Graphene oxide membranes supported on the ceramic hollow fibre for efficient H2 recovery

doi:10.1016/j.cjche.2016.11.010

›› 2017, Vol. 25 ›› Issue (6): 752-759.DOI: 10.1016/j.cjche.2016.11.010

• Separation Science and Engineering • 上一篇下一篇

Graphene oxide membranes supported on the ceramic hollow fibre for efficient H₂ recovery

Kang Huang, Jianwei Yuan, Guoshun Shen, Gongping Liu, Wanqin Jin

State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemical Engineering, Jiangsu National Synergetic Innovation Center for Advanced Materials, Nanjing Tech University, Nanjing 210009, China

收稿日期:2016-07-15 修回日期:2016-11-22 出版日期:2017-06-28 发布日期:2017-08-02
通讯作者: Wanqin Jin,E-mail address:wqjin@njtech.edu.cn
基金资助:
Supported by the National Natural Science Foundation of China (21476107, 21490585, 21406107), the Innovative Research Team Program by the Ministry of Education of China (IRT13070) and the Topnotch Academic Programs Project of Jiangsu Higher Education Institutions (TAPP).

Graphene oxide membranes supported on the ceramic hollow fibre for efficient H₂ recovery

Kang Huang, Jianwei Yuan, Guoshun Shen, Gongping Liu, Wanqin Jin

State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemical Engineering, Jiangsu National Synergetic Innovation Center for Advanced Materials, Nanjing Tech University, Nanjing 210009, China

Received:2016-07-15 Revised:2016-11-22 Online:2017-06-28 Published:2017-08-02
Supported by:
Supported by the National Natural Science Foundation of China (21476107, 21490585, 21406107), the Innovative Research Team Program by the Ministry of Education of China (IRT13070) and the Topnotch Academic Programs Project of Jiangsu Higher Education Institutions (TAPP).

摘要/Abstract

摘要： The special channels and intrinsic defects within GO laminates make it a very potential candidate for gas separation in recent years. Herein, the gas separation performance of GO membranes prepared on the surface of ceramic α-Al₂O₃ hollow fibre was investigated systematically. The microstructures of ceramic hollow fibre supported GO membranes were optimized by adjusting operation conditions. And, the GO membrane fabricated at 30 min exhibited great promising H₂ recovery ability from H₂/CO₂ mixture. At room temperature, the H₂ permeance was over 1.00×10^-7 mol·m^-2·s^-1·Pa^-1 for both single gas and binary mixture. The corresponding ideal selectivity and mixture separation factor reached around 15 and 10, respectively. In addition, humility, operation temperature, H₂ concentration in the feed and the reproducibility were also studied in this work.

关键词: Graphene oxide, Ceramic hollow fibre, Gas separation, Hydrogen recovery

Abstract: The special channels and intrinsic defects within GO laminates make it a very potential candidate for gas separation in recent years. Herein, the gas separation performance of GO membranes prepared on the surface of ceramic α-Al₂O₃ hollow fibre was investigated systematically. The microstructures of ceramic hollow fibre supported GO membranes were optimized by adjusting operation conditions. And, the GO membrane fabricated at 30 min exhibited great promising H₂ recovery ability from H₂/CO₂ mixture. At room temperature, the H₂ permeance was over 1.00×10^-7 mol·m^-2·s^-1·Pa^-1 for both single gas and binary mixture. The corresponding ideal selectivity and mixture separation factor reached around 15 and 10, respectively. In addition, humility, operation temperature, H₂ concentration in the feed and the reproducibility were also studied in this work.

Key words: Graphene oxide, Ceramic hollow fibre, Gas separation, Hydrogen recovery

Kang Huang, Jianwei Yuan, Guoshun Shen, Gongping Liu, Wanqin Jin. Graphene oxide membranes supported on the ceramic hollow fibre for efficient H₂ recovery[J]. , 2017, 25(6): 752-759.

