Hemicellulose in corn straw: Extracted from alkali solution and produced 5-hydroxymethyl furfural in HCOOH/HCOONa buffer solution

doi:10.1016/j.cjche.2016.05.016

›› 2016, Vol. 24 ›› Issue (12): 1786-1792.DOI: 10.1016/j.cjche.2016.05.016

• Biotechnology and Bioengineering • 上一篇

Hemicellulose in corn straw: Extracted from alkali solution and produced 5-hydroxymethyl furfural in HCOOH/HCOONa buffer solution

Yan Li, Hongxian Fan, Xueqing Yu, Songmei Zhang, Gang Li

Hebei Provincial Key Lab of Green Chemical Technology and High Efficient Energy Saving, School of Chemical Engineering and Technology, Hebei University of Technology, Tianjin 300130, China

收稿日期:2016-03-31 修回日期:2016-05-20 出版日期:2016-12-28 发布日期:2017-01-04
通讯作者: Gang Li,Tel.:+862260202443. E-mail address:ligang@hebut.edu.cn
基金资助:
Supported by the National Natural Science Foundation of China (No. 21576067).

Hemicellulose in corn straw: Extracted from alkali solution and produced 5-hydroxymethyl furfural in HCOOH/HCOONa buffer solution

Yan Li, Hongxian Fan, Xueqing Yu, Songmei Zhang, Gang Li

Hebei Provincial Key Lab of Green Chemical Technology and High Efficient Energy Saving, School of Chemical Engineering and Technology, Hebei University of Technology, Tianjin 300130, China

Received:2016-03-31 Revised:2016-05-20 Online:2016-12-28 Published:2017-01-04
Supported by:
Supported by the National Natural Science Foundation of China (No. 21576067).

摘要/Abstract

摘要： Hemicellulose in corn straw is a group of complex heteropolysaccharides which are composed of different sugar units, including mannans, xylans, arabinans and galactans. This study developed a simple and practical process for production of 5-hydroxymethyl furfural (HMF) using hemicellulose that was extracted from corn straw. In the hemicellulose degradation process HCOOH/HCOONa was used as buffer solution, and the optimum conditions for maximum HMF yield were explored. Various extraction conditions including NaOH concentration, reaction time, temperature, solid-to-liquid ratio and precipitant were tested for hemicellulose obtaining, giving the optimum condition of 55℃, 4 h, solid-to-liquid ratio of 1:10, 1.5 mol·L^-1 NaOH solution and ethanol as precipitant with the yield of 34.16%. Dehydration of hemicellulose under HCOOH/HCOONa buffer solution process, using solution medium of pH=0.8 hydrolyzed hemicellulose in corn straw at 190℃ after 190 min and 82% of HMF yield was achieved.

关键词: Hemicellulose, HMF, Degradation, Buffer solution, ELSD

Abstract: Hemicellulose in corn straw is a group of complex heteropolysaccharides which are composed of different sugar units, including mannans, xylans, arabinans and galactans. This study developed a simple and practical process for production of 5-hydroxymethyl furfural (HMF) using hemicellulose that was extracted from corn straw. In the hemicellulose degradation process HCOOH/HCOONa was used as buffer solution, and the optimum conditions for maximum HMF yield were explored. Various extraction conditions including NaOH concentration, reaction time, temperature, solid-to-liquid ratio and precipitant were tested for hemicellulose obtaining, giving the optimum condition of 55℃, 4 h, solid-to-liquid ratio of 1:10, 1.5 mol·L^-1 NaOH solution and ethanol as precipitant with the yield of 34.16%. Dehydration of hemicellulose under HCOOH/HCOONa buffer solution process, using solution medium of pH=0.8 hydrolyzed hemicellulose in corn straw at 190℃ after 190 min and 82% of HMF yield was achieved.

Key words: Hemicellulose, HMF, Degradation, Buffer solution, ELSD

Yan Li, Hongxian Fan, Xueqing Yu, Songmei Zhang, Gang Li. Hemicellulose in corn straw: Extracted from alkali solution and produced 5-hydroxymethyl furfural in HCOOH/HCOONa buffer solution[J]. , 2016, 24(12): 1786-1792.

