Measurement and correlation of physical properties of aqueous solutions of tetrabutylammonium hydroxide, piperazine and their aqueous blends

doi:10.1016/j.cjche.2015.08.006

摘要/Abstract

摘要： The density, viscosity and refractive index of aqueous solutions of tetrabutylammoniumhydroxide (TBAOH), piperazine (PZ) and their aqueous blends are determined at several temperatures (303.15 to 333.15 K). All these measured physicochemical properties decreases with an increase in temperature. The density data is used to calculate the coefficient of thermal expansion and excess molar volume of all aqueous binary and ternary solutions. The coefficient of thermal expansion increases with increase in temperatures and concentrations. The negativity of excess molar volume for all the aqueous solution decreasedwith increase in temperature. Each physical property is correlated with temperature by least square method and the corresponding coefficients for each property are presented. The prediction values fromcorrelations for the physical properties are in good agreement with the experimental values.

关键词: Density, ionic liquids, Density, Viscosity, Refractive index

Abstract: The density, viscosity and refractive index of aqueous solutions of tetrabutylammoniumhydroxide (TBAOH), piperazine (PZ) and their aqueous blends are determined at several temperatures (303.15 to 333.15 K). All these measured physicochemical properties decreases with an increase in temperature. The density data is used to calculate the coefficient of thermal expansion and excess molar volume of all aqueous binary and ternary solutions. The coefficient of thermal expansion increases with increase in temperatures and concentrations. The negativity of excess molar volume for all the aqueous solution decreasedwith increase in temperature. Each physical property is correlated with temperature by least square method and the corresponding coefficients for each property are presented. The prediction values fromcorrelations for the physical properties are in good agreement with the experimental values.

Key words: Density, ionic liquids, Density, Viscosity, Refractive index

Rizwan Safdar, Abdul Aziz Omar, Lukman B. Ismail, Arhama Bari, Bhajan Lal. Measurement and correlation of physical properties of aqueous solutions of tetrabutylammonium hydroxide, piperazine and their aqueous blends[J]. Chinese Journal of Chemical Engineering, 2015, 23(11): 1811-1818.

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