A solvent-free, selective liquid phase hydrogenation of nitroarenes to aniline in slurry bubble mode on porous NiMo bimetallic catalyst

doi:10.1016/j.cjche.2020.07.018

中国化学工程学报 ›› 2021, Vol. 33 ›› Issue (5): 175-180.DOI: 10.1016/j.cjche.2020.07.018

• Catalysis, Kinetics and Reaction Engineering • 上一篇下一篇

A solvent-free, selective liquid phase hydrogenation of nitroarenes to aniline in slurry bubble mode on porous NiMo bimetallic catalyst

Di Liu, Pengshan Zhao, Hao Zhang, Minjie Liu, Junyan Wang, Guoming Zhao, Qingbin Guo

College of Chemical and Biological Engineering, Shandong University of Science and Technology, Qingdao 266590, China

收稿日期:2020-03-19 修回日期:2020-06-24 出版日期:2021-05-28 发布日期:2021-08-19
通讯作者: Di Liu
基金资助:
This work was supported by the National Natural Science Foundation of China (Grant No. 21878178) and Scientific Research Foundation of Shandong University of Science and Technology for Recruited Talents (Grant No. 201

A solvent-free, selective liquid phase hydrogenation of nitroarenes to aniline in slurry bubble mode on porous NiMo bimetallic catalyst

Di Liu, Pengshan Zhao, Hao Zhang, Minjie Liu, Junyan Wang, Guoming Zhao, Qingbin Guo

College of Chemical and Biological Engineering, Shandong University of Science and Technology, Qingdao 266590, China

Received:2020-03-19 Revised:2020-06-24 Online:2021-05-28 Published:2021-08-19
Contact: Di Liu
Supported by:
This work was supported by the National Natural Science Foundation of China (Grant No. 21878178) and Scientific Research Foundation of Shandong University of Science and Technology for Recruited Talents (Grant No. 201

摘要/Abstract

摘要： NiMo bimetallic catalysts were prepared by a solid reaction method. On the NiMo catalyst, the selective liquid phase hydrogenation of nitrobenzene to aniline was achieved in slurry bubble mode. And the high yields (98.9%) were obtained under the conditions of 80 ℃, solvent-free and atmospheric pressure. The effect of Mo on the catalytic behavior of Ni based catalyst was investigated. The characterization displayed that the inclusion of Mo could improve the specific surface area and pore volume, and the solid reaction method made metal Mo enrichment on the surface of catalyst. These two aspects should be responsible for excellent catalytic performance of NiMo catalyst. In sum, we described a simple and efficient NiMo catalyst and provided a facile and green procedure for liquid phase hydrogenation of nitrobenzene to aniline.

关键词: Catalysis, Nitroarenes, Hydrogenation, NiMo catalyst, Solid reaction, Bubble column reactor

Abstract: NiMo bimetallic catalysts were prepared by a solid reaction method. On the NiMo catalyst, the selective liquid phase hydrogenation of nitrobenzene to aniline was achieved in slurry bubble mode. And the high yields (98.9%) were obtained under the conditions of 80 ℃, solvent-free and atmospheric pressure. The effect of Mo on the catalytic behavior of Ni based catalyst was investigated. The characterization displayed that the inclusion of Mo could improve the specific surface area and pore volume, and the solid reaction method made metal Mo enrichment on the surface of catalyst. These two aspects should be responsible for excellent catalytic performance of NiMo catalyst. In sum, we described a simple and efficient NiMo catalyst and provided a facile and green procedure for liquid phase hydrogenation of nitrobenzene to aniline.

Key words: Catalysis, Nitroarenes, Hydrogenation, NiMo catalyst, Solid reaction, Bubble column reactor

Di Liu, Pengshan Zhao, Hao Zhang, Minjie Liu, Junyan Wang, Guoming Zhao, Qingbin Guo. A solvent-free, selective liquid phase hydrogenation of nitroarenes to aniline in slurry bubble mode on porous NiMo bimetallic catalyst[J]. 中国化学工程学报, 2021, 33(5): 175-180.

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A solvent-free, selective liquid phase hydrogenation of nitroarenes to aniline in slurry bubble mode on porous NiMo bimetallic catalyst

A solvent-free, selective liquid phase hydrogenation of nitroarenes to aniline in slurry bubble mode on porous NiMo bimetallic catalyst

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