SCI和EI收录∣中国化工学会会刊

Chinese Journal of Chemical Engineering ›› 2015, Vol. 23 ›› Issue (4): 689-698.DOI: 10.1016/j.cjche.2014.12.003

• 化工热力学 • 上一篇    下一篇

Ultrasonic study on molecular interactions in binary mixtures of formamide with 1-propanol or 2-propanol

Manju Rani1, Suman Gahlyan2, Ankur Gaur3, Sanjeev Maken2   

  1. 1 Department of Chemical Engineering, Deenbandhu Chhotu Ram University of Science and Technology, Murthal 131039, India;
    2 Department of Chemistry, Deenbandhu Chhotu Ram University of Science and Technology, Murthal 131039, India;
    3 Department of Chemical Engineering, Motilal Nehru National Institute of Technology, Allahabad 211004, India
  • 收稿日期:2013-06-26 修回日期:2013-12-26 出版日期:2015-04-28 发布日期:2015-05-13
  • 通讯作者: Sanjeev Maken

Ultrasonic study on molecular interactions in binary mixtures of formamide with 1-propanol or 2-propanol

Manju Rani1, Suman Gahlyan2, Ankur Gaur3, Sanjeev Maken2   

  1. 1 Department of Chemical Engineering, Deenbandhu Chhotu Ram University of Science and Technology, Murthal 131039, India;
    2 Department of Chemistry, Deenbandhu Chhotu Ram University of Science and Technology, Murthal 131039, India;
    3 Department of Chemical Engineering, Motilal Nehru National Institute of Technology, Allahabad 211004, India
  • Received:2013-06-26 Revised:2013-12-26 Online:2015-04-28 Published:2015-05-13
  • Contact: Sanjeev Maken

摘要: Ultrasonic speeds have been measured at 298.15 K and 308.15 K formixtures of formamide+1-propanol or 2-propanol. For an equimolar mixture, excess molar compressibility follows the sequence of 1-propanol > 2-propanol. The ultrasonic speed data are correlated by various correlations such as Nomoto's relation, van Dael's mixing relation and impedance dependence relation, and analyzed in terms of Jacobson's free length theory and Schaaff's collision factor theory. Excess isentropic compressibility is calculated from experimental ultrasonic speed data and previously reported excess volume data. The excess molar ultrasonic speed and isentropic compressibility values are fitted to Redlich-Kister polynomial equation. Other properties such as molecular association, available volume, free volume, and intermolecular free length are also calculated. The excess isentropic compressibility data are also interpreted in terms of graph theoretical approach. The calculated isentropic compressibility values are well consistent with the experimental data. It is found that the interaction between formamide and propanol increases when hydroxyl group attached to a carbon atom has more -CH3 groups.

关键词: Ultrasonic speed, Graph theoretical approach, Formamide, Propanol, Intermolecular interaction

Abstract: Ultrasonic speeds have been measured at 298.15 K and 308.15 K formixtures of formamide+1-propanol or 2-propanol. For an equimolar mixture, excess molar compressibility follows the sequence of 1-propanol > 2-propanol. The ultrasonic speed data are correlated by various correlations such as Nomoto's relation, van Dael's mixing relation and impedance dependence relation, and analyzed in terms of Jacobson's free length theory and Schaaff's collision factor theory. Excess isentropic compressibility is calculated from experimental ultrasonic speed data and previously reported excess volume data. The excess molar ultrasonic speed and isentropic compressibility values are fitted to Redlich-Kister polynomial equation. Other properties such as molecular association, available volume, free volume, and intermolecular free length are also calculated. The excess isentropic compressibility data are also interpreted in terms of graph theoretical approach. The calculated isentropic compressibility values are well consistent with the experimental data. It is found that the interaction between formamide and propanol increases when hydroxyl group attached to a carbon atom has more -CH3 groups.

Key words: Ultrasonic speed, Graph theoretical approach, Formamide, Propanol, Intermolecular interaction