Adsorptive Recovery of Uranium from Nuclear Fuel Industrial Wastewater by Titanium Loaded Collagen Fiber

›› 2011, Vol. 19 ›› Issue (4): 592-597.

Adsorptive Recovery of Uranium from Nuclear Fuel Industrial Wastewater by Titanium Loaded Collagen Fiber

程远梅^1,2, 孙霞², 廖学品^1,2, 石碧²

1. School of Chemical Engineering, Sichuan University, Chengdu 610065, China;
2. National Engineering Laboratory for Clean Technology of Leather Manufacture, Sichuan University, Chengdu 610065, China

收稿日期:2010-11-15 修回日期:2011-03-22 出版日期:2011-08-28 发布日期:2011-08-28
通讯作者: LIAO Xuepin,E-mail:xpliao@scu.edu.cn;SHI Bi,shibi@scu.edu.cn
基金资助:
Supported by the National Natural Science Foundation of China(20976111)and Sichuan Province Technologies R&D Program (2008GZ0026).

Adsorptive Recovery of Uranium from Nuclear Fuel Industrial Wastewater by Titanium Loaded Collagen Fiber

CHENG YuanMei^1,2, SUN Xia², LIAO Xuepin^1,2, SHI Bi²

1. School of Chemical Engineering, Sichuan University, Chengdu 610065, China;
2. National Engineering Laboratory for Clean Technology of Leather Manufacture, Sichuan University, Chengdu 610065, China

Received:2010-11-15 Revised:2011-03-22 Online:2011-08-28 Published:2011-08-28
Supported by:
Supported by the National Natural Science Foundation of China(20976111)and Sichuan Province Technologies R&D Program (2008GZ0026).

摘要/Abstract

摘要： Effective recovery of UO₂²⁺ from wastewater is essential for nuclear fuel industry and related industries.In this study, a novel adsorbent was prepared by loading titanium(Ti⁴⁺) onto collagen fiber(TICF), and its physical and chemical properties as well as adsorption to UO₂²⁺ in nuclear fuel industrial wastewater were investigated.It is found that TICF can effectively recover UO₂²⁺ from the wastewater with excellent adsorption capacity.The adsorption capacity is 0.62 mmol·g^-1 at 303 K and pH 5.0 when the initial concentration of UO₂²⁺ is 1.50 mmol·L^-1.The adsorption isotherms can be described by the Langmuir equation and the adsorption capacity increases with temperature.The effect of co-existed F on the adsorption capacity for UO₂²⁺ is significant, which can be eliminated by adding aluminum ions as complexing agent, while the other co-existed ions in the solutions, including HCO₃^-, Cl^-, NO₃^-, Ca²⁺, Mg²⁺ and Cu²⁺, have little effect on the adsorption capacity for UO₂²⁺.The saturated TICF after UO₂²⁺ adsorption can be regenerated by using 0.2 mol·L^-1 nitrate(₃) as desorption agent, and the TICF can be reused at least three times.Thus the TICF is a new and effective adsorbent for the recovery of UO₂²⁺ from the wastewater.

关键词: collagen fiber, titanium(Ⅳ), adsorption, wastewater

Abstract: Effective recovery of UO₂²⁺ from wastewater is essential for nuclear fuel industry and related industries.In this study, a novel adsorbent was prepared by loading titanium(Ti⁴⁺) onto collagen fiber(TICF), and its physical and chemical properties as well as adsorption to UO₂²⁺ in nuclear fuel industrial wastewater were investigated.It is found that TICF can effectively recover UO₂²⁺ from the wastewater with excellent adsorption capacity.The adsorption capacity is 0.62 mmol·g^-1 at 303 K and pH 5.0 when the initial concentration of UO₂²⁺ is 1.50 mmol·L^-1.The adsorption isotherms can be described by the Langmuir equation and the adsorption capacity increases with temperature.The effect of co-existed F on the adsorption capacity for UO₂²⁺ is significant, which can be eliminated by adding aluminum ions as complexing agent, while the other co-existed ions in the solutions, including HCO₃^-, Cl^-, NO₃^-, Ca²⁺, Mg²⁺ and Cu²⁺, have little effect on the adsorption capacity for UO₂²⁺.The saturated TICF after UO₂²⁺ adsorption can be regenerated by using 0.2 mol·L^-1 nitrate(₃) as desorption agent, and the TICF can be reused at least three times.Thus the TICF is a new and effective adsorbent for the recovery of UO₂²⁺ from the wastewater.

Key words: collagen fiber, titanium(Ⅳ), adsorption, wastewater

程远梅, 孙霞, 廖学品, 石碧. Adsorptive Recovery of Uranium from Nuclear Fuel Industrial Wastewater by Titanium Loaded Collagen Fiber [J]. , 2011, 19(4): 592-597.

CHENG YuanMei, SUN Xia, LIAO Xuepin, SHI Bi. Adsorptive Recovery of Uranium from Nuclear Fuel Industrial Wastewater by Titanium Loaded Collagen Fiber [J]. , 2011, 19(4): 592-597.

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Adsorptive Recovery of Uranium from Nuclear Fuel Industrial Wastewater by Titanium Loaded Collagen Fiber

Adsorptive Recovery of Uranium from Nuclear Fuel Industrial Wastewater by Titanium Loaded Collagen Fiber

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