An internal circulation iron–carbon micro-electrolysis reactor for aniline wastewater treatment: Parameter optimization, degradation pathways and mechanism

doi:10.1016/j.cjche.2023.05.009

中国化学工程学报 ›› 2023, Vol. 63 ›› Issue (11): 96-107.DOI: 10.1016/j.cjche.2023.05.009

• Full Length Article • 上一篇下一篇

An internal circulation iron–carbon micro-electrolysis reactor for aniline wastewater treatment: Parameter optimization, degradation pathways and mechanism

Yanhe Han¹, Han Xu¹, Lei Zhang^1,2, Xuejiao Ma¹, Yang Man³, Zhimin Su¹, Jing Wang¹

1. Department of Environmental Engineering, Beijing Institute of Petrochemical Technology, Beijing 102617, China;
2. SUEZ Environmental Technology (Beijing) Company Limited, Beijing 100026, China;
3. Beijing Ecological Environment Assessment and Complaint Center, Beijing 100006, China

收稿日期:2023-01-29 修回日期:2023-04-28 出版日期:2023-11-28 发布日期:2024-01-08
通讯作者: Yanhe Han,E-mail:hanyanhe@bipt.edu.cn;Xuejiao Ma,E-mail:maxuejiao@bipt.edu.cn
基金资助:
This work was supported by the National Natural Science Foundation of China (21677018), the Joint Fund of the Beijing Municipal Natural Science Foundation and Beijing Municipal Education Commission (KZ201810017024) and the Cross–Disciplinary Science Foundation from Beijing Institute of Petrochemical Technology (BIPTCSF–22032205003/014).

An internal circulation iron–carbon micro-electrolysis reactor for aniline wastewater treatment: Parameter optimization, degradation pathways and mechanism

Yanhe Han¹, Han Xu¹, Lei Zhang^1,2, Xuejiao Ma¹, Yang Man³, Zhimin Su¹, Jing Wang¹

1. Department of Environmental Engineering, Beijing Institute of Petrochemical Technology, Beijing 102617, China;
2. SUEZ Environmental Technology (Beijing) Company Limited, Beijing 100026, China;
3. Beijing Ecological Environment Assessment and Complaint Center, Beijing 100006, China

Received:2023-01-29 Revised:2023-04-28 Online:2023-11-28 Published:2024-01-08
Contact: Yanhe Han,E-mail:hanyanhe@bipt.edu.cn;Xuejiao Ma,E-mail:maxuejiao@bipt.edu.cn
Supported by:
This work was supported by the National Natural Science Foundation of China (21677018), the Joint Fund of the Beijing Municipal Natural Science Foundation and Beijing Municipal Education Commission (KZ201810017024) and the Cross–Disciplinary Science Foundation from Beijing Institute of Petrochemical Technology (BIPTCSF–22032205003/014).

摘要/Abstract

摘要： Aniline is a vital industrial raw material. However, highly-toxic aniline wastewater usually deteriorated effluent quality, posed a threat to human health and ecosystem safety. Therefore, this study reported a novel internal circulation iron-carbon micro-electrolysis (ICE) reactor to treat aniline wastewater. The effects of reaction time, pH, aeration rate and iron-carbon (Fe/C) ratio on the removal rate of aniline and the chemical oxygen demand were investigated using single-factor experiments. This process exhibited high aniline degradation performance of approximately 99.86% under optimal operating conditions (reaction time = 20 min, pH = 3, aeration rate = 0.5 m³·h^-1, and Fe/C = 1:2). Based on the experimental results, the response surface method was applied to optimize the aniline removal rate. The Box-Behnken method was used to obtain the interaction effects of three main factors. The result showed that the reaction time had a dominant effect on the removal rate of aniline. The highest aniline removal rate was obtained at pH of 2, aeration rate of 0.5 m³·h^-1 and reaction time of 30 min. Under optional experimental conditions, the aniline content of effluent was reduced to 3 mg·L^-1 and the removal rate was as high as 98.24%, within the 95% confidence interval (97.84%-99.32%) of the predicted values. The solution was treated and the reaction intermediates were identified by high-performance liquid chromatography, ultraviolet-visible spectroscopy, Fourier-transform infrared spectroscopy, gas chromatography-mass spectrometry, and ion chromatography. The main intermediates were phenol, benzoquinone, and carboxylic acid. These were used to propose the potential mechanism of aniline degradation in the ICE reactor. The results obtained in this study provide optimized conditions for the treatment of industrial wastewater containing aniline and can strengthen the understanding of the degradation mechanism of iron-carbon micro-electrolysis.

