Biological oyster shell waste enhances polyphenylene sulfide composites and endows them with antibacterial properties

doi:10.1016/j.cjche.2022.08.022

中国化学工程学报 ›› 2023, Vol. 57 ›› Issue (5): 118-131.DOI: 10.1016/j.cjche.2022.08.022

• Full Length Article • 上一篇下一篇

Biological oyster shell waste enhances polyphenylene sulfide composites and endows them with antibacterial properties

Chi-Hui Tsou^1,2,3, Rui Zeng^1,2, Neng Wan^1,2, Manuel Reyes De Guzman^1,2, Xue-Fei Hu^1,2, Tao Yang^1,3, Chen Gao^1,2, Xiaomei Wei^1,2, Jia Yi^1,2, Li Lan^1,2, Rui-Tao Yang^1,2, Ya-Li Sun¹

1. School of Materials Science and Engineering, Sichuan University of Science & Engineering, Zigong 643000, China;
2. Material Corrosion and Protection Key Laboratory of Sichuan Province, Sichuan University of Science & Engineering, Zigong 643000, China;
3. Sichuan Zhixiangyi Technology Co. Ltd., Chengdu 610051, China

收稿日期:2022-05-16 修回日期:2022-08-28 出版日期:2023-05-28 发布日期:2023-07-08
通讯作者: Chi-Hui Tsou,E-mail:mayko0301@hotmail.com,tsou@suse.edu.cn;Chen Gao,E-mail:19871016gc@sohu.com
基金资助:
The authors would like to acknowledge the financial support from the following organizations:Sichuan Province Science and Technology Support Program (2022JDTD0016, 2020YFG0176); Chengdu Science and Technology (2021-RC02-00005-CG); Sichuan Golden-Elephant Sincerity Chemical Co., Ltd (HX2020019); Zigong City Science and Technology (2019CXRC01, 2020YGJC13); Opening Project of Material Corrosion and Protection Key Laboratory of Sichuan Province (2019CL05, 2020CL19, 2018CL07); Opening Project of Sichuan Province, the Foundation of Introduced Talent of Sichuan University of Science and Engineering (2017RCL16, 2019RC05, 2019RC07, 2020RC16); the Opening Project of Key Laboratories of Fine Chemicals and Surfactants in Sichuan Provincial Universities (2020JXY04); Xi'an Weijingyi Art and Culture Communication Co., Ltd (HX2021385).

Biological oyster shell waste enhances polyphenylene sulfide composites and endows them with antibacterial properties

Chi-Hui Tsou^1,2,3, Rui Zeng^1,2, Neng Wan^1,2, Manuel Reyes De Guzman^1,2, Xue-Fei Hu^1,2, Tao Yang^1,3, Chen Gao^1,2, Xiaomei Wei^1,2, Jia Yi^1,2, Li Lan^1,2, Rui-Tao Yang^1,2, Ya-Li Sun¹

1. School of Materials Science and Engineering, Sichuan University of Science & Engineering, Zigong 643000, China;
2. Material Corrosion and Protection Key Laboratory of Sichuan Province, Sichuan University of Science & Engineering, Zigong 643000, China;
3. Sichuan Zhixiangyi Technology Co. Ltd., Chengdu 610051, China

Received:2022-05-16 Revised:2022-08-28 Online:2023-05-28 Published:2023-07-08
Contact: Chi-Hui Tsou,E-mail:mayko0301@hotmail.com,tsou@suse.edu.cn;Chen Gao,E-mail:19871016gc@sohu.com
Supported by:
The authors would like to acknowledge the financial support from the following organizations:Sichuan Province Science and Technology Support Program (2022JDTD0016, 2020YFG0176); Chengdu Science and Technology (2021-RC02-00005-CG); Sichuan Golden-Elephant Sincerity Chemical Co., Ltd (HX2020019); Zigong City Science and Technology (2019CXRC01, 2020YGJC13); Opening Project of Material Corrosion and Protection Key Laboratory of Sichuan Province (2019CL05, 2020CL19, 2018CL07); Opening Project of Sichuan Province, the Foundation of Introduced Talent of Sichuan University of Science and Engineering (2017RCL16, 2019RC05, 2019RC07, 2020RC16); the Opening Project of Key Laboratories of Fine Chemicals and Surfactants in Sichuan Provincial Universities (2020JXY04); Xi'an Weijingyi Art and Culture Communication Co., Ltd (HX2021385).

