SCI和EI收录∣中国化工学会会刊

›› 2014, Vol. 22 ›› Issue (9): 955-961.DOI: 10.1016/j.cjche.2014.06.019

• 流体力学与传递现象 •    下一篇

Gas-Liquid Mass Transfer Characteristics in a Gas-Liquid-Solid Bubble Column under Elevated Pressure and Temperature

Haibo Jin1, Suohe Yang1, Guangxiang He1, Delin Liu1, Zemin Tong1, Jianhua Zhu2   

  1. 1 Department of Chemical Engineering, Beijing Institute of Petrochemical Technology, Beijing 102617, China;
    2 Faculty of Chemical Science and Engineering, China University of Petroleum, Beijing 102249, China
  • 收稿日期:2012-11-01 修回日期:2013-09-20 出版日期:2014-09-28 发布日期:2014-11-04
  • 通讯作者: Haibo Jin
  • 基金资助:
    Supported by the National Natural Science Foundation of China (20776018), and the Importation and Development of High-Caliber Talents Project of Beijing Municipal Institutions (CIT&TCD20130325).

Gas-Liquid Mass Transfer Characteristics in a Gas-Liquid-Solid Bubble Column under Elevated Pressure and Temperature

Haibo Jin1, Suohe Yang1, Guangxiang He1, Delin Liu1, Zemin Tong1, Jianhua Zhu2   

  1. 1 Department of Chemical Engineering, Beijing Institute of Petrochemical Technology, Beijing 102617, China;
    2 Faculty of Chemical Science and Engineering, China University of Petroleum, Beijing 102249, China
  • Received:2012-11-01 Revised:2013-09-20 Online:2014-09-28 Published:2014-11-04
  • Supported by:
    Supported by the National Natural Science Foundation of China (20776018), and the Importation and Development of High-Caliber Talents Project of Beijing Municipal Institutions (CIT&TCD20130325).

摘要: The volumetricmass transfer coefficient kLa of gases (H2, CO, CO2) and mass transfer coefficient kL on liquid paraffin side were studied using the dynamic absorption method in slurry bubble column reactors under elevated temperature and elevated pressure. Meanwhile, gas-holdup and gas-liquid interfacial area a were obtained. The effects of temperature, pressure, superficial gas velocity and solid concentration on themass transfer coefficient were discussed. Experimental results show that the gas-liquid volumetric mass transfer coefficient kLa and interfacial area a increasedwith the increase of pressure, temperature, and superficial gas velocity, and decreased with the slurry concentration. The mass transfer coefficient kL increased with increasing superficial gas velocity and temperature and decreased with higher slurry concentration, while it changed slightly with pressure. According to analysis of experimental data, an empirical correlation is obtained to calculate the values of kLa for H2 (CO, CO2) in the gas-paraffin-quartz system in a bubble column under elevated temperature and elevated pressure.

关键词: Mass transfer characteristic, Bubble column, Elevated pressure, Elevated temperature

Abstract: The volumetricmass transfer coefficient kLa of gases (H2, CO, CO2) and mass transfer coefficient kL on liquid paraffin side were studied using the dynamic absorption method in slurry bubble column reactors under elevated temperature and elevated pressure. Meanwhile, gas-holdup and gas-liquid interfacial area a were obtained. The effects of temperature, pressure, superficial gas velocity and solid concentration on themass transfer coefficient were discussed. Experimental results show that the gas-liquid volumetric mass transfer coefficient kLa and interfacial area a increasedwith the increase of pressure, temperature, and superficial gas velocity, and decreased with the slurry concentration. The mass transfer coefficient kL increased with increasing superficial gas velocity and temperature and decreased with higher slurry concentration, while it changed slightly with pressure. According to analysis of experimental data, an empirical correlation is obtained to calculate the values of kLa for H2 (CO, CO2) in the gas-paraffin-quartz system in a bubble column under elevated temperature and elevated pressure.

Key words: Mass transfer characteristic, Bubble column, Elevated pressure, Elevated temperature