Facile synthesis of porous Pd nanoflowerswith excellent catalytic activity towards CO oxidation

doi:10.1016/j.cjche.2015.08.009

Chinese Journal of Chemical Engineering ›› 2015, Vol. 23 ›› Issue (11): 1907-1915.DOI: 10.1016/j.cjche.2015.08.009

Facile synthesis of porous Pd nanoflowerswith excellent catalytic activity towards CO oxidation

Tareque Odoom-Wubah¹, Mingming Du¹, Williams Brown Osei¹, Daohua Sun¹, Jiale Huang¹, Qingbiao Li^1,2,3

1 Department of Chemical and Biochemical Engineering, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China;
2 Environmental Science Research Center, College of the Environment & Ecology, Xiamen University, Xiamen 361005, China;
3 College of Chemistry & Life Science, Quanzhou Normal University, Quanzhou 362000, China

收稿日期:2015-06-01 修回日期:2015-08-05 出版日期:2015-11-28 发布日期:2015-12-18
通讯作者: Jiale Huang, Qingbiao Li
基金资助:
Supported by the National Natural Science Foundation of China (21106117, 21036004).

Facile synthesis of porous Pd nanoflowerswith excellent catalytic activity towards CO oxidation

Tareque Odoom-Wubah¹, Mingming Du¹, Williams Brown Osei¹, Daohua Sun¹, Jiale Huang¹, Qingbiao Li^1,2,3

1 Department of Chemical and Biochemical Engineering, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China;
2 Environmental Science Research Center, College of the Environment & Ecology, Xiamen University, Xiamen 361005, China;
3 College of Chemistry & Life Science, Quanzhou Normal University, Quanzhou 362000, China

Received:2015-06-01 Revised:2015-08-05 Online:2015-11-28 Published:2015-12-18
Contact: Jiale Huang, Qingbiao Li
Supported by:
Supported by the National Natural Science Foundation of China (21106117, 21036004).

摘要/Abstract

摘要： Microorganism-mediated, hexadecyltrimethylammonium chloride (CTAC)-directed (MCD) method was employed in this work to synthesize Pd nanoflowers (PdNFs). Proper Pichia pastoris cells (PPCs) dosage, ascorbic acid (AA), Pd(NO₃)₂ and CTAC concentrations were essential for the growth of the PdNFs. The size of the assynthesized PdNFs could be tuned by adjusting the amount of Pd(NO₃)₂ solution and dosage of PPCs used. Characterization techniques such as X-ray diffraction, transmission electron microscopy, and X-ray photoelectron spectroscopy were used to verify the nature of the PdNFs. Finally the PdNF/PPC nanocomposites were immobilized onto TiO₂ supports to obtain bio-PdNF/TiO₂ catalysts which showed excellent catalytic activity for CO oxidation, obtaining 100% conversion at 100 ℃ and remaining stable over a period of 52 h of reaction time.

关键词: Pd nanoflowers, Microorganism, CO oxidation, CTAC

Abstract: Microorganism-mediated, hexadecyltrimethylammonium chloride (CTAC)-directed (MCD) method was employed in this work to synthesize Pd nanoflowers (PdNFs). Proper Pichia pastoris cells (PPCs) dosage, ascorbic acid (AA), Pd(NO₃)₂ and CTAC concentrations were essential for the growth of the PdNFs. The size of the assynthesized PdNFs could be tuned by adjusting the amount of Pd(NO₃)₂ solution and dosage of PPCs used. Characterization techniques such as X-ray diffraction, transmission electron microscopy, and X-ray photoelectron spectroscopy were used to verify the nature of the PdNFs. Finally the PdNF/PPC nanocomposites were immobilized onto TiO₂ supports to obtain bio-PdNF/TiO₂ catalysts which showed excellent catalytic activity for CO oxidation, obtaining 100% conversion at 100 ℃ and remaining stable over a period of 52 h of reaction time.

Key words: Pd nanoflowers, Microorganism, CO oxidation, CTAC

Tareque Odoom-Wubah, Mingming Du, Williams Brown Osei, Daohua Sun, Jiale Huang, Qingbiao Li. Facile synthesis of porous Pd nanoflowerswith excellent catalytic activity towards CO oxidation[J]. Chinese Journal of Chemical Engineering, 2015, 23(11): 1907-1915.

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Facile synthesis of porous Pd nanoflowerswith excellent catalytic activity towards CO oxidation

Facile synthesis of porous Pd nanoflowerswith excellent catalytic activity towards CO oxidation

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