Removal of Nitrophenols by Adsorption Using β-Cyclodextrin Modified Zeolites

›› 2011, Vol. 19 ›› Issue (6): 938-943.

Removal of Nitrophenols by Adsorption Using β-Cyclodextrin Modified Zeolites

李效红^1,2, 赵保卫¹, 朱琨¹, 郝学奎²

1. School of Environmental and Municipal Engineering, Lanzhou Jiaotong University, Lanzhou 730070, China;
2. The Civil Engineering Department of Lanzhou Polytechnic College, Lanzhou 730050, China

收稿日期:2010-12-13 修回日期:2011-07-05 出版日期:2011-12-28 发布日期:2012-04-24
通讯作者: ZHU Kun, E-mail: kun@mail.lzjtu.cn
基金资助:
Supported by the National Natural Science Foundation of China (NEPCP 200809098);the Natural Science Foundation of Gansu Province (0803RJZA003)

Removal of Nitrophenols by Adsorption Using β-Cyclodextrin Modified Zeolites

LI Xiaohong^1,2, ZHAO Baowei¹, ZHU Kun¹, HAO Xuekui²

1. School of Environmental and Municipal Engineering, Lanzhou Jiaotong University, Lanzhou 730070, China;
2. The Civil Engineering Department of Lanzhou Polytechnic College, Lanzhou 730050, China

Received:2010-12-13 Revised:2011-07-05 Online:2011-12-28 Published:2012-04-24
Supported by:
Supported by the National Natural Science Foundation of China (NEPCP 200809098);the Natural Science Foundation of Gansu Province (0803RJZA003)

摘要/Abstract

摘要： Removal of nitrophenols (NPs) from aqueous solutions through the adsorption process by using cationic β-cyclodextrin (CCD) modified zeolite (CCDMZ) was investigated. The effects of particle size, contact time, solution pH values and sodium chloride content in the aqueous on adsorption capacity were evaluated through a series of batch experiments. The results showed that CCDMZ had a higher adsorption capacity for removing NPs at a size fraction of 0.45-0.9 mm while adsorption of NPs on CCDMZ reached equilibrium within 60 min. The adsorption process was apparently influenced by pH values and sodium chloride content in aqueous solution. To ascertain the mechanisms of sorption, the experimental data were modeled by using the pseudo-first and pseudo-second order kinetic equations, and the results indicated that the adsorption kinetics of NPs on CCDMZ well-matched with the pseudo-second order rate expression.

关键词: adsorption, zeolite, modification, nitrophenols, adsorption kinetics

Abstract: Removal of nitrophenols (NPs) from aqueous solutions through the adsorption process by using cationic β-cyclodextrin (CCD) modified zeolite (CCDMZ) was investigated. The effects of particle size, contact time, solution pH values and sodium chloride content in the aqueous on adsorption capacity were evaluated through a series of batch experiments. The results showed that CCDMZ had a higher adsorption capacity for removing NPs at a size fraction of 0.45-0.9 mm while adsorption of NPs on CCDMZ reached equilibrium within 60 min. The adsorption process was apparently influenced by pH values and sodium chloride content in aqueous solution. To ascertain the mechanisms of sorption, the experimental data were modeled by using the pseudo-first and pseudo-second order kinetic equations, and the results indicated that the adsorption kinetics of NPs on CCDMZ well-matched with the pseudo-second order rate expression.

Key words: adsorption, zeolite, modification, nitrophenols, adsorption kinetics

李效红, 赵保卫, 朱琨, 郝学奎. Removal of Nitrophenols by Adsorption Using β-Cyclodextrin Modified Zeolites[J]. , 2011, 19(6): 938-943.

LI Xiaohong, ZHAO Baowei, ZHU Kun, HAO Xuekui. Removal of Nitrophenols by Adsorption Using β-Cyclodextrin Modified Zeolites[J]. , 2011, 19(6): 938-943.

