Cobalt-free gadolinium-doped perovskite Gdx1-xFeO3-δ as high-performance materials for oxygen separation

doi:10.1016/j.cjche.2015.08.023

Chinese Journal of Chemical Engineering ›› 2015, Vol. 23 ›› Issue (11): 1763-1767.DOI: 10.1016/j.cjche.2015.08.023

Cobalt-free gadolinium-doped perovskite Gd_x_1-xFeO_3-δ as high-performance materials for oxygen separation

Yanjie Wang, Qing Liao, Yan Chen, Libin Zhuang, Haihui Wang

School of Chemistry & Chemical Engineering, South China University of Technology, Guangzhou 510640, China

收稿日期:2015-05-06 修回日期:2015-06-16 出版日期:2015-11-28 发布日期:2015-12-18
通讯作者: Haihui Wang
基金资助:
Supported by the National Science Fund for Distinguished Young Scholars of China (21225625), the National Natural Science Foundation of China (21176087) and the Specialized Research Fund for the Doctoral Program of Higher Education (20110172110013).

Cobalt-free gadolinium-doped perovskite Gd_x_1-xFeO_3-δ as high-performance materials for oxygen separation

Yanjie Wang, Qing Liao, Yan Chen, Libin Zhuang, Haihui Wang

School of Chemistry & Chemical Engineering, South China University of Technology, Guangzhou 510640, China

Received:2015-05-06 Revised:2015-06-16 Online:2015-11-28 Published:2015-12-18
Contact: Haihui Wang
Supported by:
Supported by the National Science Fund for Distinguished Young Scholars of China (21225625), the National Natural Science Foundation of China (21176087) and the Specialized Research Fund for the Doctoral Program of Higher Education (20110172110013).

摘要/Abstract

摘要： Cobalt-free oxides Gd_x_1-xFeO_3-δ (0.01 ≤ x ≤ 0.1)were achieved by a solid state reactionmethod. It is found that Gd_x_1-xFeO_3-δ (0.025 ≤ x ≤ 0.1) exhibits the cubic perovskite structure. Among Gd_x_1-xFeO_3-δ (0.025 ≤ x ≤ 0.1), the Gd_0.025Ba_0.975FeO_3-δ (GBF2.5) membrane shows the outstanding phase structure stability and the highest oxygen permeation,which can reach 1.44ml·cm^-2·min^-1 at 950 ℃ under air/He oxygen partial pressure gradient. The GBF2.5 membranewas successfully operated formore than 100 h at 800 ℃ and the oxygen permeation flux through the membrane is 0.62 ml·cm^-2·min^-1. After 100 h oxygen permeation experiment at 800 ℃, X-ray diffraction (XRD) and energy dispersive X-ray spectrometer (EDXS) demonstrate that the GBF2.5 exhibits phase structure stability even at intermediate temperature.

关键词: Perovskite, Membranes, Permeation, BaFeO_3-&delta, , Oxygen separation

Abstract: Cobalt-free oxides Gd_x_1-xFeO_3-δ (0.01 ≤ x ≤ 0.1)were achieved by a solid state reactionmethod. It is found that Gd_x_1-xFeO_3-δ (0.025 ≤ x ≤ 0.1) exhibits the cubic perovskite structure. Among Gd_x_1-xFeO_3-δ (0.025 ≤ x ≤ 0.1), the Gd_0.025Ba_0.975FeO_3-δ (GBF2.5) membrane shows the outstanding phase structure stability and the highest oxygen permeation,which can reach 1.44ml·cm^-2·min^-1 at 950 ℃ under air/He oxygen partial pressure gradient. The GBF2.5 membranewas successfully operated formore than 100 h at 800 ℃ and the oxygen permeation flux through the membrane is 0.62 ml·cm^-2·min^-1. After 100 h oxygen permeation experiment at 800 ℃, X-ray diffraction (XRD) and energy dispersive X-ray spectrometer (EDXS) demonstrate that the GBF2.5 exhibits phase structure stability even at intermediate temperature.

Key words: Perovskite, Membranes, Permeation, BaFeO_3-&delta, , Oxygen separation

Yanjie Wang, Qing Liao, Yan Chen, Libin Zhuang, Haihui Wang. Cobalt-free gadolinium-doped perovskite Gd_x_1-xFeO_3-δ as high-performance materials for oxygen separation[J]. Chinese Journal of Chemical Engineering, 2015, 23(11): 1763-1767.

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Cobalt-free gadolinium-doped perovskite Gd_x_1-xFeO_3-δ as high-performance materials for oxygen separation

Cobalt-free gadolinium-doped perovskite Gd_x_1-xFeO_3-δ as high-performance materials for oxygen separation

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