SCI和EI收录∣中国化工学会会刊

Chinese Journal of Chemical Engineering ›› 2014, Vol. 22 ›› Issue (2): 177-180.DOI: 10.1016/S1004-9541(14)60043-4

• 化工热力学 • 上一篇    下一篇

Measurement and Correlation of Vapor-Liquid Equilibria for Hexamethyl Disiloxane + Vinyl Acetate System at 101.3 kPa

张文林1, 杜威1, 孟楠1, 孙如意1,2, 李春利1   

  1. 1 School of Chemical Engineering, Hebei University of Technology, Tianjin 300130, China;
    2 Shijiazhuang Newthreetalent Engineering, Co., Ltd, Shijiazhuang 050000, China
  • 收稿日期:2012-07-12 修回日期:2012-11-23 出版日期:2014-02-05 发布日期:2014-01-28
  • 通讯作者: ZHANG Wenlin

Measurement and Correlation of Vapor-Liquid Equilibria for Hexamethyl Disiloxane + Vinyl Acetate System at 101.3 kPa

ZHANG Wenlin1, DU Wei1, MENG Nan1, SUN Ruyi1,2, LI Chunli1   

  1. 1 School of Chemical Engineering, Hebei University of Technology, Tianjin 300130, China;
    2 Shijiazhuang Newthreetalent Engineering, Co., Ltd, Shijiazhuang 050000, China
  • Received:2012-07-12 Revised:2012-11-23 Online:2014-02-05 Published:2014-01-28
  • Contact: ZHANG Wenlin

摘要: Vapor-liquid equilibrium data of hexamethyl disiloxane + vinyl acetate system at 101.3kPa were measured by using double circulating vapor-liquid equilibrium still. The thermodynamic consistency of the VLE data was examined by Herrington method. Experimental data was correlated by non-random two-liquid (NRTL), Wilson and universal quasichemical (UNIQUAC) parameter models. All the models satisfactorily correlated with the VLE data. The result showed that the NRTL model was the most suitable one to represent experimental data satisfactorily. The system had a minimum temperature azeotrope at 345.71 K and the mole azeotropic composition was 0.0541.

关键词: vapor-liquid equilibria, vinyl acetate, hexamethyl disiloxane, determination, correlation

Abstract: Vapor-liquid equilibrium data of hexamethyl disiloxane + vinyl acetate system at 101.3kPa were measured by using double circulating vapor-liquid equilibrium still. The thermodynamic consistency of the VLE data was examined by Herrington method. Experimental data was correlated by non-random two-liquid (NRTL), Wilson and universal quasichemical (UNIQUAC) parameter models. All the models satisfactorily correlated with the VLE data. The result showed that the NRTL model was the most suitable one to represent experimental data satisfactorily. The system had a minimum temperature azeotrope at 345.71 K and the mole azeotropic composition was 0.0541.

Key words: vapor-liquid equilibria, vinyl acetate, hexamethyl disiloxane, determination, correlation