SCI和EI收录∣中国化工学会会刊

中国化学工程学报 ›› 2023, Vol. 56 ›› Issue (4): 225-232.DOI: 10.1016/j.cjche.2022.09.015

• Full Length Article • 上一篇    下一篇

Theoretical and experimental study on the inhibition of jet fuel oxidation by diarylamine

Tinghao Jia1,2,3, Yunbo Yu1,2, Qing Liu3, Yao Yang1,2, Ji-Jun Zou3,4, Xiangwen Zhang3,4, Lun Pan3,4   

  1. 1. Zhejiang Provincial Key Laboratory of Advanced Chemical Engineering Manufacture Technology, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, China;
    2. ZJU-Hangzhou Global Scientific and Technological Innovation Center, Zhejiang University, Hangzhou 311200, China;
    3. Key Laboratory for Green Chemical Technology of the Ministry of Education, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China;
    4. Haihe Laboratory of Sustainable Chemical Transformations, Tianjin 300192, China
  • 收稿日期:2022-07-21 修回日期:2022-09-06 出版日期:2023-04-28 发布日期:2023-06-13
  • 通讯作者: Lun Pan,E-mail:panlun76@tju.edu.cn
  • 基金资助:
    The authors appreciate the financial support from the Postdoctoral Science Foundation of China (2021M702810), the Haihe Laboratory of Sustainable Chemical Transformations (CYZC202103), and the National Natural Science Foundation of China (21978200 and 22222808).

Theoretical and experimental study on the inhibition of jet fuel oxidation by diarylamine

Tinghao Jia1,2,3, Yunbo Yu1,2, Qing Liu3, Yao Yang1,2, Ji-Jun Zou3,4, Xiangwen Zhang3,4, Lun Pan3,4   

  1. 1. Zhejiang Provincial Key Laboratory of Advanced Chemical Engineering Manufacture Technology, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, China;
    2. ZJU-Hangzhou Global Scientific and Technological Innovation Center, Zhejiang University, Hangzhou 311200, China;
    3. Key Laboratory for Green Chemical Technology of the Ministry of Education, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China;
    4. Haihe Laboratory of Sustainable Chemical Transformations, Tianjin 300192, China
  • Received:2022-07-21 Revised:2022-09-06 Online:2023-04-28 Published:2023-06-13
  • Contact: Lun Pan,E-mail:panlun76@tju.edu.cn
  • Supported by:
    The authors appreciate the financial support from the Postdoctoral Science Foundation of China (2021M702810), the Haihe Laboratory of Sustainable Chemical Transformations (CYZC202103), and the National Natural Science Foundation of China (21978200 and 22222808).

摘要: Antioxidants addition is believed as a facile and effective way to improve jet fuel thermal oxidation stability. However, amine antioxidants, as one of the most important antioxidants, have not received sufficient attention in the field of jet fuel autoxidation yet. Herein, the inhibition efficiency and mechanism of decane and exo-tetrahydrodicyclopentadiene (THDCPD) oxidation by di-4-tert-butylphenylamine (diarylamine) was experimentally and theoretically investigated. The results show that diarylamine can significantly inhibit decane oxidation but is less efficient for THDCPD oxidation, which is attributed to the higher energy barrier of retro-carbonyl-ene reaction (rate-determining step) in THDCPD than that in decane during diarylamine regeneration. However, the addition of diarylamine will cause undesirable color change after accelerated oxidation and produce slightly more deposits during high-temperature thermal oxidative stress for both decane and THDCPD. The results provide significant implications for the future design of effective antioxidant additives for high-performance jet fuel.

关键词: Jet fuel, Thermal oxidation stability, High-energy–density fuel, Diarylamine, Antioxidation mechanism

Abstract: Antioxidants addition is believed as a facile and effective way to improve jet fuel thermal oxidation stability. However, amine antioxidants, as one of the most important antioxidants, have not received sufficient attention in the field of jet fuel autoxidation yet. Herein, the inhibition efficiency and mechanism of decane and exo-tetrahydrodicyclopentadiene (THDCPD) oxidation by di-4-tert-butylphenylamine (diarylamine) was experimentally and theoretically investigated. The results show that diarylamine can significantly inhibit decane oxidation but is less efficient for THDCPD oxidation, which is attributed to the higher energy barrier of retro-carbonyl-ene reaction (rate-determining step) in THDCPD than that in decane during diarylamine regeneration. However, the addition of diarylamine will cause undesirable color change after accelerated oxidation and produce slightly more deposits during high-temperature thermal oxidative stress for both decane and THDCPD. The results provide significant implications for the future design of effective antioxidant additives for high-performance jet fuel.

Key words: Jet fuel, Thermal oxidation stability, High-energy–density fuel, Diarylamine, Antioxidation mechanism