SCI和EI收录∣中国化工学会会刊

中国化学工程学报 ›› 2021, Vol. 33 ›› Issue (5): 286-296.DOI: 10.1016/j.cjche.2020.07.032

• Resources and Environmental Technology • 上一篇    下一篇

In-depth investigation on the factors affecting the performance of high oil-absorption resin by response surface method

Lei Ma1, Hongxia Lv1, Haonan Yu1, Lingtong Kong1, Rongyue Zhang1, Xiaoyan Guo1, Haibo Jin1, Guangxiang He1, Xiaoyan Liu2   

  1. 1 Beijing Key Laboratory of Fuels Cleaning and Advanced Catalytic Emission Reduction Technology, College of Chemical Engineering, Beijing Institute of Petrochemical Technology, Beijing 102617,;
    China;
    2 Water Resource Office of Jining City, Shandong Province, Jining 272019, China
  • 收稿日期:2020-03-20 修回日期:2020-07-09 出版日期:2021-05-28 发布日期:2021-08-19
  • 通讯作者: Haibo Jin, Guangxiang He
  • 基金资助:
    This work was funded by Project of Construction of Innovative Teams and Teacher Career Development for Universities and Colleges under Beijing Municipality (IDHT20180508), Scientific Research Common Program of Beijing Municipal Commission of Education (KM202010017006), the Talents Project of Beijing Organization Department (2018000020124G091), the Strategic Priority Research Program of the Chinese Academy of Sciences (XDA21021101) and the National Key Research and Development Program of China (2019YFA0705803).

In-depth investigation on the factors affecting the performance of high oil-absorption resin by response surface method

Lei Ma1, Hongxia Lv1, Haonan Yu1, Lingtong Kong1, Rongyue Zhang1, Xiaoyan Guo1, Haibo Jin1, Guangxiang He1, Xiaoyan Liu2   

  1. 1 Beijing Key Laboratory of Fuels Cleaning and Advanced Catalytic Emission Reduction Technology, College of Chemical Engineering, Beijing Institute of Petrochemical Technology, Beijing 102617,;
    China;
    2 Water Resource Office of Jining City, Shandong Province, Jining 272019, China
  • Received:2020-03-20 Revised:2020-07-09 Online:2021-05-28 Published:2021-08-19
  • Contact: Haibo Jin, Guangxiang He
  • Supported by:
    This work was funded by Project of Construction of Innovative Teams and Teacher Career Development for Universities and Colleges under Beijing Municipality (IDHT20180508), Scientific Research Common Program of Beijing Municipal Commission of Education (KM202010017006), the Talents Project of Beijing Organization Department (2018000020124G091), the Strategic Priority Research Program of the Chinese Academy of Sciences (XDA21021101) and the National Key Research and Development Program of China (2019YFA0705803).

摘要: A series of high oil-absorption resins with low cross-linking degree were synthesized by suspension polymerization using stearyl methacrylate (SMA), 2-Ethylhexyl methacrylate (EHMA), and styrene (St) as monomers. Response surface methodology (RSM) with central composite design (CCD) was also applied to determine the optimal parameters that are mainly known to affect their synthesis. Thus, the effects of the monomer mass ratio (EHMA:SMA), the rigid monomer (St) dosage, the porous agent (acetone) dosage, and their pairwise interaction on the resin's oil-absorption capacity were analyzed, highlighting PSES-R2 as the resin with the optimum performance. The pure oil-absorption rates of PSES-R2 for gasoline, diesel, and kerosene were 11.19 g·g-1, 16.25 g·g-1, and 14.84 g·g-1, respectively, while the oil removal rates from oily wastewater were 98.82%, 65.11%, and 99.63%, respectively.

关键词: Oil-absorption resin, Response surface method, Oil removal rate, Waste water, Absorption, Polymerization

Abstract: A series of high oil-absorption resins with low cross-linking degree were synthesized by suspension polymerization using stearyl methacrylate (SMA), 2-Ethylhexyl methacrylate (EHMA), and styrene (St) as monomers. Response surface methodology (RSM) with central composite design (CCD) was also applied to determine the optimal parameters that are mainly known to affect their synthesis. Thus, the effects of the monomer mass ratio (EHMA:SMA), the rigid monomer (St) dosage, the porous agent (acetone) dosage, and their pairwise interaction on the resin's oil-absorption capacity were analyzed, highlighting PSES-R2 as the resin with the optimum performance. The pure oil-absorption rates of PSES-R2 for gasoline, diesel, and kerosene were 11.19 g·g-1, 16.25 g·g-1, and 14.84 g·g-1, respectively, while the oil removal rates from oily wastewater were 98.82%, 65.11%, and 99.63%, respectively.

Key words: Oil-absorption resin, Response surface method, Oil removal rate, Waste water, Absorption, Polymerization