参考文献

1 Chen, R.Z., Du, Y., Xing, W.H., Xu, N.P., “Effect of alumina particle size on Ni/Al₂O₃ catalysts for p-nitrophenol hydrogenation”, Chin. J. Chem. Eng., 15(6), 884-888(2007).
2 álvarez, P.M., García-Araya, J.F., Beltrán, F.J., Masaa, F.J., Medina, F., “Ozonation of activated carbons: Effect on the adsorption of selected phenolic compounds from aqueous solutions”, J. Colloid Interf. Sci., 283, 503-512(2005).
3 Milner, C.R., Goulder, R., “The abundance, heterotrophic activity and taxonomy of bacteria in a stream subject to pollution by chlorophenols, nitrophenols and phenoxyalkanoic acids”, Water Res., 20, 85-90(1986).
4 Egerton, T.A., Christensen, P.A., Harrison, R.W., Wang, J.W., “The effect of UV absorption on the photocatalytic oxidation of 2-nitrophenol and 4-nitrophenol”, J. App. Electrochem., 35, 799-813(2005).
5 Priya, M.H., Madras, G., “Kinetics of photocatalytic degradation of phenols with multiple substituent groups”, J. Photochem. Photobiol. A, 179, 256-262(2006).
6 Sivakumar, M., Prashant, A., Tatake, B., Aniruddha, P., “Kinetics of p-nitrophenol degradation: effect of reaction conditions and cavitational parameters for a multiple frequency system”, Chem. Eng. J., 85(2/3), 327-338(2002).
7 Baeza, A., Ortiz, J., González, I., “Control of the electrochemical reduction of o-nitrophenol by pH imposition in acetonitrile”, J. Electroanal. Chem., 429, 121-127(1997).
8 Liu, H.L., Liu, Y., Zhang, C., Shen, R.S., “Electrocatalytic oxidation of nitrophenols in aqueous solution using modified PbO₂ electrodes”, J. Appl. Electrochem., 38, 101-108(2008).
9 Razee, S., Masujima, T., “Uptake monitoring of anilines and phenols using modified zeolites”, Anal. Chim. Acta, 464(1), 1-5(2002).
10 Martin Del Valle, E.M., “Cyclodextrins and their uses: a review”, Process Biochem., 39(9), 1033-1046(2004).
11 Crini, G., “Kinetic and equilibrium studies on the removal of cationic dyes from aqueous solution by adsorption onto a cyclodextrin polymer”, Dyes and Pigments, 77, 415-426(2008).
12 Abay, I., Denizli, A., Biskin, E., Salih, B., “Removal and pre-concentration of phenolic species onto β-cyclodextrin modified poly(hydroxyethylmethacrylate-ethyleneglycoldimethacrylate) microbeads”, Chemosphere, 61, 1263-1272(2005).
13 Li, X.H., Zhu, K., Hao, X.K., “Surface modification of zeolite with beta-cyclodextrin for removal of p-nitrophenol from aqueous solution”, Water Sci. Technol., 60(2), 329-337(2009).
14 Bachar, K., Guy, J., Patrick, M., “Adsorption and competitive adsorption on zeolites of nitrophenol compounds present in wastewater”, Ind. Eng. Chem. Res., 47, 9558-9565(2008).
15 Sismanoglu, T., Pura, S., “Adsorption of aqueous nitrophenols on clinoptilolite”, Colloids Surf. A, 180, 1-6(2001).
16 Crini, G., Lekchiri, Y., Morcellet, M., “Separation of structural isomers using cyclodextrin-polymer coated on silica beads”, Chromatographia, 40, 296-302(1995).
17 Nouri, S., “Adsorption of p-nitriphenol in three different activated carbons at different pH”, J. Sci. Islamic Republic of Iran, 13(3), 241-247(2002).
18 Tang, D.Y., Zheng, Z., Lin, K., Luan, J.F., Zhang, J.B., “Adsorption of p-nitrophenol from aqueous solutions onto activated carbon fiber”, J. Hazard. Mater., 143, 49-56(2007).
19 Abel, E.N., Norma, A.C., Rosario, F.P., Bertha, P.L., “Adsorptive removal of 2-nitrophenol and 2-chlorophenol by cross-linked algae from aqueous solutions”, Sep. Sci. Technol., 43, 3183-3199(2008).
20 Turner, A., Rawling, M.C., “Influence of salting out on the sorption of neutral organic compounds in estuaries”, Water Res., 35, 4379-4389(2001).
21 Crini, G., Peindy, H.N., Gimbert, F., Robert, C., “Removal of C.I. basic green 4(malachite green) from aqueous solutions by adsorption using cyclodetrin-based adsorbent: kinetic and equilibrium studies”, Sep. Purif. Technol., 53, 97-110(2007).
22 Gucek, A., Sener, S., Bilgen, S., Mazmanci, M.A., “Adsorption and kinetic studies of cationic and anionic dyes on pyrophllite from aqueous solutions”, J. Colloid and Interf. Sci., 286, 53-60(2005).
23 Duchene, D., Cyclodextrins and Their Industrial Uses, Edition de la Sante, Paris, France(1987).
24 Casu, B., “Structure and inclusion properties of cyclodextrins”, Chimicaoggi, 15, 23-25(1987).

