SCI和EI收录∣中国化工学会会刊

中国化学工程学报 ›› 2020, Vol. 28 ›› Issue (9): 2301-2311.DOI: 10.1016/j.cjche.2020.04.002

• Separation Science and Engineering • 上一篇    下一篇

New high permeable polysulfone/ionic liquid membrane for gas separation

Mohadeseh Farrokhara, Fatereh Dorosti   

  1. Department of Chemical Engineering, Rasht Branch, Islamic Azad University, Rasht 41335-3516, Iran
  • 收稿日期:2019-11-30 修回日期:2020-03-26 出版日期:2020-09-28 发布日期:2020-10-21
  • 通讯作者: Fatereh Dorosti

New high permeable polysulfone/ionic liquid membrane for gas separation

Mohadeseh Farrokhara, Fatereh Dorosti   

  1. Department of Chemical Engineering, Rasht Branch, Islamic Azad University, Rasht 41335-3516, Iran
  • Received:2019-11-30 Revised:2020-03-26 Online:2020-09-28 Published:2020-10-21
  • Contact: Fatereh Dorosti

摘要: In this study, the effects of 1-Ethyl-3-methylimidazolium tetrafluoroborate ionic liquid on CO2/CH4 separation performance of symmetric polysulfone membranes are investigated. Pure polysulfone membrane and ionic liquid-containing membranes are characterized. Field emission scanning electron microscopy (FE-SEM) is used to analyze surface morphology and thickness of the fabricated membranes. Energy dispersive spectroscopy (EDS) and elemental mapping, Fourier transform infrared (FTIR), thermal gravimetric (TGA), X-ray diffraction (XRD) and Tensile strength analyses are also conducted to characterize the prepared membranes. CO2/CH4 separation performance of the membranes are measured twice at 0.3 MPa and room temperature (25 °C). Permeability measurements confirm that increasing ionic liquid content in polymer-ionic liquid membranes leads to a growth in CO2 permeation and CO2/CH4 selectivity due to high affinity of the ionic liquid to carbon dioxide. CO2 permeation significantly increases from 4.3 Barrer (1 Barrer=10-10 cm3(STP)·cm·cm-2·s-1·cmHg-1, 1cmHg=1.333kPa) for the pure polymer membrane to 601.9 Barrer for the 30 wt% ionic liquid membrane. Also, selectivity of this membrane is improved from 8.2 to 25.8. mixed gas tests are implemented to investigate gases interaction. The results showed, the disruptive effect of CH4 molecules for CO2 permeation lead to selectivity decrement compare to pure gas test. The fabricated membranes with high ionic liquid content in this study are promising materials for industrial CO2/CH4 separation membranes.

关键词: Membrane, CO2/CH4 separation, Polysulfone, Ionic liquid

Abstract: In this study, the effects of 1-Ethyl-3-methylimidazolium tetrafluoroborate ionic liquid on CO2/CH4 separation performance of symmetric polysulfone membranes are investigated. Pure polysulfone membrane and ionic liquid-containing membranes are characterized. Field emission scanning electron microscopy (FE-SEM) is used to analyze surface morphology and thickness of the fabricated membranes. Energy dispersive spectroscopy (EDS) and elemental mapping, Fourier transform infrared (FTIR), thermal gravimetric (TGA), X-ray diffraction (XRD) and Tensile strength analyses are also conducted to characterize the prepared membranes. CO2/CH4 separation performance of the membranes are measured twice at 0.3 MPa and room temperature (25 °C). Permeability measurements confirm that increasing ionic liquid content in polymer-ionic liquid membranes leads to a growth in CO2 permeation and CO2/CH4 selectivity due to high affinity of the ionic liquid to carbon dioxide. CO2 permeation significantly increases from 4.3 Barrer (1 Barrer=10-10 cm3(STP)·cm·cm-2·s-1·cmHg-1, 1cmHg=1.333kPa) for the pure polymer membrane to 601.9 Barrer for the 30 wt% ionic liquid membrane. Also, selectivity of this membrane is improved from 8.2 to 25.8. mixed gas tests are implemented to investigate gases interaction. The results showed, the disruptive effect of CH4 molecules for CO2 permeation lead to selectivity decrement compare to pure gas test. The fabricated membranes with high ionic liquid content in this study are promising materials for industrial CO2/CH4 separation membranes.

Key words: Membrane, CO2/CH4 separation, Polysulfone, Ionic liquid