关键词: Aniline, Iron-carbon micro-electrolysis, Circulating fluidized bed, Waste water, Degradation

Abstract: Aniline is a vital industrial raw material. However, highly-toxic aniline wastewater usually deteriorated effluent quality, posed a threat to human health and ecosystem safety. Therefore, this study reported a novel internal circulation iron-carbon micro-electrolysis (ICE) reactor to treat aniline wastewater. The effects of reaction time, pH, aeration rate and iron-carbon (Fe/C) ratio on the removal rate of aniline and the chemical oxygen demand were investigated using single-factor experiments. This process exhibited high aniline degradation performance of approximately 99.86% under optimal operating conditions (reaction time = 20 min, pH = 3, aeration rate = 0.5 m³·h^-1, and Fe/C = 1:2). Based on the experimental results, the response surface method was applied to optimize the aniline removal rate. The Box-Behnken method was used to obtain the interaction effects of three main factors. The result showed that the reaction time had a dominant effect on the removal rate of aniline. The highest aniline removal rate was obtained at pH of 2, aeration rate of 0.5 m³·h^-1 and reaction time of 30 min. Under optional experimental conditions, the aniline content of effluent was reduced to 3 mg·L^-1 and the removal rate was as high as 98.24%, within the 95% confidence interval (97.84%-99.32%) of the predicted values. The solution was treated and the reaction intermediates were identified by high-performance liquid chromatography, ultraviolet-visible spectroscopy, Fourier-transform infrared spectroscopy, gas chromatography-mass spectrometry, and ion chromatography. The main intermediates were phenol, benzoquinone, and carboxylic acid. These were used to propose the potential mechanism of aniline degradation in the ICE reactor. The results obtained in this study provide optimized conditions for the treatment of industrial wastewater containing aniline and can strengthen the understanding of the degradation mechanism of iron-carbon micro-electrolysis.

Key words: Aniline, Iron-carbon micro-electrolysis, Circulating fluidized bed, Waste water, Degradation

Yanhe Han, Han Xu, Lei Zhang, Xuejiao Ma, Yang Man, Zhimin Su, Jing Wang. An internal circulation iron–carbon micro-electrolysis reactor for aniline wastewater treatment: Parameter optimization, degradation pathways and mechanism[J]. 中国化学工程学报, 2023, 63(11): 96-107.

