SCI和EI收录∣中国化工学会会刊

中国化学工程学报 ›› 2021, Vol. 29 ›› Issue (1): 1-12.DOI: 10.1016/j.cjche.2020.08.024

• Review •    下一篇

Perspectives and challenges of hydrogen storage in solid-state hydrides

Zhen Chen1,2, Zhongliang Ma1,3, Jie Zheng4, Xingguo Li4, Etsuo Akiba1,5, Hai-Wen Li1,5,6   

  1. 1 International Research Center for Hydrogen Energy, Kyushu University, 744 Motooka Nishi-ku, Fukuoka 819-0395, Japan;
    2 School of Chemistry and Chemical Engineering, Qilu University of Technology(Shandong Academy of Sciences), Jinan 250353, China;
    3 College of Materials Science and Engineering, Nanjing Tech University, Nanjing 211816, China;
    4 Beijing National Laboratory for Molecular Science, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China;
    5 International Institute for Carbon-Neutral Energy Research, Kyushu University, 744 Motooka Nishi-ku, Fukuoka 819-0395, Japan;
    6 Platform of Inter/Transdisciplinary Energy Research, Kyushu University, 744 Motooka Nishi-ku, Fukuoka 819-0395, Japan
  • 收稿日期:2020-05-30 修回日期:2020-07-21 出版日期:2021-01-28 发布日期:2021-04-02
  • 通讯作者: Hai-Wen Li
  • 基金资助:
    The authors gratefully acknowledge the support from the JSPS KAKENHI (Grant Number 18H01738) and the Progress 100 program of Kyushu University. ZC is grateful to Qilu University of Technology (Shandong Academy of Sciences) for the financial support by the program of studying/visiting abroad (No. 450404).

Perspectives and challenges of hydrogen storage in solid-state hydrides

Zhen Chen1,2, Zhongliang Ma1,3, Jie Zheng4, Xingguo Li4, Etsuo Akiba1,5, Hai-Wen Li1,5,6   

  1. 1 International Research Center for Hydrogen Energy, Kyushu University, 744 Motooka Nishi-ku, Fukuoka 819-0395, Japan;
    2 School of Chemistry and Chemical Engineering, Qilu University of Technology(Shandong Academy of Sciences), Jinan 250353, China;
    3 College of Materials Science and Engineering, Nanjing Tech University, Nanjing 211816, China;
    4 Beijing National Laboratory for Molecular Science, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China;
    5 International Institute for Carbon-Neutral Energy Research, Kyushu University, 744 Motooka Nishi-ku, Fukuoka 819-0395, Japan;
    6 Platform of Inter/Transdisciplinary Energy Research, Kyushu University, 744 Motooka Nishi-ku, Fukuoka 819-0395, Japan
  • Received:2020-05-30 Revised:2020-07-21 Online:2021-01-28 Published:2021-04-02
  • Contact: Hai-Wen Li
  • Supported by:
    The authors gratefully acknowledge the support from the JSPS KAKENHI (Grant Number 18H01738) and the Progress 100 program of Kyushu University. ZC is grateful to Qilu University of Technology (Shandong Academy of Sciences) for the financial support by the program of studying/visiting abroad (No. 450404).

摘要: Hydrogen has been widely considered as a clean energy carrier that bridges the energy producers and energy consumers in an efficient and safe way for a sustainable society. Hydrogen can be stored in a gas, liquid and solid states and each method has its unique advantage. Though compressed hydrogen and liquefied hydrogen are mature technologies for industrial applications, appropriate measures are necessary to deal with the issues at high pressure up to around 100 MPa and low temperature at around 20 K. Distinct from those technologies, storing hydrogen in solid-state hydrides can realize a more compact and much safer approach that does not require high hydrogen pressure and cryogenic temperature. In this review, we will provide an overview of the major material groups that are capable of absorbing and desorbing hydrogen reversibly. The main features on hydrogen storage properties of each material group are summarized, together with the discussion of the key issues and the guidance of materials design, aiming at providing insights for new material development as well as industrial applications.

关键词: Hydrogen, Hydrogen storage, Hydride, Hydrogen energy, Renewable energy, Environment

Abstract: Hydrogen has been widely considered as a clean energy carrier that bridges the energy producers and energy consumers in an efficient and safe way for a sustainable society. Hydrogen can be stored in a gas, liquid and solid states and each method has its unique advantage. Though compressed hydrogen and liquefied hydrogen are mature technologies for industrial applications, appropriate measures are necessary to deal with the issues at high pressure up to around 100 MPa and low temperature at around 20 K. Distinct from those technologies, storing hydrogen in solid-state hydrides can realize a more compact and much safer approach that does not require high hydrogen pressure and cryogenic temperature. In this review, we will provide an overview of the major material groups that are capable of absorbing and desorbing hydrogen reversibly. The main features on hydrogen storage properties of each material group are summarized, together with the discussion of the key issues and the guidance of materials design, aiming at providing insights for new material development as well as industrial applications.

Key words: Hydrogen, Hydrogen storage, Hydride, Hydrogen energy, Renewable energy, Environment