参考文献

[1] P. Bernardo, E. Drioli, G. Golemme, Membrane gas separation:A review/state of the art, Ind. Eng. Chem. Res. 48(2009) 4638-4663.
[2] R.W. Baker, Future directions of membrane gas separation technology, Ind. Eng. Chem. Res. 41(2002) 1393-1411.
[3] X.L. Li, S. Tao, K.D. Li, Y.S. Wang, P. Wang, Z.J. Tian, In situ synthesis of ZIF-8 membranes with gas separation performance in a deep eutectic solvent, Acta Phys. -Chim. Sin. 32(2016) 1495-1500.
[4] A.J. Brown, N.A. Brunelli, K. Eum, F. Rashidi, J.R. Johnson, W.J. Koros, C.W. Jones, S. Nair, Interfacial microfluidic processing of metal-organic framework hollow fiber membranes, Science 345(2014) 72-75.
[5] Y. Hu, J. Wei, Y. Liang, H. Zhang, X. Zhang, W. Shen, H. Wang, Zeolitic imidazolate framework/graphene oxide hybrid nanosheets as seeds for the growth of ultrathin molecular sieving membranes, Angew. Chem. Int. Ed. 55(2016) 2048-2052.
[6] J. Shen, G. Liu, K. Huang, Z. Chu, W. Jin, N. Xu, Subnanometer two-dimensional graphene oxide channels for ultrafast gas sieving, ACS Nano 10(2016) 3398-3409.
[7] K. Huang, Z. Dong, Q. Li, W. Jin, Growth of a ZIF-8 membrane on the inner-surface of a ceramic hollow fiber via cycling precursors, Chem. Commun. 49(2013) 10326-10328.
[8] B. Radisavljevic, A. Radenovic, J. Brivio, V. Giacometti, A. Kis, Single-layer MoS₂ transistors, Nat. Nanotechnol. 6(2011) 147-150.
[9] K.G. Zhou, N.N. Mao, H.X. Wang, Y. Peng, H.L. Zhang, A mixed-solvent strategy for efficient exfoliation of inorganic graphene analogues, Angew. Chem. Int. Ed. 50(2011) 10839-10842.
[10] H. Liu, A.T. Neal, Z. Zhu, Z. Luo, X. Xu, D. Tománek, P.D. Ye, Phosphorene:An unexplored 2D semiconductor with a high hole mobility, ACS Nano 8(2014) 4033-4041.
[11] Y. Peng, Y. Li, Y. Ban, H. Jin, W. Jiao, X. Liu, W. Yang, Metal-organic framework nanosheets as building blocks for molecular sieving membranes, Science 346(2014) 1356-1359.
[12] A.K. Geim, Graphene:Status and prospects, Science 324(2009) 1530-1534.
[13] Z. Zheng, R. Grunker, X. Feng, Synthetic two-dimensional materials:A new paradigm of membranes for ultimate separation, Adv. Mater. (2016).
[14] Z.P. Smith, B.D. Freeman, Graphene oxide:a new platform for high-performance gas-and liquid-separation membranes, Angew. Chem. Int. Ed. 53(2014) 10286-10288.
[15] T.S. Chung, L.Y. Jiang, Y. Li, S. Kulprathipanja, Mixed matrix membranes (MMMs) comprising organic polymers with dispersed inorganic fillers for gas separation, Prog. Polym. Sci. 32(2007) 483-507.
[16] C. Sun, B. Wen, B. Bai, Recent advances in nanoporous graphene membrane for gas separation and water purification, Sci. Bull. 60(2015) 1807-1823.