参考文献

[1] T. Carreón, M.J. Hein, K.W. Hanley, S.M. Viet, A.M. Ruder, Bladder cancer incidence among workers exposed to o-toluidine, aniline and nitrobenzene at a rubber chemical manufacturing plant, Occup. Environ. Med. 71 (3) (2014) 175–182.
[2] A. Thakuri, M. Banerjee, A. Chatterjee, Microwave-assisted rapid and sustainable synthesis of unsymmetrical azo dyes by coupling of nitroarenes with aniline derivatives, iScience 25 (6) (2022) 104497.
[3] D.Q. Hu, Y.L. Zhou, X.F. Jiang, From aniline to phenol: Carbon-nitrogen bond activation via uranyl photoredox catalysis, Natl. Sci. Rev. 9 (6) (2021) nwab156.
[4] X.H. Li, X.D. Jin, N.N. Zhao, I. Angelidaki, Y.F. Zhang, Efficient treatment of aniline containing wastewater in bipolar membrane microbial electrolysis cell-Fenton system, Water Res. 119 (2017) 67–72.
[5] L.F. Ren, K. Chen, X.F. Zhang, Y.B. Xu, L. Chen, J.H. Shao, Y.L. He, Effect of aniline and antimony on anaerobic-anoxic-oxic system with novel amidoxime-modified polyacrylonitrile adsorbent for wastewater treatment, Bioresour. Technol. 351 (2022) 127082.
[6] M.Y. Badi, A. Esrafili, H. Pasalari, R.R. Kalantary, E. Ahmadi, M. Gholami, A. Azari, Degradation of dimethyl phthalate using persulfate activated by UV and ferrous ions: Optimizing operational parameters mechanism and pathway, J. Environ. Health Sci. Eng. 17 (2) (2019) 685–700.
[7] I. Ali, S. Afshinb, Y. Poureshgh, A. Azari, Y. Rashtbari, A. Feizizadeh, A. Hamzezadeh, M. Fazlzadeh, Green preparation of activated carbon from pomegranate peel coated with zero-valent iron nanoparticles (nZVI) and isotherm and kinetic studies of amoxicillin removal in water, Environ. Sci. Pollut. Res. Int. 27 (29) (2020) 36732–36743.
[8] A.M. Hidalgo, G. León, M. Gómez, M.D. Murcia, M.D. Bernal, S. Ortega, Polyamide nanofiltration membranes to remove aniline in aqueous solutions, Environ. Technol. 35 (9–12) (2014) 1175–1181.
[9] A. Azari, R. Nabizadeh, A.H. Mahvi, S. Nasseri, Magnetic multi-walled carbon nanotubes-loaded alginate for treatment of industrial dye manufacturing effluent: Adsorption modelling and process optimisation by central composite face-central design, Int. J. Environ. Anal. Chem. 103 (7) (2023) 1509–1529.
[10] A. Azari, R. Nabizadeh, A.H. Mahvi, S. Nasseri, Integrated Fuzzy AHP-TOPSIS for selecting the best color removal process using carbon-based adsorbent materials: Multi-criteria decision making vs. systematic review approaches and modeling of textile wastewater treatment in real conditions, Int. J. Environ. Anal. Chem. 102 (18) (2022) 7329–7344.
[11] A. Azari, M. Malakoutian, K. Yaghmaeain, N. Jaafarzadeh, N. Shariatifar, G. Mohammadi, M.R. Masoudi, R. Sadeghi, S. Hamzeh, H. Kamani, Magnetic NH₂-MIL-101(Al)/Chitosan nanocomposite as a novel adsorbent for the removal of azithromycin: Modeling and process optimization, Sci. Rep. 12 (1) (2022) 18990.
[12] A. Azari, M. Abtahi, R. Saeedi, A.R. Yari, M.H. Vaziri, G. Mohammadi, Integrated ultrasound-assisted magnetic solid-phase extraction for efficient determination and pre-concentration of polycyclic aromatic hydrocarbons from high-consumption soft drinks and non-alcoholic beers in Iran, J. Sep. Sci. 45 (16) (2022) 3139–3149.
