SCI和EI收录∣中国化工学会会刊

›› 2014, Vol. 22 ›› Issue (11/12): 1285-1290.DOI: 10.1016/j.cjche.2014.09.009

• 化工热力学 • 上一篇    下一篇

Adsorption Behavior of Rhodamine B on UiO-66

Qinqin He, Qi Chen, Mengmeng Lü, Xueting Liu   

  1. School of Chemical Engineering, Hefei University of Technology, Anhui Key Laboratory of Controllable Chemical Reaction & Material Chemical Engineering, Hefei 230009, China
  • 收稿日期:2013-07-24 修回日期:2013-12-27 出版日期:2014-12-28 发布日期:2014-12-24
  • 通讯作者: Xueting Liu

Adsorption Behavior of Rhodamine B on UiO-66

Qinqin He, Qi Chen, Mengmeng Lü, Xueting Liu   

  1. School of Chemical Engineering, Hefei University of Technology, Anhui Key Laboratory of Controllable Chemical Reaction & Material Chemical Engineering, Hefei 230009, China
  • Received:2013-07-24 Revised:2013-12-27 Online:2014-12-28 Published:2014-12-24

摘要: The adsorption characteristics of UiO-66 (a Zr-containing metal-organic framework formed by terephthalate) for Rhodamine B (RhB), such as isotherms, kinetics and thermodynamics, were investigated systematically. The batch adsorption data conform well to the Langmuir and Freundlich isotherms. The adsorption kinetics of UiO-66 for RhB can be well described by the pseudo first-order model, and the adsorption thermodynamic parametersΔG0, ΔH0 and ΔS0 at 273 K are-6.282 kJ·mol-1, 15.096 kJ·mol-1 and 78.052 J·mol-1·K-1, respectively. The thermodynamic analyses show that the adsorption process of RhB on UiO-66 is more favorable at higher temperatures. UiO-66 can be regenerated by desorbing in DMF solution with ultrasonic for 1 h. UiO-66 can keep good performance for at least six cycles of sorption/desorption.

关键词: Adsorption, UiO-66, Kinetics, Thermodynamics, Isotherm, Regeneration

Abstract: The adsorption characteristics of UiO-66 (a Zr-containing metal-organic framework formed by terephthalate) for Rhodamine B (RhB), such as isotherms, kinetics and thermodynamics, were investigated systematically. The batch adsorption data conform well to the Langmuir and Freundlich isotherms. The adsorption kinetics of UiO-66 for RhB can be well described by the pseudo first-order model, and the adsorption thermodynamic parametersΔG0, ΔH0 and ΔS0 at 273 K are-6.282 kJ·mol-1, 15.096 kJ·mol-1 and 78.052 J·mol-1·K-1, respectively. The thermodynamic analyses show that the adsorption process of RhB on UiO-66 is more favorable at higher temperatures. UiO-66 can be regenerated by desorbing in DMF solution with ultrasonic for 1 h. UiO-66 can keep good performance for at least six cycles of sorption/desorption.

Key words: Adsorption, UiO-66, Kinetics, Thermodynamics, Isotherm, Regeneration