参考文献

[1] M. Anggraini, A. Kurniawan, K.O. Lu, et al., Antibiotic detoxification from synthetic and real effluents using a novel MTAB surfactant-montmorillonite (organoclay) sorbent, RSC Adv. 4(31) (2014) 16298-16311.
[2] M.A. Paivi, S. Tapio, H. Bjarne, et al., Synthesis of sugars by hydrolysis of hemicelluloses-A review. Chem. Rev. 111(9) (2011) 5638-5666.
[3] Y. Lu, Kinetic and mechanistic studies of a biomimetic catalyst for hemicellulosic biomass hydrolysis, ProQuest, 2008.
[4] T.D. Matson, B. Katalin, A.V. Iretskii, et al., One-pot catalytic conversion of cellulose and of woody biomass solids to liquid fuels, J. Am. Chem. Soc. 133(35) (2011) 14090-14097.
[5] W. Yang, A. Sen, One-step catalytic transformation of carbohydrates and cellulosic biomass to 2,5-dimethyltetrahydrofuran for liquid fuels, ChemSusChem 3(5) (2010) 597-603.
[6] M. Chatterjee, Hydrogenation of 5-hydroxymethylfurfural in supercritical carbon dioxide-water:A tunable approach to dimethylfuran selectivity, Green Chem. 16(3) (2014) 1543-1551.
[7] Y. Zu, P. Yang, J. Wang, et al., Efficient production of the liquid fuel 2,5-dimethylfuran from 5-hydroxymethylfurfural over Ru/Co₃O₄ catalyst, Appl. Catal. B Environ. 146(3) (2014) 244-248.
[8] J.F. White, Top value-added chemicals from biomass volume II-Results of screening for potential candidates from biorefinery lignin, Biomass Fuels 2(2007) 263-275.
[9] M.J. Antal, W.S.L. Mok, G.N. Richards, Mechanism of formation of 5-(hydroxymethyl)-2-furaldehyde from d-fructose and sucrose, Carbohydr. Res. 199(1) (1990) 91-109.
[10] N. Jiang, R. Huang, W. Qi, et al., Effect of formic acid on conversion of fructose to 5-hydroxymethylfurfural in aqueous/butanol media, Bioenergy Res. 5(2) (2012) 380-386.
[11] K.K. Pandey, A study of chemical structure of soft and hardwood and wood polymers by FTIR spectroscopy, J. Appl. Polym. Sci. 71(12) (1999) 1969-1975.
[12] R. Weingarten, A. Rodriguez-Beuerman, F. Cao, et al., Selective conversion of cellulose to hydroxymethylfurfural in polar aprotic solvents, ChemCatChem 6(8) (2014) 2229-2234.
[13] J.A. Chun, J.W. Lee, Y.B. Yi, et al., Direct conversion of starch to hydroxymethylfurfural in the presence of an ionic liquid with metal chloride, Tex. Dent. J. 62(6) (2010) 326-330.
[14] L. Yang, C. Jie, J. Mao, et al., Sodium carbonate-sodium sulfite pretreatment for improving the enzymatic hydrolysis of rice straw, Ind. Crop. Prod. 43(1) (2013) 711-717.
[15] M.G. Jackson, Review article:The alkali treatment of straws, Anim. Feed Sci. Technol. 2(2) (1977) 105-130.
