A Bi-component Cu Catalyst for the Direct Synthesis of Methylchlorosilane from Silicon and Methyl Chloride

doi:10.1016/S1004-9541(14)60034-3

Chinese Journal of Chemical Engineering ›› 2014, Vol. 22 ›› Issue (3): 299-304.DOI: 10.1016/S1004-9541(14)60034-3

• 催化、动力学与反应工程 • 上一篇下一篇

A Bi-component Cu Catalyst for the Direct Synthesis of Methylchlorosilane from Silicon and Methyl Chloride

汪超, 王光润, 王金福

Beijing Key Laboratory of Green Chemical Reaction Engineering and Technology, Department of Chemical Engineering, Tsinghua University, Beijing 100084, China

收稿日期:2012-04-09 修回日期:2013-02-25 出版日期:2014-03-28 发布日期:2014-03-05
通讯作者: WANG Jinfu

A Bi-component Cu Catalyst for the Direct Synthesis of Methylchlorosilane from Silicon and Methyl Chloride

WANG Chao, WANG Guangrun, WANG Jinfu

Beijing Key Laboratory of Green Chemical Reaction Engineering and Technology, Department of Chemical Engineering, Tsinghua University, Beijing 100084, China

Received:2012-04-09 Revised:2013-02-25 Online:2014-03-28 Published:2014-03-05
Contact: WANG Jinfu

摘要/Abstract

摘要： A bi-component catalyst comprising CuCl and metallic copper was used in the direct synthesis of methylchlorosilane to study the catalytic synergy between the different copper sources. The catalyst exhibited high activity and high selectivity of dimethyldichlorosilane (M2) in the stirred bed reactor. The effect of the proportion of CuCl used was studied and 10%-30% CuCl gave the best yield of M2. The use of CuCl decreased the induction period of reaction, improved the selectivity in the induction stage, and gave a longer stable stage. These results suggest that bi-component catalyst has advantages in the direct synthesis reaction.

关键词: methylchlorosilane, direct synthesis, bi-component catalyst, synergy

Abstract: A bi-component catalyst comprising CuCl and metallic copper was used in the direct synthesis of methylchlorosilane to study the catalytic synergy between the different copper sources. The catalyst exhibited high activity and high selectivity of dimethyldichlorosilane (M2) in the stirred bed reactor. The effect of the proportion of CuCl used was studied and 10%-30% CuCl gave the best yield of M2. The use of CuCl decreased the induction period of reaction, improved the selectivity in the induction stage, and gave a longer stable stage. These results suggest that bi-component catalyst has advantages in the direct synthesis reaction.

Key words: methylchlorosilane, direct synthesis, bi-component catalyst, synergy

汪超, 王光润, 王金福. A Bi-component Cu Catalyst for the Direct Synthesis of Methylchlorosilane from Silicon and Methyl Chloride[J]. Chinese Journal of Chemical Engineering, 2014, 22(3): 299-304.

WANG Chao, WANG Guangrun, WANG Jinfu. A Bi-component Cu Catalyst for the Direct Synthesis of Methylchlorosilane from Silicon and Methyl Chloride[J]. Chin.J.Chem.Eng., 2014, 22(3): 299-304.

参考文献

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A Bi-component Cu Catalyst for the Direct Synthesis of Methylchlorosilane from Silicon and Methyl Chloride

A Bi-component Cu Catalyst for the Direct Synthesis of Methylchlorosilane from Silicon and Methyl Chloride

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