In situ synthesis and characterization of Ca–Mg–Al hydrotalcite on ceramic membrane for biodiesel production

doi:10.1016/j.cjche.2014.09.054

Chinese Journal of Chemical Engineering ›› 2015, Vol. 23 ›› Issue (6): 1035-1040.DOI: 10.1016/j.cjche.2014.09.054

• 能源、资源与环境技术 • 上一篇下一篇

In situ synthesis and characterization of Ca–Mg–Al hydrotalcite on ceramic membrane for biodiesel production

Wei Xu, Lijing Gao, Feng Jiang, Guomin Xiao

School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, China

收稿日期:2013-09-04 修回日期:2014-09-11 出版日期:2015-06-28 发布日期:2015-07-09
通讯作者: Guomin Xiao
基金资助:
Supported by the National Natural Science Foundation of China (21276050 and 21406034), the National Basic Research Program of China (2010CB732206).

In situ synthesis and characterization of Ca–Mg–Al hydrotalcite on ceramic membrane for biodiesel production

Wei Xu, Lijing Gao, Feng Jiang, Guomin Xiao

School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, China

Received:2013-09-04 Revised:2014-09-11 Online:2015-06-28 Published:2015-07-09
Contact: Guomin Xiao
Supported by:
Supported by the National Natural Science Foundation of China (21276050 and 21406034), the National Basic Research Program of China (2010CB732206).

摘要/Abstract

摘要： In situ surface synthesis of Ca–Mg–Al hydrotalcite (HT) on inorganic ceramic membrane (CM) was investigated with urea as precipitator. The effects of molar ratio of raw materials, crystallization time, and temperature on surface synthesis of HT were examined. The as-prepared HT/CM samples were characterized by XRD and SEM and an in sit growth mechanismof HT on CMwas proposed. KF/HT/CMobtained by loading potassium fluoride (KF) on the HT layer by impregnation and calcination method was used as catalyst for transesterification between palm oil and methanol. The comparison of KF/HT/CMand pure KF/HT powder under identical reaction conditions shows that the production of fatty acid methyl ester is equivalent, which means that the use of inorganic catalytic membrane in the transesterification is a viable alternative.

关键词: Hydrotalcite coating, In situ synthesis, Ceramic membrane, Biodiesel, Transesterification

Abstract: In situ surface synthesis of Ca-Mg-Al hydrotalcite (HT) on inorganic ceramic membrane (CM) was investigated with urea as precipitator. The effects of molar ratio of raw materials, crystallization time, and temperature on surface synthesis of HT were examined. The as-prepared HT/CM samples were characterized by XRD and SEM and an in sit growth mechanismof HT on CMwas proposed. KF/HT/CMobtained by loading potassium fluoride (KF) on the HT layer by impregnation and calcination method was used as catalyst for transesterification between palm oil and methanol. The comparison of KF/HT/CMand pure KF/HT powder under identical reaction conditions shows that the production of fatty acid methyl ester is equivalent, which means that the use of inorganic catalytic membrane in the transesterification is a viable alternative.

Key words: Hydrotalcite coating, In situ synthesis, Ceramic membrane, Biodiesel, Transesterification

Wei Xu, Lijing Gao, Feng Jiang, Guomin Xiao. In situ synthesis and characterization of Ca–Mg–Al hydrotalcite on ceramic membrane for biodiesel production[J]. Chinese Journal of Chemical Engineering, 2015, 23(6): 1035-1040.

Wei Xu, Lijing Gao, Feng Jiang, Guomin Xiao. In situ synthesis and characterization of Ca–Mg–Al hydrotalcite on ceramic membrane for biodiesel production[J]. Chin.J.Chem.Eng., 2015, 23(6): 1035-1040.

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In situ synthesis and characterization of Ca–Mg–Al hydrotalcite on ceramic membrane for biodiesel production

In situ synthesis and characterization of Ca–Mg–Al hydrotalcite on ceramic membrane for biodiesel production

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