[17] J. Kim, L.J. Cote, J. Huang, Two dimensional soft material:New faces of graphene oxide, Acc. Chem. Res. 45(2012) 1356-1364.
[18] G. Liu, W. Jin, N. Xu, Two-dimensional-material membranes:A new family of highperformance separation membranes, Angew. Chem. Int. Ed. 5(2016) 2-16.
[19] X. Yang, X. Yang, S. Liu, Molecular dynamics simulation of water transport through graphene-based nanopores:Flow behavior and structure characteristics, Chin. J. Chem. Eng. 23(2015) 1587-1592.
[20] R.R. Nair, H.A. Wu, P.N. Jayaram, I.V. Grigorieva, A.K. Geim, Unimpeded permeation of water through helium-leak-tight graphene-based membranes, Science 335(2012) 442-444.
[21] Y. Han, Z. Xu, C. Gao, Ultrathin graphene nanofiltration membrane for water purification, Adv. Funct. Mater. 23(2013) 3693-3700.
[22] M. Hu, B. Mi, Enabling graphene oxide nanosheets as water separation membranes, Environ. Sci. Technol. 47(2013) 3715-3723.
[23] K. Xu, B. Feng, C. Zhou, A. Huang, Synthesis of highly stable graphene oxide membranes on polydopamine functionalized supports for seawater desalination, Chem. Eng. Sci. 146(2016) 159-165.
[24] N.F.D. Aba, J.Y. Chong, B. Wang, C. Mattevi, K. Li, Graphene oxide membranes on ceramic hollow fibers-Microstructural stability and nanofiltration performance, J. Membr. Sci. 484(2015) 87-94.
[25] X. Chen, G. Liu, H. Zhang, Y. Fan, Fabrication of graphene oxide composite membranes and their application for pervaporation dehydration of butanol, Chin. J. Chem. Eng. 23(2015) 1102-1109.
[26] H. Huang, Z. Song, N. Wei, L. Shi, Y. Mao, Y. Ying, L. Sun, Z. Xu, X. Peng, Ultrafast viscous water flow through nanostrand-channelled graphene oxide membranes, Nat. Commun. 4(2013) 2979.
[27] K. Huang, G. Liu, Y. Lou, Z. Dong, J. Shen, W. Jin, A graphene oxide membrane with highly selective molecular separation of aqueous organic solution, Angew. Chem. Int. Ed. 53(2014) 6929-6932.
[28] Y.P. Tang, D.R. Paul, T.S. Chung, Free-standing graphene oxide thin films assembled by a pressurized ultrafiltration method for dehydration of ethanol, J. Membr. Sci. 458(2014) 199-208.
[29] G. Li, L. Shi, G. Zeng, Y. Zhang, Y. Sun, Efficient dehydration of the organic solvents through graphene oxide (GO)/ceramic composite membranes, RSC Adv. 4(2014) 52012-52015.
[30] W.S. Hung, Q.F. An, M. De Guzman, H.Y. Lin, S.H. Huang, W.R. Liu, C.C. Hu, K.R. Lee, J.Y. Lai, Pressure-assisted self-assembly technique for fabricating composite membranes consisting of highly ordered selective laminate layers of amphiphilic graphene oxide, Carbon 68(2014) 670-677.
[31] R.K. Joshi, P. Carbone, F.C. Wang, V.G. Kravets, Y. Su, I.V. Grigorieva, H.A. Wu, A.K. Geim, R.R. Nair, Precise and ultrafast molecular sieving through graphene oxide membranes, Science 343(2014) 752-754.
