Amine-based solvent for CO2 absorption and its impact on carbon steel corrosion: A perspective review

doi:10.1016/j.cjche.2020.02.029

摘要/Abstract

摘要： Carbon dioxide (CO₂) is one of the commonly emitted gaseous by-products in industrial processes. While CO₂ gas is the main cause to greenhouse effect, various CO₂ capture technologies have been proposed and implemented to sequester the CO₂ before the waste gases being released into the atmosphere. One of the mature technologies for CO₂ absorption is by using amine-based solvents. In this regard, different single amine solvents or blended amine solvents have been proven for their capability to remove CO₂. However, the dissolution and reaction of CO₂ gas with the amine solvents turn the solution corrosive. Such phenomenon is undesired as it posts corrosion problem to the absorption column, which normally built of carbon steel material. Henceforth, understanding the behaviour of different amine-based solvents in absorbing CO₂ and its subsequent impact on carbon steel corrosion is very significant. In this review article, we will outline some of the more commonly used solvents and their respective advantages and disadvantages, motivating further investigation into the corrosion tendency. Meanwhile, existing gaps in this research area are discussed for future investigation.

关键词: Greenhouse gases, PCCC technology, Amine solvent, Corrosion rate, Carbon steel

Abstract: Carbon dioxide (CO₂) is one of the commonly emitted gaseous by-products in industrial processes. While CO₂ gas is the main cause to greenhouse effect, various CO₂ capture technologies have been proposed and implemented to sequester the CO₂ before the waste gases being released into the atmosphere. One of the mature technologies for CO₂ absorption is by using amine-based solvents. In this regard, different single amine solvents or blended amine solvents have been proven for their capability to remove CO₂. However, the dissolution and reaction of CO₂ gas with the amine solvents turn the solution corrosive. Such phenomenon is undesired as it posts corrosion problem to the absorption column, which normally built of carbon steel material. Henceforth, understanding the behaviour of different amine-based solvents in absorbing CO₂ and its subsequent impact on carbon steel corrosion is very significant. In this review article, we will outline some of the more commonly used solvents and their respective advantages and disadvantages, motivating further investigation into the corrosion tendency. Meanwhile, existing gaps in this research area are discussed for future investigation.

Key words: Greenhouse gases, PCCC technology, Amine solvent, Corrosion rate, Carbon steel

Zhe Lun Ooi, Pui Yee Tan, Lian See Tan, Swee Pin Yeap. Amine-based solvent for CO₂ absorption and its impact on carbon steel corrosion: A perspective review[J]. 中国化学工程学报, 2020, 28(5): 1357-1367.

Zhe Lun Ooi, Pui Yee Tan, Lian See Tan, Swee Pin Yeap. Amine-based solvent for CO₂ absorption and its impact on carbon steel corrosion: A perspective review[J]. Chinese Journal of Chemical Engineering, 2020, 28(5): 1357-1367.

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Amine-based solvent for CO₂ absorption and its impact on carbon steel corrosion: A perspective review

Amine-based solvent for CO₂ absorption and its impact on carbon steel corrosion: A perspective review

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