[13] S.Y. Hashemi, M. Yegane Badi, H. Pasalari, A. Azari, H. Arfaeinia, A. Kiani, Degradation of Ceftriaxone from aquatic solution using a heterogeneous and reusable O₃/UV/Fe₃O₄@TiO₂ systems: Operational factors, kinetics and mineralisation, Int. J. Environ. Anal. Chem. 102 (18) (2022) 6904–6920.
[14] H. Abdoallahzadeh, Y. Rashtbari, J.H.P. Américo-Pinheiro, A. Azari, S. Afshin, M. Fazlzadeh, Y. Poureshgh, Application of green and red local soils as a catalyst for catalytic ozonation of fulvic acid: Experimental parameters and kinetic, Biomass Convers. Biorefin. (2023) 1–10.
[15] F. Rabiee, M. Sarkhosh, S. Azizi, A. Jahantigh, S.Y. Hashemi, M. Baziar, M. Gholami, A. Azari, The superior decomposition of 2, 4-Dinitrophenol under ultrasound-assisted Fe₃O₄@TiO₂ magnetic nanocomposite: Process modeling and optimization, Effect of various oxidants and Degradation pathway studies, Int. J. Environ. Anal. Chem. (2022) 1–23.
[16] M. Kermani, M. Dowlati, M. Gholami, H.R. Sobhi, A. Azari, A. Esrafili, M. Yeganeh, H.R. Ghaffari, A global systematic review, meta-analysis and health risk assessment on the quantity of Malathion, Diazinon and Chlorpyrifos in Vegetables, Chemosphere 270 (2021) 129382.
[17] W.S. Chai, X.Y. Zhu, W. Liu, W.D. Zhang, Z.Y. Zhou, Z.Q. Ren, Extraction of aniline from wastewater: Equilibria, model, and fitting of apparent extraction equilibrium constants, RSC Adv. 6 (8) (2016) 6125–6132.
[18] H. Chen, C.R. Sun, R.H. Liu, M.Z. Yuan, Z.H. Mao, Q. Wang, H.B. Zhou, H.N. Cheng, W.H. Zhan, Y.G. Wang, Enrichment and domestication of a microbial consortium for degrading aniline, J. Water Process. Eng. 42 (2021) 102108.
[19] H.N. Cheng, M.Z. Yuan, Q. Zeng, H.B. Zhou, W.H. Zhan, H. Chen, Z.H. Mao, Y.G. Wang, Efficient reduction of reactive black 5 and Cr(Ⅵ) by a newly isolated bacterium of Ochrobactrum anthropi, J. Hazard. Mater. 406 (2021) 124641.
[20] Q.Y. Liu, Y.X. Liu, X.J. Lu, Combined photo-Fenton and biological oxidation for the treatment of aniline wastewater, Procedia Environ. Sci. 12 (2012) 341–348.
[21] Y. Chen, Y.J. Gao, T.T. Liu, Z. Zhang, W.S. Li, Activated persulfate by iron-carbon micro electrolysis used for refractory organics degradation in wastewater: A review, Water Sci. Technol. 86 (4) (2022) 690–713.
[22] X.J. Cui, M.P. Zhang, Y.J. Ding, S.S. Sun, S.B. He, P. Yan, Enhanced nitrogen removal via iron-carbon micro-electrolysis in surface flow constructed wetlands: Selecting activated carbon or biochar? Sci. Total Environ. 815 (2022) 152800.
[23] M.Y. Hu, T.L. Luo, Q.L. Li, Y.F. Xie, G. Liu, L.J. Wang, W.J.G.M. Peijnenburg, Remediation of low C/N wastewater by iron-carbon micro-electrolysis coupled with biological denitrification: Performance, mechanisms, and application, J. Water Process. Eng. 48 (2022) 102899.
[24] Z.H. Sun, Z.H. Xu, Y.W. Zhou, D.F. Zhang, W.F. Chen, Effects of different scrap iron as anode in Fe-C micro-electrolysis system for textile wastewater degradation, Environ. Sci. Pollut. Res. Int. 26 (26) (2019) 26869–26882.
[25] Z.H. Xu, Y.Q. Gao, Z.H. Sun, D.F. Zhang, Y.W. Zhou, W.F. Chen, New insights into the reinforced reduction performance of Fe⁰/C internal electrolysis activated by persulfate for p-nitrophenol removal, Chemosphere 254 (2020) 126899.
