Amino-functionalized UiO-66-doped mixed matrix membranes with high permeation performance and fouling resistance

doi:10.1016/j.cjche.2023.09.015

中国化学工程学报 ›› 2024, Vol. 67 ›› Issue (3): 68-77.DOI: 10.1016/j.cjche.2023.09.015

Amino-functionalized UiO-66-doped mixed matrix membranes with high permeation performance and fouling resistance

Yi Zhang^1,2,3, Di Liu^2,3,4, Zhaoli Wang^1,2,3, Junjian Yu^2,3,4, Yanyin Cheng^1,2,3, Wenjing Li^1,2,3, Zhe Wang^2,3,4, Hongzhe Ni¹, Yuchao Wang⁴

1 School of Chemical Engineering, Changchun University of Technology, Changchun 130012, China;
2 Advanced Institute of Materials Science, Changchun University of Technology, Changchun 130012, China;
3 Key Laboratory of Advanced Functional Polymer Membrane Materials of Jilin Province, Changchun 130012, China;
4 School of Chemistry and Life Science, Changchun University of Technology, Changchun 130012, China

收稿日期:2023-03-31 修回日期:2023-09-16 出版日期:2024-03-28 发布日期:2024-06-01
通讯作者: Zhe Wang,E-mail address:wzccut@126.com;Hongzhe Ni,E-mail address:nihz@ccut.edu.cn;Yuchao Wang,E-mail address:wangyc057@ccut.edu.cn.
基金资助:
The authors gratefully acknowledge the financial support of this work by Natural Science Foundation of China (22075031, 51673030, 51603017 and 51803011), Jilin Provincial Science & Technology Department (20220201105GX) and Chang Bai Mountain Scholars Program of Jilin Province.

Amino-functionalized UiO-66-doped mixed matrix membranes with high permeation performance and fouling resistance

Yi Zhang^1,2,3, Di Liu^2,3,4, Zhaoli Wang^1,2,3, Junjian Yu^2,3,4, Yanyin Cheng^1,2,3, Wenjing Li^1,2,3, Zhe Wang^2,3,4, Hongzhe Ni¹, Yuchao Wang⁴

1 School of Chemical Engineering, Changchun University of Technology, Changchun 130012, China;
2 Advanced Institute of Materials Science, Changchun University of Technology, Changchun 130012, China;
3 Key Laboratory of Advanced Functional Polymer Membrane Materials of Jilin Province, Changchun 130012, China;
4 School of Chemistry and Life Science, Changchun University of Technology, Changchun 130012, China

Received:2023-03-31 Revised:2023-09-16 Online:2024-03-28 Published:2024-06-01
Contact: Zhe Wang,E-mail address:wzccut@126.com;Hongzhe Ni,E-mail address:nihz@ccut.edu.cn;Yuchao Wang,E-mail address:wangyc057@ccut.edu.cn.
Supported by:
The authors gratefully acknowledge the financial support of this work by Natural Science Foundation of China (22075031, 51673030, 51603017 and 51803011), Jilin Provincial Science & Technology Department (20220201105GX) and Chang Bai Mountain Scholars Program of Jilin Province.

摘要/Abstract

摘要： For the reduction of bovine serum proteins from wastewater, a novel mixed matrix membrane was prepared by functionalizing the substrate material polyaryletherketone (PAEK), followed by carboxyl groups (C-SPAEKS), and then adding amino-functionalized UiO-66-NH₂ (Am-UiO-66-NH₂). Aminofunctionalization of UiO-66 was accomplished by melamine, followed by an amidation reaction to immobilize Am-UiO-66-NH₂, which was immobilized on the surface of the membrane as well as in the pore channels, which enhanced the hydrophilicity of the membrane surface while increasing the negative potential of the membrane surface. This nanoparticle-loaded ultrafiltration membrane has good permeation performance, with a pure water flux of up to 482.3 L·^m-2·^h-1 for C-SPAEKS/AmUiO-66-NH₂ and a retention rate of up to 98.7% for bovine serum albumin (BSA)-contaminated solutions. Meanwhile, after several hydrophilic modifications, the flux recovery of BSA contaminants by this series of membranes increased from 56.2% to 80.55% of pure membranes. The results of ultrafiltration flux time tests performed at room temperature showed that the series of ultrafiltration membranes remained relatively stable over a test time of 300 min. Thus, the newly developed mixed matrix membrane showed potential for high efficiency and stability in wastewater treatment containing bovine serum proteins.

关键词: Ultrafiltration, Mixed matrix membranes, Amino functionalization, Hydrophilic modification, Negatively charged

Abstract: For the reduction of bovine serum proteins from wastewater, a novel mixed matrix membrane was prepared by functionalizing the substrate material polyaryletherketone (PAEK), followed by carboxyl groups (C-SPAEKS), and then adding amino-functionalized UiO-66-NH₂ (Am-UiO-66-NH₂). Aminofunctionalization of UiO-66 was accomplished by melamine, followed by an amidation reaction to immobilize Am-UiO-66-NH₂, which was immobilized on the surface of the membrane as well as in the pore channels, which enhanced the hydrophilicity of the membrane surface while increasing the negative potential of the membrane surface. This nanoparticle-loaded ultrafiltration membrane has good permeation performance, with a pure water flux of up to 482.3 L·^m-2·^h-1 for C-SPAEKS/AmUiO-66-NH₂ and a retention rate of up to 98.7% for bovine serum albumin (BSA)-contaminated solutions. Meanwhile, after several hydrophilic modifications, the flux recovery of BSA contaminants by this series of membranes increased from 56.2% to 80.55% of pure membranes. The results of ultrafiltration flux time tests performed at room temperature showed that the series of ultrafiltration membranes remained relatively stable over a test time of 300 min. Thus, the newly developed mixed matrix membrane showed potential for high efficiency and stability in wastewater treatment containing bovine serum proteins.

Key words: Ultrafiltration, Mixed matrix membranes, Amino functionalization, Hydrophilic modification, Negatively charged

Yi Zhang, Di Liu, Zhaoli Wang, Junjian Yu, Yanyin Cheng, Wenjing Li, Zhe Wang, Hongzhe Ni, Yuchao Wang. Amino-functionalized UiO-66-doped mixed matrix membranes with high permeation performance and fouling resistance[J]. 中国化学工程学报, 2024, 67(3): 68-77.

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Amino-functionalized UiO-66-doped mixed matrix membranes with high permeation performance and fouling resistance

Amino-functionalized UiO-66-doped mixed matrix membranes with high permeation performance and fouling resistance

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