[32] S.C. O'Hern, M.S. Boutilier, J.C. Idrobo, Y. Song, J. Kong, T. Laoui, M. Atieh, R. Karnik, Selective ionic transport through tunable subnanometer pores in single-layer graphene membranes, Nano Lett. 14(2014) 1234-1241.
[33] H. Li, Z. Song, X. Zhang, Y. Huang, S. Li, Y. Mao, H.J. Ploehn, Y. Bao, M. Yu, Ultrathin, molecular-sieving graphene oxide membranes for selective hydrogen separation, Science 342(2013) 95-98.
[34] H.W. Kim, H.W. Yoon, S.-M. Yoon, B.M. Yoo, B.K. Ahn, Y.H. Cho, H.J. Shin, H. Yang, U. Paik, S. Kwon, Selective gas transport through few-layered graphene and graphene oxide membranes, Science 342(2013) 91-95.
[35] S.P. Koenig, L. Wang, J. Pellegrino, J.S. Bunch, Selective molecular sieving through porous graphene, Nat. Nanotechnol. 7(2012) 728-732.
[36] H. Kaur, V.K. Bulasara, R.K. Gupta, Preparation of kaolin-based low-cost porous ceramic supports using different amounts of carbonates, Desalin. Water Treat. 57(2016) 15154-15163.
[37] A. Kaiser, S.P. Foghmoes, G. Pećanac, J. Malzbender, C. Chatzichristodoulou, J.A. Glasscock, D. Ramachandran, D.W. Ni, V. Esposito, M. Søgaard, P.V. Hendriksen, Design and optimization of porous ceramic supports for asymmetric ceria-based oxygen transport membranes, J. Membr. Sci. 513(2016) 85-94.
[38] R. Faiz, M. Fallanza, I. Ortiz, K. Li, Separation of olefin/paraffin gas mixtures using ceramic hollow fiber membrane contactors, Ind. Eng. Chem. Res. 52(2013) 7918-7929.
[39] Y. Xu, H. Bai, G. Lu, C. Li, G. Shi, Flexible graphene films via the filtration of watersoluble noncovalent functionalized graphene sheets, J. Am. Chem. Soc. 130(2008) 5856-5857.
[40] S. Pei, H.-M. Cheng, The reduction of graphene oxide, Carbon 50(2012) 3210-3228.
[41] A. Lerf, H. He, M. Forster, J. Klinowski, Structure of graphite oxide revisited, J. Phys. Chem. B 102(1998) 4477-4482.
[42] H. He, J. Klinowski, M. Forster, A. Lerf, A new structural model for graphite oxide, Chem. Phys. Lett. 287(1998) 53-56.
[43] X. Dong, K. Huang, S. Liu, R. Ren, W. Jin, Y.S. Lin, Synthesis of zeolitic imidazolate framework-78 molecular-sieve membrane:Defect formation and elimination, J. Mater. Chem. 22(2012) 19222.
[44] X. Gu, Z. Tang, J. Dong, On-stream modification of MFI zeolite membranes for enhancing hydrogen separation at high temperature, Microporous Mesoporous Mater. 111(2008) 441-448.
[45] G. Guan, T. Tanaka, K. Kusakabe, K.I. Sotowa, S. Morooka, Characterization of AlPO 4-type molecular sieving membranes formed on a porous α-alumina tube, J. Membr. Sci. 214(2003) 191-198.
[46] L.M. Robeson, The upper bound revisited, J. Membr. Sci. 320(2008) 390-400.

