Measurement and Correlation for Solubility of 2-Chloro-5-chloromethylpyridine in Different Solvents

›› 2010, Vol. 18 ›› Issue (4): 654-658.

Measurement and Correlation for Solubility of 2-Chloro-5-chloromethylpyridine in Different Solvents

石晓华, 李明, 周彩荣

Institute of Chemical Engineering and Energy, Zhengzhou University, Zhengzhou 450001, China

收稿日期:2009-12-23 修回日期:2010-05-20 出版日期:2010-08-28 发布日期:2010-08-28
通讯作者: SHI Xiaohua, E-mail:shixiaohua@zzu.edu.cn

Measurement and Correlation for Solubility of 2-Chloro-5-chloromethylpyridine in Different Solvents

SHI Xiaohua, LI Ming, ZHOU Cairong

Institute of Chemical Engineering and Energy, Zhengzhou University, Zhengzhou 450001, China

Received:2009-12-23 Revised:2010-05-20 Online:2010-08-28 Published:2010-08-28

摘要/Abstract

摘要： 2-Chloro-5-chloromethylpyridine is a crucial intermediate of pesticides.Its solid-liquid equilibrium data will provide essential support for industrial design and further theoretical studies.The solubilities of 2-chloro-5-chloromethylpyridine in water,methanol,ethanol,ethyl acetate,acetone,trichloromethane and toluene at different temperatures were measured using the synthetic method by a laser monitoring observation technique. The solubility data were correlated with the modified Apelblat equation and Wilson equation.The calculated values were in good agreement with the experimental values.

关键词: 2-chloro-5-chloromethylpyridine, solid-liquid equilibrium, solubility

Abstract: 2-Chloro-5-chloromethylpyridine is a crucial intermediate of pesticides.Its solid-liquid equilibrium data will provide essential support for industrial design and further theoretical studies.The solubilities of 2-chloro-5-chloromethylpyridine in water,methanol,ethanol,ethyl acetate,acetone,trichloromethane and toluene at different temperatures were measured using the synthetic method by a laser monitoring observation technique. The solubility data were correlated with the modified Apelblat equation and Wilson equation.The calculated values were in good agreement with the experimental values.

Key words: 2-chloro-5-chloromethylpyridine, solid-liquid equilibrium, solubility

石晓华, 李明, 周彩荣. Measurement and Correlation for Solubility of 2-Chloro-5-chloromethylpyridine in Different Solvents[J]. , 2010, 18(4): 654-658.

SHI Xiaohua, LI Ming, ZHOU Cairong. Measurement and Correlation for Solubility of 2-Chloro-5-chloromethylpyridine in Different Solvents[J]. , 2010, 18(4): 654-658.

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Measurement and Correlation for Solubility of 2-Chloro-5-chloromethylpyridine in Different Solvents

Measurement and Correlation for Solubility of 2-Chloro-5-chloromethylpyridine in Different Solvents

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