Influence of support properties on selective oxidation of 2-methylnaphthalene on vanadia-molybdena based catalyst

doi:10.1016/j.cjche.2023.06.011

中国化学工程学报 ›› 2023, Vol. 64 ›› Issue (12): 106-116.DOI: 10.1016/j.cjche.2023.06.011

• Full Length Article • 上一篇下一篇

Influence of support properties on selective oxidation of 2-methylnaphthalene on vanadia-molybdena based catalyst

Yi Yu¹, Fanfan Li², Xiaocong Li³, Guoji Liu¹, Li Xu¹, Xingchuan Yang¹

1. School of Chemical Engineering, Zhengzhou University, Zhengzhou 450001, China;
2. School of Chemical and Printing-Dyeing Engineering, Henan University of Engineering, Zhengzhou 450007, China;
3. Kaifeng Wujing Industrial Co. Ltd, Kaifeng 475000, China

收稿日期:2023-03-23 修回日期:2023-06-08 出版日期:2023-12-28 发布日期:2024-02-05
通讯作者: Li Xu,E-mail:xuli@zzu.edu.cn;Xingchuan Yang,E-mail:yangxingchuan@zzu.edu.cn
基金资助:
This work was supported by Henan Province Science and Technology Research Project (232102321041).

Influence of support properties on selective oxidation of 2-methylnaphthalene on vanadia-molybdena based catalyst

Yi Yu¹, Fanfan Li², Xiaocong Li³, Guoji Liu¹, Li Xu¹, Xingchuan Yang¹

1. School of Chemical Engineering, Zhengzhou University, Zhengzhou 450001, China;
2. School of Chemical and Printing-Dyeing Engineering, Henan University of Engineering, Zhengzhou 450007, China;
3. Kaifeng Wujing Industrial Co. Ltd, Kaifeng 475000, China

Received:2023-03-23 Revised:2023-06-08 Online:2023-12-28 Published:2024-02-05
Contact: Li Xu,E-mail:xuli@zzu.edu.cn;Xingchuan Yang,E-mail:yangxingchuan@zzu.edu.cn
Supported by:
This work was supported by Henan Province Science and Technology Research Project (232102321041).

摘要/Abstract

摘要： In this work, the catalytic performance of vanadia-molybdena loaded on TiO₂, MgO, ZSM-5, NaY and Mordenite was investigated in the selective oxidation of 2-methylnaphthalene (2-MN) to 2-naphthaldehyde (2-NA). Results show that strong interactions between supports (TiO₂, ZSM-5) and active components can promote the dispersion of active component. Monolayer VO_x and MoO_x are the main form on the catalyst surface, which is beneficial to the 2-NA selectivity. However, the corresponding weak interactions between Mordenite and active components may lead to the production of oxide crystals and the separation of active components, thus reducing the 2-NA selectivity. Due to the high Na content, new crystal NaVMoO₆ forms on the NaY surface, which is inactive in the reaction. For V-Mo/TiO₂, V and Mo can be inserted into the TiO₂ lattice, changing the electronic structures of active components and support and improving the activity of surface oxygen species. This investigation highlights an important consideration on supports properties when designing supported catalysts.

关键词: 2-Methylnaphthalene, Catalysis, Partial oxidation, Support, Interactions

Abstract: In this work, the catalytic performance of vanadia-molybdena loaded on TiO₂, MgO, ZSM-5, NaY and Mordenite was investigated in the selective oxidation of 2-methylnaphthalene (2-MN) to 2-naphthaldehyde (2-NA). Results show that strong interactions between supports (TiO₂, ZSM-5) and active components can promote the dispersion of active component. Monolayer VO_x and MoO_x are the main form on the catalyst surface, which is beneficial to the 2-NA selectivity. However, the corresponding weak interactions between Mordenite and active components may lead to the production of oxide crystals and the separation of active components, thus reducing the 2-NA selectivity. Due to the high Na content, new crystal NaVMoO₆ forms on the NaY surface, which is inactive in the reaction. For V-Mo/TiO₂, V and Mo can be inserted into the TiO₂ lattice, changing the electronic structures of active components and support and improving the activity of surface oxygen species. This investigation highlights an important consideration on supports properties when designing supported catalysts.

Key words: 2-Methylnaphthalene, Catalysis, Partial oxidation, Support, Interactions

Yi Yu, Fanfan Li, Xiaocong Li, Guoji Liu, Li Xu, Xingchuan Yang. Influence of support properties on selective oxidation of 2-methylnaphthalene on vanadia-molybdena based catalyst[J]. 中国化学工程学报, 2023, 64(12): 106-116.

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Influence of support properties on selective oxidation of 2-methylnaphthalene on vanadia-molybdena based catalyst

Influence of support properties on selective oxidation of 2-methylnaphthalene on vanadia-molybdena based catalyst

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