SCI和EI收录∣中国化工学会会刊

Chinese Journal of Chemical Engineering ›› 2013, Vol. 21 ›› Issue (3): 310-317.DOI: 10.1016/S1004-9541(13)60464-4

• 化工热力学 • 上一篇    下一篇

Solubility of CO2 in Methanol, 1-Octyl-3-methylimidazolium Bis(trifluoromethylsulfonyl)imide, and Their Mixtures

雷志刚1, 张本凤1, 朱吉钦1, 宫万福2, 吕建宁2, 李延生2   

  1. 1 State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China;
    2 Wison Engineering Ltd., 1399 Zhangheng Road, Shanghai 201203, China
  • 收稿日期:2011-11-14 修回日期:2012-03-02 出版日期:2013-03-28 发布日期:2013-04-01
  • 通讯作者: LEI Zhigang
  • 基金资助:

    Supported by the National Natural Science Foundation of China (21121064, 21076008), and the Projects in the National Science & Technology Pillar Program During the Twelfth Five-Year Plan Period (2011BAC06B04).

Solubility of CO2 in Methanol, 1-Octyl-3-methylimidazolium Bis(trifluoromethylsulfonyl)imide, and Their Mixtures

LEI Zhigang1, ZHANG Benfeng1, ZHU Jiqin1, GONG Wanfu2, L? Jianning2, LI Yansheng2   

  1. 1 State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China;
    2 Wison Engineering Ltd., 1399 Zhangheng Road, Shanghai 201203, China
  • Received:2011-11-14 Revised:2012-03-02 Online:2013-03-28 Published:2013-04-01
  • Supported by:

    Supported by the National Natural Science Foundation of China (21121064, 21076008), and the Projects in the National Science & Technology Pillar Program During the Twelfth Five-Year Plan Period (2011BAC06B04).

摘要: Solubility data of carbon dioxide (CO2) (1) in methanol (2), 1-octyl-3-methylimidazolium bis(trifluoro- methylsulfonyl)imide ([omim]+[Tf2N]-) (3), and their mixtures (w3 0.2, 0.5, and 0.8) at temperatures 313.2 and 333.2 K and pressures up to 7.0 MPa were measured by a high-pressure view-cell technique. The solubility of CO2 in methanol (w3=0), [omim]+[Tf2N]- (w3=1.0) and their mixtures follows the order of (w3=0)<(w3=0.2)< (w3=0.5)<(w3=0.8)<(w3=1.0) at the same temperature and pressure, while the magnitude of Henry's constants follows the reverse order at a given temperature, which is consistent with the COSMO-RS (conductor-like screening for real solvents) calculation. The solubility data of CO2 in methanol and [omim]+[Tf2N]- are correlated with the Peng-Robinson equation of state, and the solubility of CO2 in the mixtures of methanol and [omim]+[Tf2N]- can be well predicted based on the mole fraction average of methanol and [omim]+[Tf2N]- over the solubility of CO2 in pure methanol and [omim]+[Tf2N]-. The mixtures of methanol and [omim]+[Tf2N]- may be used as physical solvents for capturing CO2 with high partial pressures since they combine the advantages of organic solvents and ionic liquids.

关键词: CO2, solubility, methanol, ionic liquids, Peng-Robinson equation of state

Abstract: Solubility data of carbon dioxide (CO2) (1) in methanol (2), 1-octyl-3-methylimidazolium bis(trifluoro- methylsulfonyl)imide ([omim]+[Tf2N]-) (3), and their mixtures (w3 0.2, 0.5, and 0.8) at temperatures 313.2 and 333.2 K and pressures up to 7.0 MPa were measured by a high-pressure view-cell technique. The solubility of CO2 in methanol (w3=0), [omim]+[Tf2N]- (w3=1.0) and their mixtures follows the order of (w3=0)<(w3=0.2)< (w3=0.5)<(w3=0.8)<(w3=1.0) at the same temperature and pressure, while the magnitude of Henry's constants follows the reverse order at a given temperature, which is consistent with the COSMO-RS (conductor-like screening for real solvents) calculation. The solubility data of CO2 in methanol and [omim]+[Tf2N]- are correlated with the Peng-Robinson equation of state, and the solubility of CO2 in the mixtures of methanol and [omim]+[Tf2N]- can be well predicted based on the mole fraction average of methanol and [omim]+[Tf2N]- over the solubility of CO2 in pure methanol and [omim]+[Tf2N]-. The mixtures of methanol and [omim]+[Tf2N]- may be used as physical solvents for capturing CO2 with high partial pressures since they combine the advantages of organic solvents and ionic liquids.

Key words: CO2, solubility, methanol, ionic liquids, Peng-Robinson equation of state