[26] Y.H. Han, M.M. Qi, L. Zhang, Y.M. Sang, M.L. Liu, T.T. Zhao, J.F. Niu, S.Q. Zhang, Degradation of nitrobenzene by synchronistic oxidation and reduction in an internal circulation microelectrolysis reactor, J. Hazard. Mater. 365 (2019) 448–456.
[27] D.W. Ying, J. Peng, X.Y. Xu, K. Li, Y.L. Wang, J.P. Jia, Treatment of mature landfill leachate by internal micro-electrolysis integrated with coagulation: A comparative study on a novel sequencing batch reactor based on zero valent iron, J. Hazard. Mater. 229-230 (2012) 426–433.
[28] Y.H. Han, H. Li, M.L. Liu, Y.M. Sang, C.Z. Liang, J.Q. Chen, Purification treatment of dyes wastewater with a novel micro-electrolysis reactor, Sep. Purif. Technol. 170 (2016) 241–247.
[29] X.Y. Yang, Interior microelectrolysis oxidation of polyester wastewater and its treatment technology, J. Hazard. Mater. 169 (1–3) (2009) 480–485.
[30] Y.T. Zhang, H.B. Lun, Research on micro-electrolysis method to treat the chrome-containing steel wastewater, Appl. Mech. Mater. 448-453 (2013) 620–624.
[31] M. Räsänen, T. Eerikäinen, H. Ojamo, Characterization and hydrodynamics of a novel helix airlift reactor, Chem. Eng. Process. 108 (2016) 44–57.
[32] K. Wadaugsorn, S. Limtrakul, T. Vatanatham, P.A. Ramachandran, Hydrodynamic behaviors and mixing characteristics in an internal loop airlift reactor based on CFD simulation, Chem. Eng. Res. Des. 113 (2016) 125–139.
[33] Y.H. Han, L. Zhang, M.L. Liu, J.F. Niu, Numerical simulation of the hydrodynamic behavior and the synchronistic oxidation and reduction in an internal circulation micro-electrolysis reactor, Chem. Eng. J. 381 (2020) 122709.
[34] L. Zhang, M.Y. Wu, Y.H. Han, M.L. Liu, J.F. Niu, Structural parameter optimization for novel internal-loop iron-carbon micro-electrolysis reactors using computational fluid dynamics, Chin. J. Chem. Eng. 27 (4) (2019) 737–744.
[35] M. Yeganeh, A. Azari, H.R. Sobhi, M. Farzadkia, A. Esrafili, M. Gholami, A comprehensive systematic review and meta-analysis on the extraction of pesticide by various solid phase-based separation methods: A case study of malathion, Int. J. Environ. Anal. Chem. 103 (5) (2023) 1068–1085.
[36] B. Lai, Y.X. Zhou, H.K. Qin, C.Y. Wu, C.C. Pang, Y. Lian, J.X. Xu, Pretreatment of wastewater from acrylonitrile-butadiene-styrene (ABS) resin manufacturing by microelectrolysis, Chem. Eng. J. 179 (2012) 1–7.
[37] C. Zhang, M.H. Zhou, G.B. Ren, X.M. Yu, L. Ma, J. Yang, F.K. Yu, Heterogeneous electro-Fenton using modified iron-carbon as catalyst for 2, 4-dichlorophenol degradation: Influence factors, mechanism and degradation pathway, Water Res. 70 (2015) 414–424.
[38] W.W. Ma, Y.X. Han, C.Y. Xu, H.J. Han, W.C. Ma, H. Zhu, K. Li, D.X. Wang, Enhanced degradation of phenolic compounds in coal gasification wastewater by a novel integration of micro-electrolysis with biological reactor (MEBR) under the micro-oxygen condition, Bioresour. Technol. 251 (2018) 303–310.
[39] X.Y. Zhu, X.J. Chen, Z.M. Yang, Y. Liu, Z.Y. Zhou, Z.Q. Ren, Investigating the influences of electrode material property on degradation behavior of organic wastewaters by iron-carbon micro-electrolysis, Chem. Eng. J. 338 (2018) 46–54.