[1]	Baoyu Liu, Feng Xiong, Jianwen Zhang, Manna Wang, Yi Huang, Yanxiong Fang, Jinxiang Dong. Enhanced ortho-selective t–butylation of phenol over sulfonic acid functionalized mesopore MTW zeolites[J]. 中国化学工程学报, 2023, 60(8): 1-7.
[2]	Yingli Li, Zhishuncheng Li, Guangfei Qu, Rui Li, Shuaiyu Liang, Junhong Zhou, Wei Ji, Huiming Tang. Mechanism, behaviour and application of iron nitrate modified carbon nanotube composites for the adsorption of arsenic in aqueous solutions[J]. 中国化学工程学报, 2023, 60(8): 26-36.
[3]	Jing Huang, Honghui Cai, Qian Zhao, Yunpeng Zhou, Haibo Liu, Jing Wang. Dual-functional pyrene implemented mesoporous silicon material used for the detection and adsorption of metal ions[J]. 中国化学工程学报, 2023, 60(8): 108-117.
[4]	Wenwen Zhang, Zhigang Xue, Liyun Cui, Haoliang Gao, Di Zhao, Rongfei Zhou, Weihong Xing. Synthesis of an IMF zeolite membrane for the separation of xylene isomer[J]. 中国化学工程学报, 2023, 60(8): 205-211.
[5]	Lingli Chen, Yueting Shi, Sijun Xu, Junle Xiong, Fang Gao, Shengtao Zhang, Hongru Li. Enhanced adsorption of target branched compounds including antibiotic norfloxacin frameworks on mild steel surface for efficient protection: An experimental and molecular modelling study[J]. 中国化学工程学报, 2023, 60(8): 212-227.
[6]	Hammad Saulat, Jianhua Yang, Tao Yan, Waseem Raza, Wensen Song, Gaohong He. Tungsten incorporated mobil-type eleven zeolite membranes: Facile synthesis and tuneable wettability for highly efficient separation of oil/water mixtures[J]. 中国化学工程学报, 2023, 60(8): 242-252.
[7]	Alexander Nti Kani, Evans Dovi, Aaron Albert Aryee, Runping Han, Zhaohui Li, Lingbo Qu. Mechanisms and reusability potentials of zirconium-polyaziridine-engineered tiger nut residue towards anionic pollutants[J]. 中国化学工程学报, 2023, 60(8): 275-292.
[8]	Yuan Liu, Hanting Xiong, Jingwen Chen, Shixia Chen, Zhenyu Zhou, Zheling Zeng, Shuguang Deng, Jun Wang. One-step ethylene separation from ternary C₂ hydrocarbon mixture with a robust zirconium metal-organic framework[J]. 中国化学工程学报, 2023, 59(7): 9-15.
[9]	Hui Jiang, Zijian Zhao, Ning Yu, Yi Qin, Zhengwei Luo, Wenhua Geng, Jianliang Zhu. Synthesis, characterization, and performance comparison of boron using adsorbents based on N-methyl-D-glucosamine[J]. 中国化学工程学报, 2023, 59(7): 16-31.
[10]	Meihua Zhu, Xingguo An, Tian Gui, Ting Wu, Yuqin Li, Xiangshu Chen. Effects of ion-exchange on the pervaporation performance and microstructure of NaY zeolite membrane[J]. 中国化学工程学报, 2023, 59(7): 176-181.
[11]	Tingjun Fu, Ran Wang, Kun Ren, Liangliang Zhang, Zhong Li. Intensified shape selectivity and alkylation reaction for the two-step conversion of methanol aromatization to p-xylene[J]. 中国化学工程学报, 2023, 59(7): 240-250.
[12]	Runze Chen, Yuran Chen, Xuemin Liang, Yapeng Kong, Yangyang Fan, Quan Liu, Zhenyu Yang, Feiying Tang, Johnny Muya Chabu, Maru Dessie Walle, Liqiang Wang. Oxidative exfoliation of spent cathode carbon: A two-in-one strategy for its decontamination and high-valued application[J]. 中国化学工程学报, 2023, 59(7): 262-269.
[13]	Shanghong Ma, Haitao Zhang, Jianbo Qu, Xiuzhong Zhu, Qingfei Hu, Jianyong Wang, Peng Ye, Futao Sai, Shiwei Chen. Preparation of waterborne polyurethane/β-cyclodextrin composite nanosponge by ion condensation method and its application in removing of dyes from wastewater[J]. 中国化学工程学报, 2023, 58(6): 124-136.
[14]	Bin Gao, Junwen Chen, Qi Zuo, Hongyan Wang, Wenlin Li. The critical role of Zr in controlling the activity of Pd/Beta on the hydrogenation of phenol to cyclohexanone[J]. 中国化学工程学报, 2023, 57(5): 79-87.
[15]	Yueting Shi, Junhai Zhao, Lingli Chen, Hongru Li, Shengtao Zhang, Fang Gao. Double open mouse-like terpyridine parts based amphiphilic ionic molecules displaying strengthened chemical adsorption for anticorrosion of copper in sulfuric acid solution[J]. 中国化学工程学报, 2023, 57(5): 233-246.

Removal of Nitrophenols by Adsorption Using β-Cyclodextrin Modified Zeolites

Removal of Nitrophenols by Adsorption Using β-Cyclodextrin Modified Zeolites

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价