Solubility of iron(III) and nickel(II) acetylacetonates in supercritical carbon dioxide

doi:10.1016/j.cjche.2023.07.001

中国化学工程学报 ›› 2024, Vol. 65 ›› Issue (1): 29-34.DOI: 10.1016/j.cjche.2023.07.001

• Full Length Article • 上一篇下一篇

Solubility of iron(III) and nickel(II) acetylacetonates in supercritical carbon dioxide

Haixin Sun¹, Jianlei Qi², Jianfei Sun¹, Lin Li¹, Kunpeng Yu¹, Jintao Wu¹, Jianzhong Yin¹

1 State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, Dalian 116024, China;
2 College of Chemical Engineering, Inner Mongolia University of Technology, Hohhot 010051, China

收稿日期:2023-04-21 修回日期:2023-07-09 出版日期:2024-01-28 发布日期:2024-04-17
通讯作者: Jianzhong Yin,E-mail:jzyin@dlut.edu.cn
基金资助:
The authors are appreciative of financial support from the National Key Research and Development Program of China (2020YFA0710202), the National Natural Science Foundation of China (21978043, U1662130), Inner Mongolia University of Technology Scientific Research Initial Funding (DC2300001240), Talent Introduction Support Project of Inner Mongolia (DC2300001426).

Solubility of iron(III) and nickel(II) acetylacetonates in supercritical carbon dioxide

Haixin Sun¹, Jianlei Qi², Jianfei Sun¹, Lin Li¹, Kunpeng Yu¹, Jintao Wu¹, Jianzhong Yin¹

1 State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, Dalian 116024, China;
2 College of Chemical Engineering, Inner Mongolia University of Technology, Hohhot 010051, China

Received:2023-04-21 Revised:2023-07-09 Online:2024-01-28 Published:2024-04-17
Contact: Jianzhong Yin,E-mail:jzyin@dlut.edu.cn
Supported by:
The authors are appreciative of financial support from the National Key Research and Development Program of China (2020YFA0710202), the National Natural Science Foundation of China (21978043, U1662130), Inner Mongolia University of Technology Scientific Research Initial Funding (DC2300001240), Talent Introduction Support Project of Inner Mongolia (DC2300001426).

摘要/Abstract

摘要： As a common precursor for supercritical CO₂ (scCO₂) deposition techniques, solubility data of organometallic complexes in scCO₂ is crucial for the preparation of nanocomposites. Recently, metal acetylacetonates have shown great potential for the preparation of single-atom catalytic materials. In this study, the solubilities of iron(III) acetylacetonate (Fe(acac)₃) and nickel(II) acetylacetonate (Ni(acac)₂) were measured at the temperature from 313.15 to 333.15 K and in the pressure range of 9.5-25.2 MPa to accumulate new solubility data. Solubility was measured using a static weight loss method. The semi-empirical models proposed by Chrastil and Sung et al. were used to correlate the solubility data of Fe(acac)₃ and Ni(acac)₂. The equations obtained can be used to predict the solubility of the same system in the experimental range.

关键词: Iron(III) acetylacetonate, Nickel(II) acetylacetonate, Supercritical carbon dioxide, Solubility measurement, Correlation model, Phase equilibrium

Abstract: As a common precursor for supercritical CO₂ (scCO₂) deposition techniques, solubility data of organometallic complexes in scCO₂ is crucial for the preparation of nanocomposites. Recently, metal acetylacetonates have shown great potential for the preparation of single-atom catalytic materials. In this study, the solubilities of iron(III) acetylacetonate (Fe(acac)₃) and nickel(II) acetylacetonate (Ni(acac)₂) were measured at the temperature from 313.15 to 333.15 K and in the pressure range of 9.5-25.2 MPa to accumulate new solubility data. Solubility was measured using a static weight loss method. The semi-empirical models proposed by Chrastil and Sung et al. were used to correlate the solubility data of Fe(acac)₃ and Ni(acac)₂. The equations obtained can be used to predict the solubility of the same system in the experimental range.

Key words: Iron(III) acetylacetonate, Nickel(II) acetylacetonate, Supercritical carbon dioxide, Solubility measurement, Correlation model, Phase equilibrium

Haixin Sun, Jianlei Qi, Jianfei Sun, Lin Li, Kunpeng Yu, Jintao Wu, Jianzhong Yin. Solubility of iron(III) and nickel(II) acetylacetonates in supercritical carbon dioxide[J]. 中国化学工程学报, 2024, 65(1): 29-34.

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Solubility of iron(III) and nickel(II) acetylacetonates in supercritical carbon dioxide

Solubility of iron(III) and nickel(II) acetylacetonates in supercritical carbon dioxide

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