[40] Q. Zhang, Treatment of oilfield produced water using Fe/C micro-electrolysis assisted by zero-valent copper and zero-valent aluminium, Environ. Technol. 36 (1–4) (2015) 515–520.
[41] M.A. Bezerra, R.E. Santelli, E.P. Oliveira, L.S. Villar, L.A. Escaleira, Response surface methodology (RSM) as a tool for optimization in analytical chemistry, Talanta 76 (5) (2008) 965–977.
[42] M.Z. Ahmad, S. Ehtisham-Ul-Haque, N. Nisar, K. Qureshi, A. Ghaffar, M. Abbas, J. Nisar, M. Iqbal, Detoxification of photo-catalytically treated 2-chlorophenol: Optimization through response surface methodology, Water Sci. Technol. 76 (2) (2017) 323–336.
[43] K.J. Wan, G.Q. Wang, W.T. Bo, S.W. Xue, Z.Y. Miao, A sandwich structure of fulvic acid and PMIDA-modified LDHs for the simultaneous removal of Cu²⁺ and aniline in multicomponent solutions, Langmuir 39 (7) (2023) 2537–2547.
[44] X.R. Wang, Y. Wang, Z. Shu, Y.W. Cao, X.M. Wang, F. Zhou, J.H. Huang, Phenolic hydroxyl-functionalized hyper-cross-linked polymers for efficient adsorptive removal of aniline, Sep. Purif. Technol. 305 (2023) 122443.
[45] B.Y. Ma, W.J. Lv, J.Y. Li, C.W. Yang, Q. Tang, D. Wang, Promotion removal of aniline with electro-Fenton processes utilizing carbon nanotube 3D morphology modification of an Ag-loaded copper foam cathode, J. Water Process. Eng. 43 (2021) 102295.
[46] Y. Li, J.Y. Zhu, J.Y. Hu, W. Li, Y.X. Li, D.Y. Zhang, Y.Q. Lan, Catalytic ozonation for effective degradation of aniline by sulfur-doped copper-nickel bimetallic oxide in aqueous solution, J. Environ. Chem. Eng. 9 (1) (2021) 104953.
[47] S. Ahmadi, F. Mostafapour, E. Bazrafshan. Removal of Aniline and from Aqueous Solutions by Coagulation/Flocculation–Flotation[J]. Chemi. Sci. Int. J., 18(2017)1–10.
[48] S. Ahmadi, F. Mostafapour, E. Bazrafshan, Removal of aniline and from aqueous solutions by coagulation/flocculation–flotation, Chem. Sci. Int. J. 18 (3) (2017) 1–10.
[49] Y.H. Tu, L.F. Ren, J.H. Shao, Y.L. He, Simultaneous removal of aniline and antimony (Sb(V)) from textile wastewater using amidoxime-PAN/PLA nanofiber microsphere supported TiO₂, Sep. Purif. Technol. 286 (2022) 120435.
[50] J.P. Feng, Q. Zhang, B. Tan, M. Li, H.J. Peng, J. He, Y.J. Zhang, J.H. Su, Microbial community and metabolic characteristics evaluation in start-up stage of electro-enhanced SBR for aniline wastewater treatment, J. Water Process. Eng. 45 (2022) 102489.
[51] H. Wang, L. Zhang, Y. Tian, Y. Jia, G.Z. Bo, L.T. Luo, L. Liu, G.Y. Shi, F.P. Li, Performance of nitrobenzene and its intermediate aniline removal by constructed wetlands coupled with the micro-electric field, Chemosphere 264 (Pt 1) (2021) 128456.
[52] Y.H. Han, C.T. Wu, X.L. Fu, Z.M. Su, M.L. Liu, Sulfate removal mechanism by internal circulation iron-carbon micro-electrolysis, Sep. Purif. Technol. 279 (2021) 119762.
[53] W.J. Sang, J.Q. Cui, Y.J. Feng, L.J. Mei, Q. Zhang, D. Li, W.J. Zhang, Degradation of aniline in aqueous solution by dielectric barrier discharge plasma: Mechanism and degradation pathways, Chemosphere 223 (2019) 416–424.

