Fabricating amide functional group modified hyper-cross-linked adsorption resin with enhanced adsorption and recognition performance for 5-hydroxymethylfurfural adsorption via simple one-step

doi:10.1016/j.cjche.2021.11.006

中国化学工程学报 ›› 2022, Vol. 43 ›› Issue (3): 230-239.DOI: 10.1016/j.cjche.2021.11.006

Fabricating amide functional group modified hyper-cross-linked adsorption resin with enhanced adsorption and recognition performance for 5-hydroxymethylfurfural adsorption via simple one-step

Lei Hu¹, Shunhui Tao¹, Junting Xian¹, Xiaodong Zhang¹, Yao Liu¹, Xiaojie Zheng¹, Xiaoqing Lin^1,2,3

1. School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou 510006, China;
2. Guangdong Provincial Key Laboratory of Plant Resources Biorefinery, Guangdong University of Technology, Guangzhou 510006, China;
3. Guangzhou Key Laboratory of Clean Transportation Energy Chemistry, Guangdong University of Technology, Guangzhou 510006, China

收稿日期:2021-08-26 修回日期:2021-11-03 出版日期:2022-03-28 发布日期:2022-04-28
通讯作者: Xiaoqing Lin,E-mail:linxiaoqing@gdut.edu.cn
基金资助:
This work was supported by National Natural Science Foundation of China (21978053, 51508547), the Key Area Research and Development Program of Guangdong Province (2020B0101070001), and the "One-Hundred Young Talents" Program of Guangdong University of Technology (220413185).

Fabricating amide functional group modified hyper-cross-linked adsorption resin with enhanced adsorption and recognition performance for 5-hydroxymethylfurfural adsorption via simple one-step

Lei Hu¹, Shunhui Tao¹, Junting Xian¹, Xiaodong Zhang¹, Yao Liu¹, Xiaojie Zheng¹, Xiaoqing Lin^1,2,3

1. School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou 510006, China;
2. Guangdong Provincial Key Laboratory of Plant Resources Biorefinery, Guangdong University of Technology, Guangzhou 510006, China;
3. Guangzhou Key Laboratory of Clean Transportation Energy Chemistry, Guangdong University of Technology, Guangzhou 510006, China

Received:2021-08-26 Revised:2021-11-03 Online:2022-03-28 Published:2022-04-28
Contact: Xiaoqing Lin,E-mail:linxiaoqing@gdut.edu.cn
Supported by:
This work was supported by National Natural Science Foundation of China (21978053, 51508547), the Key Area Research and Development Program of Guangdong Province (2020B0101070001), and the "One-Hundred Young Talents" Program of Guangdong University of Technology (220413185).

摘要/Abstract

摘要： In this study, three kinds of amide functional group modified hyper-cross-linked adsorption resin were synthesized by alternating radical copolymerization in simple one-step and applied for 5-hydroxymethylfurfural (5-HMF) adsorption. The successful synthesis and properties of adsorbents were evaluated with Fourier transform infrared spectroscopy, scanning electron microscopy, nitrogen adsorption–desorption isotherms, thermogravimetric analysis, and elemental analysis. Poly (N, N'-4,4'-diphenylmethane-bismaleimide-alt-divinylbenzene) (poly (BDM-alt-DVB)) resin exhibited highest adsorption capacity for 5-HMF (64.0 mg·g^-1 wet resin) and excellent adsorption selectivity (α_5-HMF/LA = 2.71 ±0.12, α_5-HMF/FA = 13.88 ±0.15, α_{5-HMF/Glucose} = 11.91 ±1.11) in the multi-component solution at 25 ℃. Langmuir isotherm model well fitted the equilibrium adsorption data within the initial 5-HMF concentration range of 0.5–10.0 g·L^-1 with highest correlation coefficient. Furthermore, the thermodynamic parameters demonstrated that the adsorption of 5-HMF onto poly (BDM-alt-DVB) resin was spontaneous and exothermic. Kinetic study revealed that the adsorption process was fast, reaching equilibrium within 12 min. Importantly, the poly (BDM-alt-DVB) resin also demonstrated excellent reusability. In summary, the poly (BDM-alt-DVB) resin will be useful in 5-HMF hydrolysate separation applications.

关键词: Adsorption, 5-Hydroxymethylfurfural, Isotherm, Thermodynamics, Kinetics, Mechanism

Abstract: In this study, three kinds of amide functional group modified hyper-cross-linked adsorption resin were synthesized by alternating radical copolymerization in simple one-step and applied for 5-hydroxymethylfurfural (5-HMF) adsorption. The successful synthesis and properties of adsorbents were evaluated with Fourier transform infrared spectroscopy, scanning electron microscopy, nitrogen adsorption–desorption isotherms, thermogravimetric analysis, and elemental analysis. Poly (N, N'-4,4'-diphenylmethane-bismaleimide-alt-divinylbenzene) (poly (BDM-alt-DVB)) resin exhibited highest adsorption capacity for 5-HMF (64.0 mg·g^-1 wet resin) and excellent adsorption selectivity (α_5-HMF/LA = 2.71 ±0.12, α_5-HMF/FA = 13.88 ±0.15, α_{5-HMF/Glucose} = 11.91 ±1.11) in the multi-component solution at 25 ℃. Langmuir isotherm model well fitted the equilibrium adsorption data within the initial 5-HMF concentration range of 0.5–10.0 g·L^-1 with highest correlation coefficient. Furthermore, the thermodynamic parameters demonstrated that the adsorption of 5-HMF onto poly (BDM-alt-DVB) resin was spontaneous and exothermic. Kinetic study revealed that the adsorption process was fast, reaching equilibrium within 12 min. Importantly, the poly (BDM-alt-DVB) resin also demonstrated excellent reusability. In summary, the poly (BDM-alt-DVB) resin will be useful in 5-HMF hydrolysate separation applications.

Key words: Adsorption, 5-Hydroxymethylfurfural, Isotherm, Thermodynamics, Kinetics, Mechanism

Lei Hu, Shunhui Tao, Junting Xian, Xiaodong Zhang, Yao Liu, Xiaojie Zheng, Xiaoqing Lin. Fabricating amide functional group modified hyper-cross-linked adsorption resin with enhanced adsorption and recognition performance for 5-hydroxymethylfurfural adsorption via simple one-step[J]. 中国化学工程学报, 2022, 43(3): 230-239.

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Fabricating amide functional group modified hyper-cross-linked adsorption resin with enhanced adsorption and recognition performance for 5-hydroxymethylfurfural adsorption via simple one-step

Fabricating amide functional group modified hyper-cross-linked adsorption resin with enhanced adsorption and recognition performance for 5-hydroxymethylfurfural adsorption via simple one-step

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