Boron Nitride Nanowires Produced on Commercial Stainless Steel foil

›› 2008, Vol. 16 ›› Issue (3): 485-487.

Boron Nitride Nanowires Produced on Commercial Stainless Steel foil

陈拥军, 童张法, 骆丽杰

School of Chemistry and Chemical Engineering, Guangxi University, Nanning 530004, China

收稿日期:2007-09-24 修回日期:2008-01-14 出版日期:2008-06-28 发布日期:2008-06-28
通讯作者: CHEN Yongjun,E-mail:yongchen@gxu.edu.cn

Boron Nitride Nanowires Produced on Commercial Stainless Steel foil

CHEN Yongjun, TONG Zhangfa, LUO Lijie

School of Chemistry and Chemical Engineering, Guangxi University, Nanning 530004, China

Received:2007-09-24 Revised:2008-01-14 Online:2008-06-28 Published:2008-06-28

摘要/Abstract

摘要： Chemical vapor deposition growth of one-dimensional nanomaterials usually demands substrates that have been coated with a layer of catalyst film. In this study, a green process to synthesize boron nitride (BN) nanowires directly on commercial stainless steel foils was proposed by heating boron and zinc oxide powders under a mixture gas flow of N₂ and 15% H₂ at 1100℃, and a large quantities of pure h-BN nanowires have been produced directly on commercial stainless steel foil. The stainless steel foils not only acted as the substrate but also the catalyst for the nanowire growth. The synthesized BN nanowires were characterized by X-ray diffraction, scanning and transmission electron microscopes, X-ray energy dispersive spectrometer and photoluminescence spectroscopy. The nanowires also possess strong PL emission bands at 515, 535, and 728 nm.

关键词: boron nitride nanowires, chemical vapor deposition, stainless steel foil

Abstract: Chemical vapor deposition growth of one-dimensional nanomaterials usually demands substrates that have been coated with a layer of catalyst film. In this study, a green process to synthesize boron nitride (BN) nanowires directly on commercial stainless steel foils was proposed by heating boron and zinc oxide powders under a mixture gas flow of N₂ and 15% H₂ at 1100℃, and a large quantities of pure h-BN nanowires have been produced directly on commercial stainless steel foil. The stainless steel foils not only acted as the substrate but also the catalyst for the nanowire growth. The synthesized BN nanowires were characterized by X-ray diffraction, scanning and transmission electron microscopes, X-ray energy dispersive spectrometer and photoluminescence spectroscopy. The nanowires also possess strong PL emission bands at 515, 535, and 728 nm.

Key words: boron nitride nanowires, chemical vapor deposition, stainless steel foil

陈拥军, 童张法, 骆丽杰. Boron Nitride Nanowires Produced on Commercial Stainless Steel foil[J]. , 2008, 16(3): 485-487.

CHEN Yongjun, TONG Zhangfa, LUO Lijie. Boron Nitride Nanowires Produced on Commercial Stainless Steel foil[J]. , 2008, 16(3): 485-487.

参考文献

1 Cui, Y., Wei, Q.Q., Park, H.K., Lieber, C.M., “Nanowire nanosensors for highly sensitive and selective detection of biological and chemical species”, Science, 293, 1289-1292(2001).
2 Favier, F., Walter, E.C., Zach, M.P., Benter, T., Penner, R.M., “Hydrogen sensors and switches from electrodeposited palladium mesowire Arrays”, Science, 293, 2227-2231(2001).
3 Paine, R.T., Narula, C.K., “Synthetic routes to boron nitride”, Chem. Rev., 90, 73-91(1990).
4 Chopra, N.G., Luyken, R.J., Cherrey, K., Crespi, V.H., Cohen, M.L., Louie, S.G., Zettl, A., “Boron nitride nanotubes”, Science, 269, 966-967(1995).
5 Lourie, O.R., Jones, C.R., Bartlett, B.M., Gibbons, P.C., Ruoff, R.S., Buhro, W.E., “CVD growth of boron nitride nanotubes”, Chem. Mater., 12, 1808-1810(2000).
6 Fan, L.T., Song, J.C., Yutani, N., “Long ropes of boron nitride nanotubes grown by a continuous laser heating”, Appl. Phys. Lett., 76, 3239-3241(2000).
7 Han, W.Q., Bando, Y., Kurashima, K., Sato, Y., “Synthesis of boron nitride nanotubes from carbon nanotubes by a substitution reaction”, Appl. Phys. Lett., 73, 3085-3089(1998).
8 Velazquez-Salazar, J.J., Munoz-Sandoval, E., Romo-Herrera, J.M., Lupo, F., Ruhle, M., Terrones, H., Terrones, M., “Synthesis and state of art characterization of BN bamboo-like nanotubes:Evidence of a root growth mechanism catalyzed by Fe”, Chem. Phys. Lett., 416, 342-348(2005).
9 Huo, K.F, Hu, Z., Chen, F., Fu, J.J., Chen, Y., Liu, B.H., Ding, J., Dong, Z.L., White, T., “Synthesis of boron nitride nanowires”, Appl. Phys. Lett., 80, 3611-3613(2002).
10 Deepak, F.L., Vinod, C.P., Mukhopadhyay, K., Govindaraj, A., Rao, C.N.R., “Boron nitride nanotubes and nanowires”, Chem. Phys. Lett., 353, 345-352(2002).
11 Sekiguchi, T., Liu, Q., Tanaka, T., Hu, J., Zhu, Y., Bando, Y., “Cathodoluminescence study of widegap-semiconductor. Nanowires”, Eur. J. Appl. Phys., 27, 107-109(2004).
12 Chen, Y.J., Zhang, H.Z., Chen, Y., “Pure boron nitride nanowires produced from boron triiodide”, Nanotech., 17, 786-789(2006).
13 Chen, Y.J., Chi, B., Mahon, D.C., Chen, Y., “An effective approach to grow boron nitride nanowires directly on stainless-steel substrates”, Nanotech., 17, 2942-2946(2006).
14 Solozhenko, V.L., Lazarenko, A.G., Petitet, J.P., Kanaev, A.V., “Bandgap energy of graphite-like hexagonal boron nitride”, J. Phys. Chem. Solid., 62, 1331-1334(2001).
15 Yao, B., Liu, L., Su, W.H., Shen, Z.X., Liu, L., Sun, W.X., Ding, J., “Effects of degree of three-dimensional order and Fe impurities on photoluminescence of boron nitride”, J. Appl. Phys., 96, 1947-1952(2004).
16 Li, X.T., Shao, C.L., Qiu, S.L., Xiao, F.S., Zheng, W.T., Terasaki, Q., “BN and Si nanostructures:Preparation and visible photoluminescence properties”, Mater. Lett., 44, 341-346(2000).
17 Brus, L.E., “The origin of the extensive interest is that the absorption spectrum of the clusters is a strong function of their radii”, J. Phys. Chem., 80, 4403-4409(1984).
18 Wirth, K.E., “Nanometer size semiconductor clusters:Materials synthesis, quantum size effect and photophysica properties”, J. Phys. Chem., 95, 525-532(1991).
19 Zhu, Y.C., Bando, Y., Xue, D.F., Sekiguchi, T., Golberg, D., Xu, F.F., Liu, Q.L., “New boron nitride whiskers:Showing strong ultraviolet and visible light luminescence”, J. Phys. Chem. B, 108, 6193-6196(2004).

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Boron Nitride Nanowires Produced on Commercial Stainless Steel foil

Boron Nitride Nanowires Produced on Commercial Stainless Steel foil

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