[16] F.R. Tao, C. Zhuang, Y.Z. Cui, et al., Dehydration of glucose into 5-hydroxymethylfurfural in SO₃H-functionalized ionic liquids, Chin. Chem. Lett. 25(5) (2014) 757-761.
[17] X. Liu, N. Ai, H. Zhang, et al., Quantification of glucose, xylose, arabinose, furfural, and HMF in corncob hydrolysate by HPLC-PDA-ELSD, Carbohydr. Res. 353(9) (2012) 111-114.
[18] M. Roslund, P. Tahtinen, M. Niemitz, et al., Complete assignments of the ¹H and ¹³C chemical shifts and J(H,H) coupling constants in NMR spectra of D-glucopyranose and all D-glucopyranosyl-D-glucopyranosides, Carbohydr. Res. 343(1) (2008) 101-112.
[19] Q.Q. Wu, Y.L. Ma, X. Chang, et al., Optimization and kinetic analysis on the sulfuric acid-catalyzed depolymerization of wheat straw, Carbohydr. Polym. 129(2015) 79-86.
[20] M.J. Antal, T. Leesomboon, W.S. Mok, et al., Mechanism of formation of 2-furaldehyde from d-xylose, Carbohydr. Res. 91(1991) 71-85.
[21] D. Ferreira, A. Barros, M.A. Coimbra, et al., Use of FT-IR spectroscopy to follow the effect of processing in cell wall polysaccharide extracts of a sun-dried pear, Carbohydr. Polym. 45(2) (2001) 175-182.
[22] T. Guo, X. Tong, C. Yi, et al., Tin-catalyzed efficient conversion of carbohydrates for the production of 5-hydroxymethylfurfural in the presence of quaternary ammonium salts, Carbohydr. Res. 370(14) (2013) 33-37.
[23] F. Benvenuti, C. Carlini, P. Patrono, et al., Heterogeneous zirconium and titanium catalysts for the selective synthesis of 5-hydroxymethyl-2-furaldehyde from carbohydrates, Appl. Catal. A Gen. 193(1-2) (2000) 147-153.
[24] A. Avci, B.C. Saha, G.J. Kennedy, et al., High temperature dilute phosphoric acid pretreatment of corn stover for furfural and ethanol production, Ind. Crop. Prod. 50(10) (2013) 478-484.
[25] J.Q. Li, The chemistry and technology of furfural and its many by-products, Chem. Eng. J. 81(1) (2001) 338-339.
[26] R. Karinen, K. Vilonen, P. Niemelä, Biorefining:Heterogeneously catalyzed reactions of carbohydrates for the production of furfural and hydroxymethylfurfural, ChemSusChem 4(8) (2011) 1002-1016.
[27] I. Jiménez-Morales, M. Moreno-Recio, J. Santamaría-González, et al., Mesoporous tantalum oxide as catalyst for dehydration of glucose to 5-hydroxymethylfurfural, Appl. Catal. B Environ. 154-155(7) (2014) 190-196.
[28] H. Liu, C. Hua, C. Song, et al., Commercially available ammonium salt-catalyzed efficient dehydration of fructose to 5-hydroxymethylfurfural in ionic liquid, Inorg. Chim. Acta 428(2015) 32-36.
[29] P. Kavousi, H. Mirhosseini, H. Ghazali, et al., Formation and reduction of 5-hydroxymethylfurfural at frying temperature in model system as a function of amino acid and sugar composition, Food Chem. 182(2015) 164-170.

