Synthesis of porous carbon nanomaterials and their application in tetracycline removal from aqueous solutions

doi:10.1016/j.cjche.2022.12.014

中国化学工程学报 ›› 2023, Vol. 59 ›› Issue (7): 200-209.DOI: 10.1016/j.cjche.2022.12.014

• Full Length Article • 上一篇下一篇

Synthesis of porous carbon nanomaterials and their application in tetracycline removal from aqueous solutions

Sufei Wang¹, Mengjie Hao², Danyang Xiao¹, Tianmiao Zhang¹, Hua Li¹, Zhongshan Chen²

1. College of Life and Environmental Sciences, Minzu University of China, Beijing 100081, China;
2. College of Environmental Science and Technology, North China Electric Power University, Beijing 102206, China

收稿日期:2022-10-25 修回日期:2022-12-13 出版日期:2023-07-28 发布日期:2023-10-14
通讯作者: Hua Li,E-mail:lihua@muc.edu.cn;Zhongshan Chen,E-mail:zschen@necepu.edu.cn
基金资助:
Financial support from the National Natural Science Foundation of China (22276054) was acknowledged.

Synthesis of porous carbon nanomaterials and their application in tetracycline removal from aqueous solutions

Sufei Wang¹, Mengjie Hao², Danyang Xiao¹, Tianmiao Zhang¹, Hua Li¹, Zhongshan Chen²

1. College of Life and Environmental Sciences, Minzu University of China, Beijing 100081, China;
2. College of Environmental Science and Technology, North China Electric Power University, Beijing 102206, China

Received:2022-10-25 Revised:2022-12-13 Online:2023-07-28 Published:2023-10-14
Contact: Hua Li,E-mail:lihua@muc.edu.cn;Zhongshan Chen,E-mail:zschen@necepu.edu.cn
Supported by:
Financial support from the National Natural Science Foundation of China (22276054) was acknowledged.

摘要/Abstract

摘要： The low-cost and efficient elimination of tetracycline from wastewater and to decrease the concentration in soils, sediments, rivers, underground water, or lakes are crucial to human health. Herein, three-dimensional porous carbon nanomaterials were synthesized using glucose and NH₄Cl by sugar-blowing process at 900 ℃ and then oxidized under air atmosphere for surface functional group modification. The prepared 3D porous carbon nanomaterials were applied for the removal of tetracycline from aqueous solutions. The sorption isotherms were well simulated by the Langmuir model, with the calculated sorption capacity of 2378 mg·g^-1 for C-450 at pH = 6.5, which was the highest value of today’s reported materials. The porous carbon nanomaterials showed high stability at acidic conditions and selectivity in high salt concentrations. The good recycle ability and high removal efficiency of tetracycline from natural groundwater indicated the potential application of the porous carbon nanomaterials in natural environmental antibiotic pollution cleanup. The outstanding sorption properties were attributed to the structures, surface areas and functional groups, strong interactions such as H-bonding, π-π interaction, electrostatic attraction, etc. This paper highlighted the synthesis of porous carbon nanomaterials with high specific surfaces, high sorption capacities, stability, and reusability in organic chemicals’ pollution treatment.

关键词: Porous carbon nanomaterials, Tetracycline, Sorption, Pollution management

Abstract: The low-cost and efficient elimination of tetracycline from wastewater and to decrease the concentration in soils, sediments, rivers, underground water, or lakes are crucial to human health. Herein, three-dimensional porous carbon nanomaterials were synthesized using glucose and NH₄Cl by sugar-blowing process at 900 ℃ and then oxidized under air atmosphere for surface functional group modification. The prepared 3D porous carbon nanomaterials were applied for the removal of tetracycline from aqueous solutions. The sorption isotherms were well simulated by the Langmuir model, with the calculated sorption capacity of 2378 mg·g^-1 for C-450 at pH = 6.5, which was the highest value of today’s reported materials. The porous carbon nanomaterials showed high stability at acidic conditions and selectivity in high salt concentrations. The good recycle ability and high removal efficiency of tetracycline from natural groundwater indicated the potential application of the porous carbon nanomaterials in natural environmental antibiotic pollution cleanup. The outstanding sorption properties were attributed to the structures, surface areas and functional groups, strong interactions such as H-bonding, π-π interaction, electrostatic attraction, etc. This paper highlighted the synthesis of porous carbon nanomaterials with high specific surfaces, high sorption capacities, stability, and reusability in organic chemicals’ pollution treatment.

Key words: Porous carbon nanomaterials, Tetracycline, Sorption, Pollution management

Sufei Wang, Mengjie Hao, Danyang Xiao, Tianmiao Zhang, Hua Li, Zhongshan Chen. Synthesis of porous carbon nanomaterials and their application in tetracycline removal from aqueous solutions[J]. 中国化学工程学报, 2023, 59(7): 200-209.

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Synthesis of porous carbon nanomaterials and their application in tetracycline removal from aqueous solutions

Synthesis of porous carbon nanomaterials and their application in tetracycline removal from aqueous solutions

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