Kinetic-Thermodynamic Analysis of the Reactive Distillation Process of the Cyclohexene Hydration Using the Zeolite Catalyst

›› 2011, Vol. 19 ›› Issue (5): 808-814.

Kinetic-Thermodynamic Analysis of the Reactive Distillation Process of the Cyclohexene Hydration Using the Zeolite Catalyst

叶建初, 黄佳丽, 林晗丹, 曹克腾, 沙勇

College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian China

收稿日期:2011-06-10 修回日期:2011-07-25 出版日期:2011-10-28 发布日期:2011-10-28
通讯作者: SHA Yong,E-mail:ysha@xmu.edu.cn

Kinetic-Thermodynamic Analysis of the Reactive Distillation Process of the Cyclohexene Hydration Using the Zeolite Catalyst

YE Jianchu, HUANG Jiali, LIN Handan, CAO Keteng, SHA Yong

College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian China

Received:2011-06-10 Revised:2011-07-25 Online:2011-10-28 Published:2011-10-28

摘要/Abstract

摘要： Reactive distillation could be utilized to produce cyclohexanol through the cyclohexene hydration. By means of highly active zeolite catalyst HZSM-5, the kinetic-thermodynamic analysis of this reactive distillation has been carried out to get the characteristics of the reactive distillation. Results from kinetic and thermodynamic analysis indicate that the optimal pressure of this reactive distillation process should be set to higher pressure such as 0.3 or 0.4 MPa. To avoid the recovery of cyclohexanol at the top of the column, an unreactive section should be allo-cated at the upper column. In addition, the inert component benzene is more unfavorable to the reactive distillation process in comparison with the inert cyclohexane.

关键词: hydration, reactive distillation, residue curves, phase splitting, cyclohexanol

Abstract: Reactive distillation could be utilized to produce cyclohexanol through the cyclohexene hydration. By means of highly active zeolite catalyst HZSM-5, the kinetic-thermodynamic analysis of this reactive distillation has been carried out to get the characteristics of the reactive distillation. Results from kinetic and thermodynamic analysis indicate that the optimal pressure of this reactive distillation process should be set to higher pressure such as 0.3 or 0.4 MPa. To avoid the recovery of cyclohexanol at the top of the column, an unreactive section should be allo-cated at the upper column. In addition, the inert component benzene is more unfavorable to the reactive distillation process in comparison with the inert cyclohexane.

Key words: hydration, reactive distillation, residue curves, phase splitting, cyclohexanol

叶建初, 黄佳丽, 林晗丹, 曹克腾, 沙勇. Kinetic-Thermodynamic Analysis of the Reactive Distillation Process of the Cyclohexene Hydration Using the Zeolite Catalyst[J]. , 2011, 19(5): 808-814.

YE Jianchu, HUANG Jiali, LIN Handan, CAO Keteng, SHA Yong. Kinetic-Thermodynamic Analysis of the Reactive Distillation Process of the Cyclohexene Hydration Using the Zeolite Catalyst[J]. , 2011, 19(5): 808-814.

参考文献

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Kinetic-Thermodynamic Analysis of the Reactive Distillation Process of the Cyclohexene Hydration Using the Zeolite Catalyst

Kinetic-Thermodynamic Analysis of the Reactive Distillation Process of the Cyclohexene Hydration Using the Zeolite Catalyst

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