Enhancing hydrophobicity via core–shell metal organic frameworks for high-humidity flue gas CO2 capture

doi:10.1016/j.cjche.2023.03.002

中国化学工程学报 ›› 2023, Vol. 61 ›› Issue (9): 82-89.DOI: 10.1016/j.cjche.2023.03.002

• Full Length Article • 上一篇下一篇

Enhancing hydrophobicity via core–shell metal organic frameworks for high-humidity flue gas CO₂ capture

Yinji Wan¹, Dekai Kong¹, Feng Xiong², Tianjie Qiu², Song Gao², Qiuning Zhang¹, Yefan Miao¹, Mulin Qin², Shengqiang Wu², Yonggang Wang², Ruiqin Zhong¹, Ruqiang Zou²

1. State Key Laboratory of Heavy Oil Processing, China University of Petroleum (Beijing), Beijing 102249, China;
2. Beijing Key Laboratory for Theory and Technology of Advanced Battery Materials, School of Materials Science and Engineering, Peking University, Beijing 100871, China

收稿日期:2022-10-27 修回日期:2023-03-10 出版日期:2023-09-28 发布日期:2023-12-14
通讯作者: Ruiqin Zhong,E-mail:rzhong@cup.edu.cn;Ruqiang Zou,E-mail:rzou@pku.edu.cn
基金资助:
This work was supported by the National Natural Science Foundation of China (51772329, 51972340, and 51825201).

Enhancing hydrophobicity via core–shell metal organic frameworks for high-humidity flue gas CO₂ capture

Yinji Wan¹, Dekai Kong¹, Feng Xiong², Tianjie Qiu², Song Gao², Qiuning Zhang¹, Yefan Miao¹, Mulin Qin², Shengqiang Wu², Yonggang Wang², Ruiqin Zhong¹, Ruqiang Zou²

1. State Key Laboratory of Heavy Oil Processing, China University of Petroleum (Beijing), Beijing 102249, China;
2. Beijing Key Laboratory for Theory and Technology of Advanced Battery Materials, School of Materials Science and Engineering, Peking University, Beijing 100871, China

Received:2022-10-27 Revised:2023-03-10 Online:2023-09-28 Published:2023-12-14
Contact: Ruiqin Zhong,E-mail:rzhong@cup.edu.cn;Ruqiang Zou,E-mail:rzou@pku.edu.cn
Supported by:
This work was supported by the National Natural Science Foundation of China (51772329, 51972340, and 51825201).

摘要/Abstract

摘要： Developing metal–organic framework (MOF) materials with the moisture-resistant feature is highly desirable for CO₂ capture from highly humid flue gas. In this work, a new core–shell MOF@MOF composite using Mg-MOF-74 with high CO₂ capture capacity as a functional core and hydrophobic zeolitic imidazolate framework-8 (ZIF-8) as a protective shell is fabricated by the epitaxial growth method. Experimental results show that the CO₂ adsorption performance of the core–shell structured Mg-MOF-74@ZIF-8 composites from water-containing flue gas is enhanced along with their improved hydrophobicity. The dynamic breakthrough results show that the Mg-MOF-74@ZIF-8 with three assembled layers (Mg-MOF-74@ZIF-8-3) can capture 3.56 mmol·g^-1 CO₂ from wet CO₂/N₂ (V_CO₂ : V_N₂ = 15:85) mixtures, which outperforms Mg-MOF-74 (0.37 mmol·g^-1) and most of the reported physisorbents.

关键词: Core–shell, Mg-MOF-74@ZIF-8, CO₂ capture, Hydrophobic effect

Abstract: Developing metal–organic framework (MOF) materials with the moisture-resistant feature is highly desirable for CO₂ capture from highly humid flue gas. In this work, a new core–shell MOF@MOF composite using Mg-MOF-74 with high CO₂ capture capacity as a functional core and hydrophobic zeolitic imidazolate framework-8 (ZIF-8) as a protective shell is fabricated by the epitaxial growth method. Experimental results show that the CO₂ adsorption performance of the core–shell structured Mg-MOF-74@ZIF-8 composites from water-containing flue gas is enhanced along with their improved hydrophobicity. The dynamic breakthrough results show that the Mg-MOF-74@ZIF-8 with three assembled layers (Mg-MOF-74@ZIF-8-3) can capture 3.56 mmol·g^-1 CO₂ from wet CO₂/N₂ (V_CO₂ : V_N₂ = 15:85) mixtures, which outperforms Mg-MOF-74 (0.37 mmol·g^-1) and most of the reported physisorbents.

Key words: Core–shell, Mg-MOF-74@ZIF-8, CO₂ capture, Hydrophobic effect

Yinji Wan, Dekai Kong, Feng Xiong, Tianjie Qiu, Song Gao, Qiuning Zhang, Yefan Miao, Mulin Qin, Shengqiang Wu, Yonggang Wang, Ruiqin Zhong, Ruqiang Zou. Enhancing hydrophobicity via core–shell metal organic frameworks for high-humidity flue gas CO₂ capture[J]. 中国化学工程学报, 2023, 61(9): 82-89.

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Enhancing hydrophobicity via core–shell metal organic frameworks for high-humidity flue gas CO₂ capture

Enhancing hydrophobicity via core–shell metal organic frameworks for high-humidity flue gas CO₂ capture

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