An internal circulation iron–carbon micro-electrolysis reactor for aniline wastewater treatment: Parameter optimization, degradation pathways and mechanism

An internal circulation iron–carbon micro-electrolysis reactor for aniline wastewater treatment: Parameter optimization, degradation pathways and mechanism

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	Ali Nikkhah, Hasan Nikkhah, Hadis langari, Alireza Nouri, Abdul Wahab Mohammad, Ang Wei Lun, Ng law Yong, Rosiah Rohani, Ebrahim Mahmoudi. MXene: From synthesis to environment remediation[J]. 中国化学工程学报, 2023, 61(9): 260-280.
[2]	Bo Yu, Guang Fu, Xinpei Li, Libo Zhang, Jing Li, Hongtao Qu, Dongbin Wang, Qingfeng Dong, Mengmeng Zhang. Arsenic removal from acidic industrial wastewater by ultrasonic activated phosphorus pentasulfide[J]. 中国化学工程学报, 2023, 60(8): 46-52.
[3]	Xia Miao, Xiaofan Pang, Shiyu Li, Haoguang Wei, Jianhao Yin, Xiangming Kong. Mechanical strength and the degradation mechanism of metakaolin based geopolymer mixed with ordinary Portland cement and cured at high temperature and high relative humidity[J]. 中国化学工程学报, 2023, 60(8): 118-130.
[4]	Xiaolin Pan, Mengyuan Gao, Yun Wang, Yanping He, Tian Si, Yanlin Sun. Poly(lactic acid)-aspirin microspheres prepared via the traditional and improved solvent evaporation methods and its application performances[J]. 中国化学工程学报, 2023, 60(8): 194-204.
[5]	Yanli Zhang, Zhengkun Hou, Dong Yao, Xiaomin Qiu, Hongru Zhang, Peizhe Cui, Yinglong Wang, Jun Gao, Zhaoyou Zhu, Limei Zhong. Energy, exergy, economic and environmental comprehensive analysis and multi-objective optimization of a sustainable zero liquid discharge integrated process for fixed-bed coal gasification wastewater[J]. 中国化学工程学报, 2023, 58(6): 341-354.
[6]	Linlin Su, Meijun Chen, Li Gong, Hua Yang, Chao Chen, Jun Wu, Ling Luo, Gang Yang, Lulu Long. Boost activation of peroxymonosulfate by iron doped K_2-xMn₈O₁₆: Mechanism and properties[J]. 中国化学工程学报, 2023, 57(5): 88-97.
[7]	Hu Chen, Ying Wang, Puyu Wang, Yongkang Lv. Assessing quinoline removal performances of an aerobic continuous moving bed biofilm reactor (MBBR) bioaugmented with Pseudomonas citronellolis LV1[J]. 中国化学工程学报, 2023, 57(5): 132-140.
[8]	Yaqiao Liu, Shuozhen Hu, Xinsheng Zhang, Shigang Sun. Investigation of photoelectrocatalytic degradation mechanism of methylene blue by α-Fe₂O₃ nanorods array[J]. 中国化学工程学报, 2023, 57(5): 162-172.
[9]	Jiajun Wang, Wenbin Yang, Jiangtao Geng, Zhigang Shao, Wei Song. Experimental investigation on degradation mechanism of membrane electrode assembly at different humidity under automotive protocol[J]. 中国化学工程学报, 2023, 56(4): 70-79.
[10]	Iltaf Khan, Chunjuan Wang, Shoaib Khan, Jinyin Chen, Aftab Khan, Sayyar Ali Shah, Aihua Yuan, Sohail Khan, Mehwish K. Butt, Humaira Asghar. Bio-capped and green synthesis of ZnO/g-C₃N₄ nanocomposites and its improved antibiotic and photocatalytic activities: An exceptional approach towards environmental remediation[J]. 中国化学工程学报, 2023, 56(4): 215-224.
[11]	Feng Jiang, Xiao Li, Guopeng Qi, Xiulun Li. Effects of particle type on the particle fluidization and distribution in a liquid–solid circulating fluidized bed boiler[J]. 中国化学工程学报, 2023, 54(2): 53-66.
[12]	Abid Ali, Bilal Ul Amin, Wenwu Yu, Taijiang Gui, Weiwei Cong, Kai Zhang, Zheming Tong, Jiankun Hu, Xiaoli Zhan, Qinghua Zhang. Eco-friendly biodegradable polyurethane based coating for antibacterial and antifouling performance[J]. 中国化学工程学报, 2023, 54(2): 80-88.
[13]	Jingjing Pan, Haoran Sun, Keyi Chen, Yuhao Zhang, Pengnian Shan, Weilong Shi, Feng Guo. Nanodiamonds decorated yolk-shell ZnFe₂O₄ sphere as magnetically separable and recyclable composite for boosting antibiotic degradation performance[J]. 中国化学工程学报, 2023, 54(2): 162-172.
[14]	Aiqin Gao, Xiang Luo, Huanghuang Chen, Aiqin Hou, Hongjuan Zhang, Kongliang Xie. Design of the reactive dyes containing large planar multi-conjugated systems and their application in non-aqueous dyeing[J]. 中国化学工程学报, 2023, 54(2): 264-271.
[15]	Chao Zhang, Youzhi Liu, Weizhou Jiao, Hongyan Shen, Xigang Yuan, Shengkun Jia. An optimization method for enhancement of gas–liquid mass transfer in a bubble column reactor based on the entropy generation extremum principle[J]. 中国化学工程学报, 2023, 53(1): 83-88.