Preparation and characterization of monodisperse zirconia spherical nanometer powder via lamellar liquid crystal template method

doi:10.1016/j.cjche.2015.08.032

›› 2015, Vol. 23 ›› Issue (10): 1721-1727.DOI: 10.1016/j.cjche.2015.08.032

Preparation and characterization of monodisperse zirconia spherical nanometer powder via lamellar liquid crystal template method

Weiyan He, Jinrong Liu, Zhenzhu Cao, Caihong Li, Yanfang Gao

School of Chemical Engineering, Inner Mongolia University of Technology, Hohhot 010051, China

收稿日期:2014-11-10 修回日期:2015-02-04 出版日期:2015-10-28 发布日期:2015-11-27
通讯作者: Jinrong Liu

Preparation and characterization of monodisperse zirconia spherical nanometer powder via lamellar liquid crystal template method

Weiyan He, Jinrong Liu, Zhenzhu Cao, Caihong Li, Yanfang Gao

School of Chemical Engineering, Inner Mongolia University of Technology, Hohhot 010051, China

Received:2014-11-10 Revised:2015-02-04 Online:2015-10-28 Published:2015-11-27

摘要/Abstract

摘要： Cubic phase spherical zirconia nano-powderwas prepared by a direct template route in the lamellar liquid crystal formed by polyoxyethylene tert-octylphenyl ether (Triton X-100)/sodium dodecyl sulfate (SDS)/H₂O. The precursor powder and zirconia powder were characterized by XRD, FT-IR, TG/DSC, TEM, and SEM methods. Results show that the stability of the lamellar liquid crystal is controlled by NH₃ · H₂O concentration. The size of nanoparticles is greatly affected by NH₃·H₂Oand ZrOCl₂ · 8H₂O concentrations. The zirconia nanoparticles shownarrow particle size distribution of 10-30 nm.

关键词: Zirconia, Spherical nanometer powder, Lamellar liquid crystal template

Abstract: Cubic phase spherical zirconia nano-powderwas prepared by a direct template route in the lamellar liquid crystal formed by polyoxyethylene tert-octylphenyl ether (Triton X-100)/sodium dodecyl sulfate (SDS)/H₂O. The precursor powder and zirconia powder were characterized by XRD, FT-IR, TG/DSC, TEM, and SEM methods. Results show that the stability of the lamellar liquid crystal is controlled by NH₃ · H₂O concentration. The size of nanoparticles is greatly affected by NH₃·H₂Oand ZrOCl₂ · 8H₂O concentrations. The zirconia nanoparticles shownarrow particle size distribution of 10-30 nm.

Key words: Zirconia, Spherical nanometer powder, Lamellar liquid crystal template

Weiyan He, Jinrong Liu, Zhenzhu Cao, Caihong Li, Yanfang Gao. Preparation and characterization of monodisperse zirconia spherical nanometer powder via lamellar liquid crystal template method[J]. , 2015, 23(10): 1721-1727.

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Preparation and characterization of monodisperse zirconia spherical nanometer powder via lamellar liquid crystal template method

Preparation and characterization of monodisperse zirconia spherical nanometer powder via lamellar liquid crystal template method

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