Two dimensional MoS2 finding its way towards constructing high-performance alkaline recovery membranes

doi:10.1016/j.cjche.2023.01.019

中国化学工程学报 ›› 2023, Vol. 60 ›› Issue (8): 155-164.DOI: 10.1016/j.cjche.2023.01.019

• Full Length Article • 上一篇下一篇

Two dimensional MoS₂ finding its way towards constructing high-performance alkaline recovery membranes

Xinxin Li, Hongwei Shao, Shichao Zhang, Yong Li, Jingjing Gu, Qiang Huang, Jin Ran

Anhui Key Laboratory of Advanced Catalytic Materials and Reaction Engineering, School of Chemistry and Chemical Engineering, Hefei University of Technology, Anhui 230009, China

收稿日期:2022-10-27 修回日期:2022-12-30 出版日期:2023-08-28 发布日期:2023-10-28
通讯作者: Jin Ran,E-mail:ranjin@hfut.edu.cn
基金资助:
This project has been partially supported by the National Key Research and Development Program of China (2022YFB3805102), and the National Natural Science Foundation of China (22278105, 21978062).

Two dimensional MoS₂ finding its way towards constructing high-performance alkaline recovery membranes

Xinxin Li, Hongwei Shao, Shichao Zhang, Yong Li, Jingjing Gu, Qiang Huang, Jin Ran

Anhui Key Laboratory of Advanced Catalytic Materials and Reaction Engineering, School of Chemistry and Chemical Engineering, Hefei University of Technology, Anhui 230009, China

Received:2022-10-27 Revised:2022-12-30 Online:2023-08-28 Published:2023-10-28
Contact: Jin Ran,E-mail:ranjin@hfut.edu.cn
Supported by:
This project has been partially supported by the National Key Research and Development Program of China (2022YFB3805102), and the National Natural Science Foundation of China (22278105, 21978062).

摘要/Abstract

摘要： The available alkaline recovery membranes are currently dominated by polymeric materials, but they suffer from a permeation-selectivity trade-off and inferior chemical resistance. Robust two dimensional (2D) lamellar membranes with sub-nanometer wide channels are promising candidates for discerning OH^- and other anions. Here, we report the development of alkaline recycling membranes through stacking MoS₂ nanosheets. Benefiting from the ordered and narrow 2D channels, MoS₂ membranes show excellent alkaline recovery performances. The OH^- dialysis coefficient () and separation factor (S) towards simulated OH^- and across the 500 nm thick MoS₂ laminates reach 6.9×10^-3 m·h^-1 and 34.3 respectively. Furthermore, the chemical environments of MoS₂ laminates were modulated by intercalating ionic poly(sodium 4-styrene sulfonate) (PSS@MoS₂). The and S values of PSS@MoS₂ membrane further improve to 11.7×10^-3 m·h^-1 and 49.8 respectively. Besides, both MoS₂ and PSS@MoS₂ membranes exhibit promising stability.

关键词: Alkaline recovery, Diffusion dialysis, Two dimensional membranes, MoS₂, Poly(sodium 4-styrene sulfonate)

Abstract: The available alkaline recovery membranes are currently dominated by polymeric materials, but they suffer from a permeation-selectivity trade-off and inferior chemical resistance. Robust two dimensional (2D) lamellar membranes with sub-nanometer wide channels are promising candidates for discerning OH^- and other anions. Here, we report the development of alkaline recycling membranes through stacking MoS₂ nanosheets. Benefiting from the ordered and narrow 2D channels, MoS₂ membranes show excellent alkaline recovery performances. The OH^- dialysis coefficient () and separation factor (S) towards simulated OH^- and across the 500 nm thick MoS₂ laminates reach 6.9×10^-3 m·h^-1 and 34.3 respectively. Furthermore, the chemical environments of MoS₂ laminates were modulated by intercalating ionic poly(sodium 4-styrene sulfonate) (PSS@MoS₂). The and S values of PSS@MoS₂ membrane further improve to 11.7×10^-3 m·h^-1 and 49.8 respectively. Besides, both MoS₂ and PSS@MoS₂ membranes exhibit promising stability.

Key words: Alkaline recovery, Diffusion dialysis, Two dimensional membranes, MoS₂, Poly(sodium 4-styrene sulfonate)

Xinxin Li, Hongwei Shao, Shichao Zhang, Yong Li, Jingjing Gu, Qiang Huang, Jin Ran. Two dimensional MoS₂ finding its way towards constructing high-performance alkaline recovery membranes[J]. 中国化学工程学报, 2023, 60(8): 155-164.

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Two dimensional MoS₂ finding its way towards constructing high-performance alkaline recovery membranes

Two dimensional MoS₂ finding its way towards constructing high-performance alkaline recovery membranes

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