Boost activation of peroxymonosulfate by iron doped K2-xMn8O16: Mechanism and properties

doi:10.1016/j.cjche.2022.08.020

中国化学工程学报 ›› 2023, Vol. 57 ›› Issue (5): 88-97.DOI: 10.1016/j.cjche.2022.08.020

• Full Length Article • 上一篇下一篇

Boost activation of peroxymonosulfate by iron doped K_2-xMn₈O₁₆: Mechanism and properties

Linlin Su¹, Meijun Chen¹, Li Gong², Hua Yang¹, Chao Chen¹, Jun Wu¹, Ling Luo¹, Gang Yang¹, Lulu Long¹

1. Institute of Ecological and Environmental Sciences, Sichuan Agricultural University, Chengdu 611130, China;
2. Sichuan Keyuan Testing Center of Engineering Technology, Chengdu 610091, China

收稿日期:2022-06-05 修回日期:2022-08-15 出版日期:2023-05-28 发布日期:2023-07-08
通讯作者: Lulu Long,E-mail:lululong@sicau.edu.cn
基金资助:
This work is supported by the National Natural Science Foundation of China (21806115), Sichuan Science and Technology Program (2020YJ0149), the Power Construction of China (P42819, DJ-ZDXM-2019-42) and the Supported by Sichuan Science and Technology Program (2021ZDZX0012).

Boost activation of peroxymonosulfate by iron doped K_2-xMn₈O₁₆: Mechanism and properties

Linlin Su¹, Meijun Chen¹, Li Gong², Hua Yang¹, Chao Chen¹, Jun Wu¹, Ling Luo¹, Gang Yang¹, Lulu Long¹

1. Institute of Ecological and Environmental Sciences, Sichuan Agricultural University, Chengdu 611130, China;
2. Sichuan Keyuan Testing Center of Engineering Technology, Chengdu 610091, China

Received:2022-06-05 Revised:2022-08-15 Online:2023-05-28 Published:2023-07-08
Contact: Lulu Long,E-mail:lululong@sicau.edu.cn
Supported by:
This work is supported by the National Natural Science Foundation of China (21806115), Sichuan Science and Technology Program (2020YJ0149), the Power Construction of China (P42819, DJ-ZDXM-2019-42) and the Supported by Sichuan Science and Technology Program (2021ZDZX0012).

摘要/Abstract

摘要： Among the numerous transition metal catalysts, manganese-based compounds are considered as promising peroxymonosulfate (PMS) catalysts due to their low cost and environmental friendliness, such as cryptomelane manganese oxide (K_2-xMn₈O₁₆: abbreviation KMnO). However, the limited catalytic performance of KMnO limits its practical application. In this work, iron-doped KMnO (Fe-KMnO) was prepared by one-step hydrothermal method to optimize its catalytic performance. Compared with KMnO/PMS system, Fe-KMnO/PMS system possessed more excellent removal efficiency of tetracycline (TC). Meanwhile, the Fe-KMnO/PMS system also exhibited good practical application potential and excellent stability. The mechanism of Fe-KMnO activation of PMS was further analyzed in detail. It was found that Fe participated in the redox of high-valent Mn, which promoted the activation of PMS. Moreover, The Fe site as an adsorption site enhanced the TC enrichment ability of the catalyst, reducing the mass transfer resistance and further enhancing the TC removal ability of Fe-KMnO/PMS system. This work not only provides an excellent PMS catalyst, but also offers new insights into the mechanism of PMS activation by bimetallic manganese-based catalysts.

关键词: Catalyst, Environment, Waste water, Peroxymonosulfate, K_2-xMn₈O₁₆, Iron doping

Abstract: Among the numerous transition metal catalysts, manganese-based compounds are considered as promising peroxymonosulfate (PMS) catalysts due to their low cost and environmental friendliness, such as cryptomelane manganese oxide (K_2-xMn₈O₁₆: abbreviation KMnO). However, the limited catalytic performance of KMnO limits its practical application. In this work, iron-doped KMnO (Fe-KMnO) was prepared by one-step hydrothermal method to optimize its catalytic performance. Compared with KMnO/PMS system, Fe-KMnO/PMS system possessed more excellent removal efficiency of tetracycline (TC). Meanwhile, the Fe-KMnO/PMS system also exhibited good practical application potential and excellent stability. The mechanism of Fe-KMnO activation of PMS was further analyzed in detail. It was found that Fe participated in the redox of high-valent Mn, which promoted the activation of PMS. Moreover, The Fe site as an adsorption site enhanced the TC enrichment ability of the catalyst, reducing the mass transfer resistance and further enhancing the TC removal ability of Fe-KMnO/PMS system. This work not only provides an excellent PMS catalyst, but also offers new insights into the mechanism of PMS activation by bimetallic manganese-based catalysts.

Key words: Catalyst, Environment, Waste water, Peroxymonosulfate, K_2-xMn₈O₁₆, Iron doping

Linlin Su, Meijun Chen, Li Gong, Hua Yang, Chao Chen, Jun Wu, Ling Luo, Gang Yang, Lulu Long. Boost activation of peroxymonosulfate by iron doped K_2-xMn₈O₁₆: Mechanism and properties[J]. 中国化学工程学报, 2023, 57(5): 88-97.

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Boost activation of peroxymonosulfate by iron doped K_2-xMn₈O₁₆: Mechanism and properties

Boost activation of peroxymonosulfate by iron doped K_2-xMn₈O₁₆: Mechanism and properties

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