摘要/Abstract

摘要： To date, there is no research that deals with biological waste as fillers in polyphenylene sulfide (PPS). In this study, oyster shells were recycled and treated to prepare thermally-treated oyster shells (TOS), which were used as PPS fillers to make new bio-based antibacterial composite materials. The effect of varying the content of TOS was studied by means of structure and performance characterization. PPS/TOS composites were demonstrated to have an antibacterial effect on the growth of E coli and S. aureus. Qualitative analysis showed that when the TOS content was ≥ 30% and 40%, the composite materials had an apparent inhibition zone. Quantitative analysis showed that the antibacterial activity increased with the TOS content. Fourier transform infrared spectroscopy indicated the formation of hydrogen bonds between the molecular chains of TOS and PPS and the occurrence of a coordination reaction. At 10% TOS, the composite tensile strength reached a maximum value of 72.5 MPa, which is 9.65% higher than that of pure PPS. The trend of bending properties is the same as that of tensile properties, showing that the maximum property was reached for the composite with 10% TOS. At the same time, the crystallinity and contact angle were the highest, and the permeability coefficient was the lowest. The fatigue test results indicated that for the composite with 10% TOS, the tensile strength was 23% lower than static tensile strength, and the yield strength was 10% lower than the static yield strength. The results of the study showed that TOS not only could reduce the cost of PPS, but also could impart antibacterial properties and enhance the mechanical and, barrier properties, the thermostability, as well as the crystallinity.

关键词: Oyster shell powder, Polyphenylene sulfide (PPS), Antibacterial properties, Filler, Composite material, Fatigue

Abstract: To date, there is no research that deals with biological waste as fillers in polyphenylene sulfide (PPS). In this study, oyster shells were recycled and treated to prepare thermally-treated oyster shells (TOS), which were used as PPS fillers to make new bio-based antibacterial composite materials. The effect of varying the content of TOS was studied by means of structure and performance characterization. PPS/TOS composites were demonstrated to have an antibacterial effect on the growth of E coli and S. aureus. Qualitative analysis showed that when the TOS content was ≥ 30% and 40%, the composite materials had an apparent inhibition zone. Quantitative analysis showed that the antibacterial activity increased with the TOS content. Fourier transform infrared spectroscopy indicated the formation of hydrogen bonds between the molecular chains of TOS and PPS and the occurrence of a coordination reaction. At 10% TOS, the composite tensile strength reached a maximum value of 72.5 MPa, which is 9.65% higher than that of pure PPS. The trend of bending properties is the same as that of tensile properties, showing that the maximum property was reached for the composite with 10% TOS. At the same time, the crystallinity and contact angle were the highest, and the permeability coefficient was the lowest. The fatigue test results indicated that for the composite with 10% TOS, the tensile strength was 23% lower than static tensile strength, and the yield strength was 10% lower than the static yield strength. The results of the study showed that TOS not only could reduce the cost of PPS, but also could impart antibacterial properties and enhance the mechanical and, barrier properties, the thermostability, as well as the crystallinity.

Key words: Oyster shell powder, Polyphenylene sulfide (PPS), Antibacterial properties, Filler, Composite material, Fatigue

Chi-Hui Tsou, Rui Zeng, Neng Wan, Manuel Reyes De Guzman, Xue-Fei Hu, Tao Yang, Chen Gao, Xiaomei Wei, Jia Yi, Li Lan, Rui-Tao Yang, Ya-Li Sun. Biological oyster shell waste enhances polyphenylene sulfide composites and endows them with antibacterial properties[J]. 中国化学工程学报, 2023, 57(5): 118-131.

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Biological oyster shell waste enhances polyphenylene sulfide composites and endows them with antibacterial properties

Biological oyster shell waste enhances polyphenylene sulfide composites and endows them with antibacterial properties

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