Simple separation method of Zn(II) and Cd(II) from brine solution of zinc plant residue and synthetic chloride media using solvent extraction

doi:10.1016/j.cjche.2019.12.003

中国化学工程学报 ›› 2020, Vol. 28 ›› Issue (4): 1055-1061.DOI: 10.1016/j.cjche.2019.12.003

• Separation Science and Engineering • 上一篇下一篇

Simple separation method of Zn(II) and Cd(II) from brine solution of zinc plant residue and synthetic chloride media using solvent extraction

Ali Asghar Balesini Aghdam¹, Hossein Yoozbashizadeh¹, Javad Moghaddam²

1 Department of Materials Engineering, Science and Research Branch, Islamic Azad University, Tehran, Iran;
2 Materials and Metallurgical Engineering Department, University of Zanjan, Zanjan, Iran

收稿日期:2019-09-22 修回日期:2019-11-24 出版日期:2020-04-28 发布日期:2020-07-27
通讯作者: Hossein Yoozbashizadeh
基金资助:
The authors gratefully acknowledge the Zanjan Zinc Khalessazan Industries Company (ZZKICO), Znajan, Iran and Science and Research Branch, Islamic Azad University (IAU), Tehran, Iran for the financial and technical support of this work.

Simple separation method of Zn(II) and Cd(II) from brine solution of zinc plant residue and synthetic chloride media using solvent extraction

Ali Asghar Balesini Aghdam¹, Hossein Yoozbashizadeh¹, Javad Moghaddam²

1 Department of Materials Engineering, Science and Research Branch, Islamic Azad University, Tehran, Iran;
2 Materials and Metallurgical Engineering Department, University of Zanjan, Zanjan, Iran

Received:2019-09-22 Revised:2019-11-24 Online:2020-04-28 Published:2020-07-27
Contact: Hossein Yoozbashizadeh
Supported by:
The authors gratefully acknowledge the Zanjan Zinc Khalessazan Industries Company (ZZKICO), Znajan, Iran and Science and Research Branch, Islamic Azad University (IAU), Tehran, Iran for the financial and technical support of this work.

摘要/Abstract

摘要： In this work, the possibility of separation of Zn²⁺ and Cd²⁺ metal ions from chloride (brine) solutions was examined. For this purpose, simple solvent extraction (SX) experiments by di-2-ethylhexyl phosphoric acid (D2EHPA) in kerosene as a diluent was performed on synthetic and industrial chloride solution obtained from brine leaching of zinc filter cakes (by-product of zinc hydrometallurgical processing). The optimal conditions for separation were determined. The zinc extraction efficiency was 99% with negligible co-extraction of cadmium. Therefore, a high ΔpH_0.5 value for Zn(Ⅱ) and Cd(Ⅱ) was achieved. FT-IR and slope analysis indicated that ZnClA·3HA and CdClA·3HA species were probably extracted.

关键词: Solvent extraction, Brine media, Leaching filter cakes, Zinc, Cadmium

Abstract: In this work, the possibility of separation of Zn²⁺ and Cd²⁺ metal ions from chloride (brine) solutions was examined. For this purpose, simple solvent extraction (SX) experiments by di-2-ethylhexyl phosphoric acid (D2EHPA) in kerosene as a diluent was performed on synthetic and industrial chloride solution obtained from brine leaching of zinc filter cakes (by-product of zinc hydrometallurgical processing). The optimal conditions for separation were determined. The zinc extraction efficiency was 99% with negligible co-extraction of cadmium. Therefore, a high ΔpH_0.5 value for Zn(Ⅱ) and Cd(Ⅱ) was achieved. FT-IR and slope analysis indicated that ZnClA·3HA and CdClA·3HA species were probably extracted.

Key words: Solvent extraction, Brine media, Leaching filter cakes, Zinc, Cadmium

Ali Asghar Balesini Aghdam, Hossein Yoozbashizadeh, Javad Moghaddam. Simple separation method of Zn(II) and Cd(II) from brine solution of zinc plant residue and synthetic chloride media using solvent extraction[J]. 中国化学工程学报, 2020, 28(4): 1055-1061.

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Simple separation method of Zn(II) and Cd(II) from brine solution of zinc plant residue and synthetic chloride media using solvent extraction

Simple separation method of Zn(II) and Cd(II) from brine solution of zinc plant residue and synthetic chloride media using solvent extraction

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