Acid precipitation coupled membrane-dispersion advanced oxidation process (MAOP) to treat crystallization mother liquor of pulp wastewater

doi:10.1016/j.cjche.2019.08.001

中国化学工程学报 ›› 2020, Vol. 28 ›› Issue (7): 1911-1917.DOI: 10.1016/j.cjche.2019.08.001

• Energy, Resources and Environmental Technology • 上一篇下一篇

Acid precipitation coupled membrane-dispersion advanced oxidation process (MAOP) to treat crystallization mother liquor of pulp wastewater

Rongzong Li, Zhaoyang Li, Qian Jiang, Zhaoxiang Zhong, Ming Zhou, Weihong Xing

State Key Laboratory of Materials-Oriented Chemical Engineering, National Engineering Research Center for Special Separation Membrane, Nanjing Tech University, Nanjing 210009, China

收稿日期:2019-06-18 修回日期:2019-07-30 出版日期:2020-07-28 发布日期:2020-08-31
通讯作者: Ming Zhou, Weihong Xing
基金资助:
Financial supports from the Prospective Joint Research Project of Jiangsu Province (BY2014005-06), National Natural Science Foundation of China (U1510202), and the Jiangsu National Synergistic Innovation Center for Advanced Materials (SICAM) are gratefully acknowledged.

Acid precipitation coupled membrane-dispersion advanced oxidation process (MAOP) to treat crystallization mother liquor of pulp wastewater

Rongzong Li, Zhaoyang Li, Qian Jiang, Zhaoxiang Zhong, Ming Zhou, Weihong Xing

State Key Laboratory of Materials-Oriented Chemical Engineering, National Engineering Research Center for Special Separation Membrane, Nanjing Tech University, Nanjing 210009, China

Received:2019-06-18 Revised:2019-07-30 Online:2020-07-28 Published:2020-08-31
Contact: Ming Zhou, Weihong Xing
Supported by:
Financial supports from the Prospective Joint Research Project of Jiangsu Province (BY2014005-06), National Natural Science Foundation of China (U1510202), and the Jiangsu National Synergistic Innovation Center for Advanced Materials (SICAM) are gratefully acknowledged.

摘要/Abstract

摘要： Treatment to crystallization mother liquor containing high concentration of organic and inorganic substances is a challenge in zero liquid discharge of industrial wastewater. Acid precipitation coupled membrane-dispersion advanced oxidation process (MAOP) was proposed for organics degradation before salt crystallization by evaporation. With acid-MAOP treatment CODCr in mother liquor of pulping wastewater was eliminated by 55.2% from ultrahigh initial concentration up to 12,500 mg·L^-1. The decolorization rate was 96.5%. Recovered salt was mainly NaCl (83.3 wt%) having whiteness 50 brighter than industrial baysalt of whiteness 45. The oxidation conditions were optimized as C_O₃ = 0.11 g·L^-1 and C_H₂O₂ = 2.0 g·L^-1 with dispersing rate 0.53 ml·min^-1 for 100 min reaction toward acidified liquor of pH = 2. Acidification has notably improved evaporation efficiency during crystallization. Addition of H₂O₂ made through membrane dispersion has eliminated hydroxyl radical “quench effect” and enhanced the degradation capacity, in particular, the breakage of carbon-chloride bonds (of both aliphatic and aromatic). As a result, the proposed coupling method has improved organic pollutant reduction so as the purity of salt from the wastewater mixture which can facilitate water and salt recycling in industry.

关键词: Advanced oxidation process, Crystallization mother liquor, Ceramic membrane dispersion, Pulping wastewater

Abstract: Treatment to crystallization mother liquor containing high concentration of organic and inorganic substances is a challenge in zero liquid discharge of industrial wastewater. Acid precipitation coupled membrane-dispersion advanced oxidation process (MAOP) was proposed for organics degradation before salt crystallization by evaporation. With acid-MAOP treatment CODCr in mother liquor of pulping wastewater was eliminated by 55.2% from ultrahigh initial concentration up to 12,500 mg·L^-1. The decolorization rate was 96.5%. Recovered salt was mainly NaCl (83.3 wt%) having whiteness 50 brighter than industrial baysalt of whiteness 45. The oxidation conditions were optimized as C_O₃ = 0.11 g·L^-1 and C_H₂O₂ = 2.0 g·L^-1 with dispersing rate 0.53 ml·min^-1 for 100 min reaction toward acidified liquor of pH = 2. Acidification has notably improved evaporation efficiency during crystallization. Addition of H₂O₂ made through membrane dispersion has eliminated hydroxyl radical “quench effect” and enhanced the degradation capacity, in particular, the breakage of carbon-chloride bonds (of both aliphatic and aromatic). As a result, the proposed coupling method has improved organic pollutant reduction so as the purity of salt from the wastewater mixture which can facilitate water and salt recycling in industry.

Key words: Advanced oxidation process, Crystallization mother liquor, Ceramic membrane dispersion, Pulping wastewater

Rongzong Li, Zhaoyang Li, Qian Jiang, Zhaoxiang Zhong, Ming Zhou, Weihong Xing. Acid precipitation coupled membrane-dispersion advanced oxidation process (MAOP) to treat crystallization mother liquor of pulp wastewater[J]. 中国化学工程学报, 2020, 28(7): 1911-1917.

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Acid precipitation coupled membrane-dispersion advanced oxidation process (MAOP) to treat crystallization mother liquor of pulp wastewater

Acid precipitation coupled membrane-dispersion advanced oxidation process (MAOP) to treat crystallization mother liquor of pulp wastewater

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