Bio-inspired enantioseparation for chiral compounds

doi:10.1016/j.cjche.2015.07.003

Chinese Journal of Chemical Engineering ›› 2016, Vol. 24 ›› Issue (1): 31-38.DOI: 10.1016/j.cjche.2015.07.003

• 第25届中国过程控制会议专栏 • 上一篇下一篇

Bio-inspired enantioseparation for chiral compounds

Yan Fu¹, Jinjin Yang¹, Jinli Zhang^1,2, Wei Li¹

1 Key Laboratory for Green Chemical Technology MOE, Key Laboratory of Systems Bioengineering MOE, Collaborative Innovation Center of Chemical Science and Chemical Engineering (Tianjin), School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China;
2 School of Chemistry and Chemical Engineering, Shihezi University, Shihezi 832000, China

收稿日期:2014-10-30 修回日期:2015-05-12 出版日期:2016-01-28 发布日期:2016-02-23
通讯作者: Wei Li
基金资助:
Supported by the National Natural Science Foundation of China (21206107), the National High-tech R&D Program of China (2012AA03A609), and Program for Changjiang Scholars and Innovative Research Team in University (IRT1161).

Bio-inspired enantioseparation for chiral compounds

Yan Fu¹, Jinjin Yang¹, Jinli Zhang^1,2, Wei Li¹

1 Key Laboratory for Green Chemical Technology MOE, Key Laboratory of Systems Bioengineering MOE, Collaborative Innovation Center of Chemical Science and Chemical Engineering (Tianjin), School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China;
2 School of Chemistry and Chemical Engineering, Shihezi University, Shihezi 832000, China

Received:2014-10-30 Revised:2015-05-12 Online:2016-01-28 Published:2016-02-23
Contact: Wei Li
Supported by:
Supported by the National Natural Science Foundation of China (21206107), the National High-tech R&D Program of China (2012AA03A609), and Program for Changjiang Scholars and Innovative Research Team in University (IRT1161).

摘要/Abstract

摘要： Biomacromolecules including protein and nucleic acids are considered as promising chiral selectors in the fields of enantioselective separation, owing to their inherent chirality, polymorphous structures, stable physicochemical properties, good biocompatibility as well as susceptible modification and regulation. In this review, firstly, enantioselective recognition mechanismof proteins and nucleic acids toward different enantiomers is discussed, as well as their potential applications on the chiral separation of racemic compounds. Secondly, preparative enantioseparation adopting biomolecule-modified hybrid materials including porous microspheres, magnetic nanoparticles and affinity membranes, are introduced respectively. Finally, novel chiroptical materials constructed on the basis of chiral induction, transfer, amplification and transcription, are recognized as promising candidates in future applications.

关键词: Chirality, Enantiose paration, Protein, DNA

Abstract: Biomacromolecules including protein and nucleic acids are considered as promising chiral selectors in the fields of enantioselective separation, owing to their inherent chirality, polymorphous structures, stable physicochemical properties, good biocompatibility as well as susceptible modification and regulation. In this review, firstly, enantioselective recognition mechanismof proteins and nucleic acids toward different enantiomers is discussed, as well as their potential applications on the chiral separation of racemic compounds. Secondly, preparative enantioseparation adopting biomolecule-modified hybrid materials including porous microspheres, magnetic nanoparticles and affinity membranes, are introduced respectively. Finally, novel chiroptical materials constructed on the basis of chiral induction, transfer, amplification and transcription, are recognized as promising candidates in future applications.

Key words: Chirality, Enantiose paration, Protein, DNA

Yan Fu, Jinjin Yang, Jinli Zhang, Wei Li. Bio-inspired enantioseparation for chiral compounds[J]. Chinese Journal of Chemical Engineering, 2016, 24(1): 31-38.

Yan Fu, Jinjin Yang, Jinli Zhang, Wei Li. Bio-inspired enantioseparation for chiral compounds[J]. Chin.J.Chem.Eng., 2016, 24(1): 31-38.

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Bio-inspired enantioseparation for chiral compounds

Bio-inspired enantioseparation for chiral compounds

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