A breathing A4 paper by in situ growth of green metal–organic frameworks for air freshening and cleaning

doi:10.1016/j.cjche.2021.12.003

中国化学工程学报 ›› 2022, Vol. 52 ›› Issue (12): 95-102.DOI: 10.1016/j.cjche.2021.12.003

• Full Length Article • 上一篇下一篇

A breathing A4 paper by in situ growth of green metal–organic frameworks for air freshening and cleaning

Bo Zhang¹, Hongwen Chen¹, Liming Jiang², Youqing Shen^1,4, Dan Zhao³, Zhuxian Zhou^1,4

1. Key Laboratory of Biomass Chemical Engineering of Ministry of Education and Zhejiang Key Laboratory of Smart Biomaterials, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, China;
2. Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, China;
3. Department of Chemical & Biomolecular Engineering, National University of Singapore, 117585, Singapore;
4. Hangzhou Global Scientific and Technological Innovation Center, Zhejiang University, Hangzhou 311215, China

收稿日期:2021-08-14 修回日期:2021-11-29 出版日期:2022-12-28 发布日期:2023-01-31
通讯作者: Zhuxian Zhou,E-mail:zhouzx@zju.edu.cn
基金资助:
This work is supported by the National Key Research and Development Program of China (2016YFA0200301), the National Natural Science Foundation of China (21875211, 52073249, 51833008, and 51603181), and the Zhejiang Provincial Key Research and Development Program (2020C01123).

A breathing A4 paper by in situ growth of green metal–organic frameworks for air freshening and cleaning

Bo Zhang¹, Hongwen Chen¹, Liming Jiang², Youqing Shen^1,4, Dan Zhao³, Zhuxian Zhou^1,4

1. Key Laboratory of Biomass Chemical Engineering of Ministry of Education and Zhejiang Key Laboratory of Smart Biomaterials, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, China;
2. Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, China;
3. Department of Chemical & Biomolecular Engineering, National University of Singapore, 117585, Singapore;
4. Hangzhou Global Scientific and Technological Innovation Center, Zhejiang University, Hangzhou 311215, China

Received:2021-08-14 Revised:2021-11-29 Online:2022-12-28 Published:2023-01-31
Contact: Zhuxian Zhou,E-mail:zhouzx@zju.edu.cn
Supported by:
This work is supported by the National Key Research and Development Program of China (2016YFA0200301), the National Natural Science Foundation of China (21875211, 52073249, 51833008, and 51603181), and the Zhejiang Provincial Key Research and Development Program (2020C01123).

摘要/Abstract

摘要： Surface modification of natural cellulose fibers with nanomaterials is an effective strategy for producing functional textiles for multiple applications. A4-sized printing paper is a commonly used, cheap, and easily acquirable office supply which is mainly made of cellulose fibers. Here, we report green and simple nanofabrication of A4 paper to endow it with high capability for fragrance encapsulation and sustained release, and strong adsorption to indoor air pollutants. The method utilizes the sugar molecule of cellulose for in-situ growth of γ-cyclodextrin (γ-CD) metal–organic frameworks (MOFs) on A4 paper. The obtained γ-CD-MOF/A4 nanocomposites have superior specific surface area and high porous structure. The γ-CD-MOF/A4 nanocomposites can effectively encapsulate fragrant molecules through host–guest interaction. The γ-CD-MOF/A4 nanocomposites also show strong absorption capability to formaldehyde and carbon dioxide through the formation of hydrogen bonding and chemical bonds. These γ-CD-MOF/A4 nanocomposites combine the advantages of both A4 paper and γ-CD-MOF, which can be used in indoor air freshening and cleaning.

关键词: Metal–organic frameworks, A4 printing paper, In situ synthesis, Fragrance encapsulation, Formaldehyde removal, Carbon dioxide capture

Abstract: Surface modification of natural cellulose fibers with nanomaterials is an effective strategy for producing functional textiles for multiple applications. A4-sized printing paper is a commonly used, cheap, and easily acquirable office supply which is mainly made of cellulose fibers. Here, we report green and simple nanofabrication of A4 paper to endow it with high capability for fragrance encapsulation and sustained release, and strong adsorption to indoor air pollutants. The method utilizes the sugar molecule of cellulose for in-situ growth of γ-cyclodextrin (γ-CD) metal–organic frameworks (MOFs) on A4 paper. The obtained γ-CD-MOF/A4 nanocomposites have superior specific surface area and high porous structure. The γ-CD-MOF/A4 nanocomposites can effectively encapsulate fragrant molecules through host–guest interaction. The γ-CD-MOF/A4 nanocomposites also show strong absorption capability to formaldehyde and carbon dioxide through the formation of hydrogen bonding and chemical bonds. These γ-CD-MOF/A4 nanocomposites combine the advantages of both A4 paper and γ-CD-MOF, which can be used in indoor air freshening and cleaning.

Key words: Metal–organic frameworks, A4 printing paper, In situ synthesis, Fragrance encapsulation, Formaldehyde removal, Carbon dioxide capture

Bo Zhang, Hongwen Chen, Liming Jiang, Youqing Shen, Dan Zhao, Zhuxian Zhou. A breathing A4 paper by in situ growth of green metal–organic frameworks for air freshening and cleaning[J]. 中国化学工程学报, 2022, 52(12): 95-102.

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A breathing A4 paper by in situ growth of green metal–organic frameworks for air freshening and cleaning

A breathing A4 paper by in situ growth of green metal–organic frameworks for air freshening and cleaning

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