Hemicellulose in corn straw: Extracted from alkali solution and produced 5-hydroxymethyl furfural in HCOOH/HCOONa buffer solution

Hemicellulose in corn straw: Extracted from alkali solution and produced 5-hydroxymethyl furfural in HCOOH/HCOONa buffer solution

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	Xia Miao, Xiaofan Pang, Shiyu Li, Haoguang Wei, Jianhao Yin, Xiangming Kong. Mechanical strength and the degradation mechanism of metakaolin based geopolymer mixed with ordinary Portland cement and cured at high temperature and high relative humidity[J]. 中国化学工程学报, 2023, 60(8): 118-130.
[2]	Xiaolin Pan, Mengyuan Gao, Yun Wang, Yanping He, Tian Si, Yanlin Sun. Poly(lactic acid)-aspirin microspheres prepared via the traditional and improved solvent evaporation methods and its application performances[J]. 中国化学工程学报, 2023, 60(8): 194-204.
[3]	Hu Chen, Ying Wang, Puyu Wang, Yongkang Lv. Assessing quinoline removal performances of an aerobic continuous moving bed biofilm reactor (MBBR) bioaugmented with Pseudomonas citronellolis LV1[J]. 中国化学工程学报, 2023, 57(5): 132-140.
[4]	Yaqiao Liu, Shuozhen Hu, Xinsheng Zhang, Shigang Sun. Investigation of photoelectrocatalytic degradation mechanism of methylene blue by α-Fe₂O₃ nanorods array[J]. 中国化学工程学报, 2023, 57(5): 162-172.
[5]	Jiajun Wang, Wenbin Yang, Jiangtao Geng, Zhigang Shao, Wei Song. Experimental investigation on degradation mechanism of membrane electrode assembly at different humidity under automotive protocol[J]. 中国化学工程学报, 2023, 56(4): 70-79.
[6]	Iltaf Khan, Chunjuan Wang, Shoaib Khan, Jinyin Chen, Aftab Khan, Sayyar Ali Shah, Aihua Yuan, Sohail Khan, Mehwish K. Butt, Humaira Asghar. Bio-capped and green synthesis of ZnO/g-C₃N₄ nanocomposites and its improved antibiotic and photocatalytic activities: An exceptional approach towards environmental remediation[J]. 中国化学工程学报, 2023, 56(4): 215-224.
[7]	Abid Ali, Bilal Ul Amin, Wenwu Yu, Taijiang Gui, Weiwei Cong, Kai Zhang, Zheming Tong, Jiankun Hu, Xiaoli Zhan, Qinghua Zhang. Eco-friendly biodegradable polyurethane based coating for antibacterial and antifouling performance[J]. 中国化学工程学报, 2023, 54(2): 80-88.
[8]	Jingjing Pan, Haoran Sun, Keyi Chen, Yuhao Zhang, Pengnian Shan, Weilong Shi, Feng Guo. Nanodiamonds decorated yolk-shell ZnFe₂O₄ sphere as magnetically separable and recyclable composite for boosting antibiotic degradation performance[J]. 中国化学工程学报, 2023, 54(2): 162-172.
[9]	Chao Zhang, Youzhi Liu, Weizhou Jiao, Hongyan Shen, Xigang Yuan, Shengkun Jia. An optimization method for enhancement of gas–liquid mass transfer in a bubble column reactor based on the entropy generation extremum principle[J]. 中国化学工程学报, 2023, 53(1): 83-88.
[10]	Hongwei Guo, Linyuan Chen, Xueying Zhang, Huanhao Chen, Yan Shao. Silicalite-1 zeolite encapsulated Fe nanocatalyst for Fenton-like degradation of methylene blue[J]. 中国化学工程学报, 2023, 53(1): 251-259.
[11]	Feng Guo, Chunli Shi, Wei Sun, Yanan Liu, Xue Lin, Weilong Shi. Pomelo biochar as an electron acceptor to modify graphitic carbon nitride for boosting visible-light-driven photocatalytic degradation of tetracycline[J]. 中国化学工程学报, 2022, 48(8): 1-11.
[12]	Min Lu, Mengxuan Liu, Chunli Xu, Yu Yin, Lei Shi, Hong Wu, Aihua Yuan, Xiao-Ming Ren, Shaobin Wang, Hongqi Sun. Location and size regulation of manganese oxides within mesoporous silica for enhanced antibiotic degradation[J]. 中国化学工程学报, 2022, 48(8): 36-43.
[13]	Hao Zhou, Qi Yin. Hydrothermal preparation of Nb-doped NaTaO₃ with enhanced photocatalytic activity for removal of organic dye[J]. 中国化学工程学报, 2022, 46(6): 142-149.
[14]	Jiafei Wu, Yuning Jin, Danping Wu, Xiaoying Yan, Na Ma, Wei Dai. Well-construction of Zn₂SnO₄/SnO₂@ZIF-8 core–shell hetero-structure with efficient photocatalytic activity towards tetracycline under restricted space[J]. 中国化学工程学报, 2022, 52(12): 45-55.
[15]	Fenghongkang Pan, Yimeng Wang, Kaiqing Zhao, Jun Hu, Honglai Liu, Ying Hu. Photocatalytic degradation of tetracycline hydrochloride with visible light-responsive bismuth tungstate/conjugated microporous polymer[J]. 中国化学工程学报, 2022, 41(1): 488-496.