hao Zhou, Qi Yin. Hydrothermal preparation of Nb-doped NaTaO₃ with enhanced photocatalytic activity for removal of organic dye[J]. 中国化学工程学报, 2022, 46(6): 142-149.
[6]	Linlan Wu, Zhengxin Jiao, Suhang Xun, Minqiang He, Lei Fan, Chao Wang, Wenshu Yang, Wenshuai Zhu, Huaming Li. Photocatalytic oxidative of Keggin-type polyoxometalate ionic liquid for enhanced extractive desulfurization in binary deep eutectic solvents[J]. 中国化学工程学报, 2022, 44(4): 205-211.
[7]	Xiaoqing Yan, Hua An, Zihao Chen, Guidong Yang. Significantly enhanced charge transfer efficiency and surface reaction on NiP₂/g-C₃N₄ heterojunction for photocatalytic hydrogen evolution[J]. 中国化学工程学报, 2022, 43(3): 31-39.
[8]	Tao Yang, Fen Liu, Houfeng Xiong, Qiyong Yang, Fushan Chen, Changchao Zhan. Fouling process and anti-fouling mechanisms of dynamic membrane assisted by photocatalytic oxidation under sub-critical fluxes[J]. 中国化学工程学报, 2019, 27(8): 1798-1806.
[9]	Yangyang Yu, Kejing Wu, Shiyu Lu, Kui Ma, Shan Zhong, Hegui Zhang, Yingming Zhu, Jing Guo, Hairong Yue, Changjun Liu, Siyang Tang, Bin Liang. Engineering an ultrathin amorphous TiO₂ layer for boosting the weatherability of TiO₂ pigment with high lightening power[J]. 中国化学工程学报, 2019, 27(11): 2825-2834.
[10]	Yongbing Xie, Yingying Chen, Jin Yang, Chenming Liu, He Zhao, Hongbin Cao. Distinct synergetic effects in the ozone enhanced photocatalytic degradation of phenol and oxalic acid with Fe³⁺/TiO₂ catalyst[J]. Chinese Journal of Chemical Engineering, 2018, 26(7): 1528-1535.
[11]	Abdus Samad, Shamim Ahsan, Ikki Tateishi, Mai Furukawa, Hideyuki Katsumata, Tohru Suzuki, Satoshi Kaneco. Indirect photocatalytic reduction of arsenate to arsenite in aqueous solution with TiO₂ in the presence of hole scavengers[J]. Chinese Journal of Chemical Engineering, 2018, 26(3): 529-533.
[12]	Feng Zhang, Zhilong Xu, Kun Wang, Rizhi Chen, Zhaoxiang Zhong, Weihong Xing. Controllable preparation of ZnO porous flower through a membrane dispersion reactor and their photocatalytic properties[J]. Chinese Journal of Chemical Engineering, 2018, 26(10): 2192-2198.
[13]	Lianwei Shan, Jinbo Mi, Limin Dong, Zhidong Han, Bo Liu. Enhanced Photocatalytic Properties of Silver Oxide Loaded Bismuth Vanadate[J]. Chinese Journal of Chemical Engineering, 2014, 22(8): 909-913.
[14]	周亚松. TiO₂及TiO₂-SiO₂复合氧化物特性及其降解水中有机污染物的光催化活性[J]. , 2003, 11(6): 665-670.
[15]	史载锋, 范益群, 徐南平, 时钧. Kinetics of Photocatalytic Degradation of Methylene Blue overTiO₂ Particles in Aqueous Suspensions[J]. , 2000, 8(1): 15-19.