Graphene oxide membranes supported on the ceramic hollow fibre for efficient H₂ recovery

Graphene oxide membranes supported on the ceramic hollow fibre for efficient H₂ recovery

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	Sinu Poolachira, Sivasubramanian Velmurugan. Graphene oxide/hydrotalcite modified polyethersulfone nanohybrid membrane for the treatment of lead ion from battery industrial effluent[J]. 中国化学工程学报, 2023, 60(8): 253-261.
[2]	Xingzhong Li, Kunlin Yu, Zibo He, Bo Liu, Rongfei Zhou, Weihong Xing. Improved SSZ-13 thin membranes fabricated by seeded-gel approach for efficient CO₂ capture[J]. 中国化学工程学报, 2023, 56(4): 273-280.
[3]	Zhengchi Yin, Xiaoke Wu, Yanwei Yang, Huayu Zhang, Wangtao Li, Ruimin Zhu, Qiancheng Zheng, Zhengbao Wang. Fabrication of ZIF-8 membranes on dual-layer ZnO-PES/PES organic hollow fibers by in-situ crystallization[J]. 中国化学工程学报, 2023, 55(3): 101-110.
[4]	Jian Tian, Gen Li, Wang He, Kok Bing Tan, Daohua Sun, Junfu Wei, Qingbiao Li. Insight into the dynamic adsorption behavior of graphene oxide multichannel architecture toward contaminants[J]. 中国化学工程学报, 2023, 53(1): 124-132.
[5]	Yingmeng Zhang, Luting Liu, Qingwei Deng, Wanlin Wu, Yongliang Li, Xiangzhong Ren, Peixin Zhang, Lingna Sun. Hybrid CuO-Co₃O₄ nanosphere/RGO sandwiched composites as anode materials for lithium-ion batteries[J]. 中国化学工程学报, 2022, 47(7): 185-192.
[6]	Xionghui Liu, Jianfeng Du, Yu Ye, Yuchuan Liu, Shun Wang, Xianyu Meng, Xiaowei Song, Zhiqiang Liang, Wenfu Yan. Boosting selective C₂H₂/CH₄, C₂H₄/CH₄ and CO₂/CH₄ adsorption performance via 1,2,3-triazole functionalized triazine-based porous organic polymers[J]. 中国化学工程学报, 2022, 42(2): 64-72.
[7]	Lu-Yue Liu, Zhuang Liu, Han-Yu Peng, Xiao-Ting Mu, Qian Zhao, Xiao-Jie Ju, Wei Wang, Rui Xie, Liang-Yin Chu. Reduced graphene oxide modified melamine sponges filling with paraffin for efficient solar-thermal conversion and heat management[J]. 中国化学工程学报, 2022, 41(1): 497-506.
[8]	Kin Kit Fong, Inn Shi Tan, Henry Chee Yew Foo, Man Kee Lam, Adrian Chiong Yuh Tiong, Steven Lim. Optimization and evaluation of reduced graphene oxide hydrogel composite as a demulsifier for heavy crude oil-in-water emulsion[J]. 中国化学工程学报, 2021, 33(5): 297-305.
[9]	Yexun Shi, Chang Li, Liming Shen, Ningzhong Bao. Structure-dependent re-dispersibility of graphene oxide powders prepared by fast spray drying[J]. 中国化学工程学报, 2021, 32(4): 485-492.
[10]	M. Ijaz Khan, Seifedine Kadry, Yuming Chu, M. Waqas. Modeling and numerical analysis of nanoliquid (titanium oxide, graphene oxide) flow viscous fluid with second order velocity slip and entropy generation[J]. 中国化学工程学报, 2021, 29(3): 17-25.
[11]	Zhi-Hao Chen, Zhuang Liu, Lei Zhang, Quan-Wei Cai, Jia-Qi Hu, Wei Wang, Xiao-Jie Ju, Rui Xie, Liang-Yin Chu. Functional graphene oxide nanosheets modified with cyclodextrins for removal of Bisphenol A from water[J]. 中国化学工程学报, 2021, 39(11): 79-87.
[12]	Golchehreh Bayat, Roozbeh Saghatchi, Jafar Azamat, Alireza Khataee. Separation of methane from different gas mixtures using modified silicon carbide nanosheet: Micro and macro scale numerical studies[J]. 中国化学工程学报, 2020, 28(5): 1268-1276.
[13]	Yingyan Mao, Chao Wang, Li Liu. Preparation of graphene oxide/natural rubber composites by latex cocoagulation: Relationship between microstructure and reinforcement[J]. 中国化学工程学报, 2020, 28(4): 1187-1193.
[14]	Mengqi Shi, Chenxi Dong, Zhi Wang, Xinxia Tian, Song Zhao, Jixiao Wang. Support surface pore structures matter: Effects of support surface pore structures on the TFC gas separation membrane performance over a wide pressure range[J]. 中国化学工程学报, 2019, 27(8): 1807-1816.
[15]	Ning Zhang, Wenxu Qi, Lili Huang, En Jiang, Junjiang Bao, Xiaopeng Zhang, Baigang An, Gaohong He. Review on structural control and modification of graphene oxide-based membranes in water treatment: From separation performance to robust operation[J]. 中国化学工程学报, 2019, 27(6): 1348-1360.