Fabricating titanium dioxide/N-doped carbon nanofibers as advanced interlayer for improving cycling reversibility of lithium-sulfur batteries

doi:10.1016/j.cjche.2022.03.019

中国化学工程学报 ›› 2022, Vol. 52 ›› Issue (12): 88-94.DOI: 10.1016/j.cjche.2022.03.019

• Full Length Article • 上一篇下一篇

Fabricating titanium dioxide/N-doped carbon nanofibers as advanced interlayer for improving cycling reversibility of lithium-sulfur batteries

Xingmei Guo¹, Jinfeng Xie¹, Jing Wang¹, Shangqing Sun¹, Feng Zhang², Fu Cao¹, Yuanjun Liu¹, Xiangjun Zheng¹, Junhao Zhang¹, Qinghong Kong³

1. School of Environmental and Chemical Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, China;
2. Key Laboratory for Advanced Technology in Environmental Protection of Jiangsu Province, Yancheng Institute of Technology, Yancheng 224051, China;
3. School of the Environment and Safety Engineering, Jiangsu University, Zhenjiang 212013, China

收稿日期:2022-01-03 修回日期:2022-03-04 出版日期:2022-12-28 发布日期:2023-01-31
通讯作者: Junhao Zhang,E-mail:jhzhang6@just.edu.cn
基金资助:
This work was financially supported by the National Natural Science Foundation of China (52102100, 52072330), Industry-University-Research Cooperation Project of Jiangsu Province (BY2021525), Guangdong Basic and Applied Basic Research Foundation (2020A1515110035).

Fabricating titanium dioxide/N-doped carbon nanofibers as advanced interlayer for improving cycling reversibility of lithium-sulfur batteries

Xingmei Guo¹, Jinfeng Xie¹, Jing Wang¹, Shangqing Sun¹, Feng Zhang², Fu Cao¹, Yuanjun Liu¹, Xiangjun Zheng¹, Junhao Zhang¹, Qinghong Kong³

1. School of Environmental and Chemical Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, China;
2. Key Laboratory for Advanced Technology in Environmental Protection of Jiangsu Province, Yancheng Institute of Technology, Yancheng 224051, China;
3. School of the Environment and Safety Engineering, Jiangsu University, Zhenjiang 212013, China

Received:2022-01-03 Revised:2022-03-04 Online:2022-12-28 Published:2023-01-31
Contact: Junhao Zhang,E-mail:jhzhang6@just.edu.cn
Supported by:
This work was financially supported by the National Natural Science Foundation of China (52102100, 52072330), Industry-University-Research Cooperation Project of Jiangsu Province (BY2021525), Guangdong Basic and Applied Basic Research Foundation (2020A1515110035).

摘要/Abstract

摘要： “Shuttle effect” is detrimental for maintaining the high capacity and cycling reversibility of lithium-sulfur batteries (LSBs). To inhibit polysulfide migration, N-doped carbon nanofibers (N-CNFs) membrane comprising TiO₂ nanoparticles (TiO₂/N-CNFs) is fabricated using an electrospinning-calcination method and further applied as interlayer in LSBs. The TiO₂/N-CNFs interlayer helps the battery to deliver a high specific capacity of 1155.2 mA·h·g^-1 at 0.2 C with high Coulombic efficiency, good rate capability and stability. When cycling at 0.5 C, a capacity retention rate of 62.4% is achieved over 300 cycles, which is higher than that of CNFs and TiO₂/CNFs counterparts. The excellent performance should mainly be attributed to the alleviated “shuttle effect” deriving from high polysulfide trapping ability of TiO₂ nanoparticles and N heteroatoms in interwoven CNFs.

关键词: TiO₂/N-CNFs interlayer, Composites, Microstructure, Adsorption, Lithium-sulfur battery, Shuttle effect

Abstract: “Shuttle effect” is detrimental for maintaining the high capacity and cycling reversibility of lithium-sulfur batteries (LSBs). To inhibit polysulfide migration, N-doped carbon nanofibers (N-CNFs) membrane comprising TiO₂ nanoparticles (TiO₂/N-CNFs) is fabricated using an electrospinning-calcination method and further applied as interlayer in LSBs. The TiO₂/N-CNFs interlayer helps the battery to deliver a high specific capacity of 1155.2 mA·h·g^-1 at 0.2 C with high Coulombic efficiency, good rate capability and stability. When cycling at 0.5 C, a capacity retention rate of 62.4% is achieved over 300 cycles, which is higher than that of CNFs and TiO₂/CNFs counterparts. The excellent performance should mainly be attributed to the alleviated “shuttle effect” deriving from high polysulfide trapping ability of TiO₂ nanoparticles and N heteroatoms in interwoven CNFs.

Key words: TiO₂/N-CNFs interlayer, Composites, Microstructure, Adsorption, Lithium-sulfur battery, Shuttle effect

Xingmei Guo, Jinfeng Xie, Jing Wang, Shangqing Sun, Feng Zhang, Fu Cao, Yuanjun Liu, Xiangjun Zheng, Junhao Zhang, Qinghong Kong. Fabricating titanium dioxide/N-doped carbon nanofibers as advanced interlayer for improving cycling reversibility of lithium-sulfur batteries[J]. 中国化学工程学报, 2022, 52(12): 88-94.

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Fabricating titanium dioxide/N-doped carbon nanofibers as advanced interlayer for improving cycling reversibility of lithium-sulfur batteries

Fabricating titanium dioxide/N-doped carbon nanofibers as advanced interlayer for improving cycling reversibility of lithium-sulfur batteries

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